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2-[(1R*,4R*)-1,4-Dihydroxycyclohexyl]acetic acid
The title compound, C(8)H(14)O(4), is an isolation product of the aerial parts of Senecio desfontanei. The acetic acid group is oriented at a dihedral angle of 48.03 (9)° with respect to the basal plane of the cyclohexane-1,4-diol chair. An intramolecular O—H⋯O hydrogen bond generates an S(6) ring...
Autores principales: | , , , , |
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Formato: | Texto |
Lenguaje: | English |
Publicado: |
International Union of Crystallography
2011
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Materias: | |
Acceso en línea: | https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3100032/ https://www.ncbi.nlm.nih.gov/pubmed/21754231 http://dx.doi.org/10.1107/S1600536811010397 |
Sumario: | The title compound, C(8)H(14)O(4), is an isolation product of the aerial parts of Senecio desfontanei. The acetic acid group is oriented at a dihedral angle of 48.03 (9)° with respect to the basal plane of the cyclohexane-1,4-diol chair. An intramolecular O—H⋯O hydrogen bond generates an S(6) ring with an envelope conformation. In the crystal, molecules are linked by O—H⋯O hydrogen bonds, resulting in R (3) (3)(20) ring motifs and C(2) O—H⋯O—H⋯O—H⋯ chains. Overall, a three-dimensional polymeric network arises. A C—H⋯O contact is also present. |
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