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catena-Poly[[dichloridocobalt(II)]-μ-4,4′-bis(benzimidazol-1-yl)biphenyl]
In the title compound, [CoCl(2)(C(26)H(18)N(4))](n), the Co(II) atom (site symmetry 2) is tetrahedrally coordinated by two chloride ions and two N atoms from 4,4′-bis(benzimidazol-1-yl)biphenyl ligands: the complete ligand is generated by crystallographic twofold symmetry. The dihedral angle betwe...
Autores principales: | , , , , |
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Formato: | Texto |
Lenguaje: | English |
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International Union of Crystallography
2011
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Acceso en línea: | https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3100034/ https://www.ncbi.nlm.nih.gov/pubmed/21754002 http://dx.doi.org/10.1107/S1600536811010671 |
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author | Li, Hui Han, Qiuping Yao, Chenzhong Gong, Qiaojuan Wei, Zhuangwei |
author_facet | Li, Hui Han, Qiuping Yao, Chenzhong Gong, Qiaojuan Wei, Zhuangwei |
author_sort | Li, Hui |
collection | PubMed |
description | In the title compound, [CoCl(2)(C(26)H(18)N(4))](n), the Co(II) atom (site symmetry 2) is tetrahedrally coordinated by two chloride ions and two N atoms from 4,4′-bis(benzimidazol-1-yl)biphenyl ligands: the complete ligand is generated by crystallographic twofold symmetry. The dihedral angle between the benzene rings is 34.67 (8)° and the angle between the benene ring and the adjacent benzimidazole ring system is 43.26 (10)°. The bridging ligand links the Co(II) atoms into chains propagating in [[Image: see text]01]. |
format | Text |
id | pubmed-3100034 |
institution | National Center for Biotechnology Information |
language | English |
publishDate | 2011 |
publisher | International Union of Crystallography |
record_format | MEDLINE/PubMed |
spelling | pubmed-31000342011-07-13 catena-Poly[[dichloridocobalt(II)]-μ-4,4′-bis(benzimidazol-1-yl)biphenyl] Li, Hui Han, Qiuping Yao, Chenzhong Gong, Qiaojuan Wei, Zhuangwei Acta Crystallogr Sect E Struct Rep Online Metal-Organic Papers In the title compound, [CoCl(2)(C(26)H(18)N(4))](n), the Co(II) atom (site symmetry 2) is tetrahedrally coordinated by two chloride ions and two N atoms from 4,4′-bis(benzimidazol-1-yl)biphenyl ligands: the complete ligand is generated by crystallographic twofold symmetry. The dihedral angle between the benzene rings is 34.67 (8)° and the angle between the benene ring and the adjacent benzimidazole ring system is 43.26 (10)°. The bridging ligand links the Co(II) atoms into chains propagating in [[Image: see text]01]. International Union of Crystallography 2011-03-26 /pmc/articles/PMC3100034/ /pubmed/21754002 http://dx.doi.org/10.1107/S1600536811010671 Text en © Li et al. 2011 http://creativecommons.org/licenses/by/2.0/uk/ This is an open-access article distributed under the terms of the Creative Commons Attribution Licence, which permits unrestricted use, distribution, and reproduction in any medium, provided the original authors and source are cited. |
spellingShingle | Metal-Organic Papers Li, Hui Han, Qiuping Yao, Chenzhong Gong, Qiaojuan Wei, Zhuangwei catena-Poly[[dichloridocobalt(II)]-μ-4,4′-bis(benzimidazol-1-yl)biphenyl] |
title |
catena-Poly[[dichloridocobalt(II)]-μ-4,4′-bis(benzimidazol-1-yl)biphenyl] |
title_full |
catena-Poly[[dichloridocobalt(II)]-μ-4,4′-bis(benzimidazol-1-yl)biphenyl] |
title_fullStr |
catena-Poly[[dichloridocobalt(II)]-μ-4,4′-bis(benzimidazol-1-yl)biphenyl] |
title_full_unstemmed |
catena-Poly[[dichloridocobalt(II)]-μ-4,4′-bis(benzimidazol-1-yl)biphenyl] |
title_short |
catena-Poly[[dichloridocobalt(II)]-μ-4,4′-bis(benzimidazol-1-yl)biphenyl] |
title_sort | catena-poly[[dichloridocobalt(ii)]-μ-4,4′-bis(benzimidazol-1-yl)biphenyl] |
topic | Metal-Organic Papers |
url | https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3100034/ https://www.ncbi.nlm.nih.gov/pubmed/21754002 http://dx.doi.org/10.1107/S1600536811010671 |
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