4-(4,4-Difluoro-1,3,5,7-tetra­methyl-3a-aza-4a-azonia-4-borata-s-indacen-8-yl)benzonitrile

The title compound, C(20)H(18)BF(2)N(3), contains one C(9)BN(2) (Bodipy) framework and one cyano­benzyl group. The Bodipy framework is essentially planar with a maximum deviation of 0.041 (2) Å. The introduction of two methyl groups at positions 1 and 7 of s-indacene in the Bodipy unit results in al...

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Detalles Bibliográficos
Autores principales: Chen, Yuting, Jiang, Jianzhuang
Formato: Texto
Lenguaje:English
Publicado: International Union of Crystallography 2011
Materias:
Organic Papers
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3100033/
https://www.ncbi.nlm.nih.gov/pubmed/21754182
http://dx.doi.org/10.1107/S1600536811009457
Descripción
Sumario:The title compound, C(20)H(18)BF(2)N(3), contains one C(9)BN(2) (Bodipy) framework and one cyano­benzyl group. The Bodipy framework is essentially planar with a maximum deviation of 0.041 (2) Å. The introduction of two methyl groups at positions 1 and 7 of s-indacene in the Bodipy unit results in almost orthogonal configuration between the mean plane of the Bodipy unit and the cyano­benzyl group [dihedral angle = 89.78 (4)°].

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