4-(4,4-Difluoro-1,3,5,7-tetra­methyl-3a-aza-4a-azonia-4-borata-s-indacen-8-yl)benzonitrile

The title compound, C(20)H(18)BF(2)N(3), contains one C(9)BN(2) (Bodipy) framework and one cyano­benzyl group. The Bodipy framework is essentially planar with a maximum deviation of 0.041 (2) Å. The introduction of two methyl groups at positions 1 and 7 of s-indacene in the Bodipy unit results in al...

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Detalles Bibliográficos
Autores principales: Chen, Yuting, Jiang, Jianzhuang
Formato: Texto
Lenguaje:English
Publicado: International Union of Crystallography 2011
Materias:
Organic Papers
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3100033/
https://www.ncbi.nlm.nih.gov/pubmed/21754182
http://dx.doi.org/10.1107/S1600536811009457
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author Chen, Yuting
Jiang, Jianzhuang
author_facet Chen, Yuting
Jiang, Jianzhuang
author_sort Chen, Yuting
collection PubMed
description The title compound, C(20)H(18)BF(2)N(3), contains one C(9)BN(2) (Bodipy) framework and one cyano­benzyl group. The Bodipy framework is essentially planar with a maximum deviation of 0.041 (2) Å. The introduction of two methyl groups at positions 1 and 7 of s-indacene in the Bodipy unit results in almost orthogonal configuration between the mean plane of the Bodipy unit and the cyano­benzyl group [dihedral angle = 89.78 (4)°].
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spelling pubmed-31000332011-07-13 4-(4,4-Difluoro-1,3,5,7-tetra­methyl-3a-aza-4a-azonia-4-borata-s-indacen-8-yl)benzonitrile Chen, Yuting Jiang, Jianzhuang Acta Crystallogr Sect E Struct Rep Online Organic Papers The title compound, C(20)H(18)BF(2)N(3), contains one C(9)BN(2) (Bodipy) framework and one cyano­benzyl group. The Bodipy framework is essentially planar with a maximum deviation of 0.041 (2) Å. The introduction of two methyl groups at positions 1 and 7 of s-indacene in the Bodipy unit results in almost orthogonal configuration between the mean plane of the Bodipy unit and the cyano­benzyl group [dihedral angle = 89.78 (4)°]. International Union of Crystallography 2011-03-19 /pmc/articles/PMC3100033/ /pubmed/21754182 http://dx.doi.org/10.1107/S1600536811009457 Text en © Chen and Jiang 2011 http://creativecommons.org/licenses/by/2.0/uk/ This is an open-access article distributed under the terms of the Creative Commons Attribution Licence, which permits unrestricted use, distribution, and reproduction in any medium, provided the original authors and source are cited.
spellingShingle Organic Papers
Chen, Yuting
Jiang, Jianzhuang
4-(4,4-Difluoro-1,3,5,7-tetra­methyl-3a-aza-4a-azonia-4-borata-s-indacen-8-yl)benzonitrile
title 4-(4,4-Difluoro-1,3,5,7-tetra­methyl-3a-aza-4a-azonia-4-borata-s-indacen-8-yl)benzonitrile
title_full 4-(4,4-Difluoro-1,3,5,7-tetra­methyl-3a-aza-4a-azonia-4-borata-s-indacen-8-yl)benzonitrile
title_fullStr 4-(4,4-Difluoro-1,3,5,7-tetra­methyl-3a-aza-4a-azonia-4-borata-s-indacen-8-yl)benzonitrile
title_full_unstemmed 4-(4,4-Difluoro-1,3,5,7-tetra­methyl-3a-aza-4a-azonia-4-borata-s-indacen-8-yl)benzonitrile
title_short 4-(4,4-Difluoro-1,3,5,7-tetra­methyl-3a-aza-4a-azonia-4-borata-s-indacen-8-yl)benzonitrile
title_sort 4-(4,4-difluoro-1,3,5,7-tetra­methyl-3a-aza-4a-azonia-4-borata-s-indacen-8-yl)benzonitrile
topic Organic Papers
url https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3100033/
https://www.ncbi.nlm.nih.gov/pubmed/21754182
http://dx.doi.org/10.1107/S1600536811009457
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