Cargando…

catena-Poly[[dichloridocobalt(II)]-μ-4,4′-bis­(benzimidazol-1-yl)biphen­yl]

In the title compound, [CoCl(2)(C(26)H(18)N(4))](n), the Co(II) atom (site symmetry 2) is tetra­hedrally coordinated by two chloride ions and two N atoms from 4,4′-bis­(benzimidazol-1-yl)biphenyl ligands: the complete ligand is generated by crystallographic twofold symmetry. The dihedral angle betwe...

Descripción completa

Detalles Bibliográficos
Autores principales: Li, Hui, Han, Qiuping, Yao, Chenzhong, Gong, Qiaojuan, Wei, Zhuangwei
Formato: Texto
Lenguaje:English
Publicado: International Union of Crystallography 2011
Materias:
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3100034/
https://www.ncbi.nlm.nih.gov/pubmed/21754002
http://dx.doi.org/10.1107/S1600536811010671
_version_ 1782204143597780992
author Li, Hui
Han, Qiuping
Yao, Chenzhong
Gong, Qiaojuan
Wei, Zhuangwei
author_facet Li, Hui
Han, Qiuping
Yao, Chenzhong
Gong, Qiaojuan
Wei, Zhuangwei
author_sort Li, Hui
collection PubMed
description In the title compound, [CoCl(2)(C(26)H(18)N(4))](n), the Co(II) atom (site symmetry 2) is tetra­hedrally coordinated by two chloride ions and two N atoms from 4,4′-bis­(benzimidazol-1-yl)biphenyl ligands: the complete ligand is generated by crystallographic twofold symmetry. The dihedral angle between the benzene rings is 34.67 (8)° and the angle between the benene ring and the adjacent benzimidazole ring system is 43.26 (10)°. The bridging ligand links the Co(II) atoms into chains propagating in [[Image: see text]01].
format Text
id pubmed-3100034
institution National Center for Biotechnology Information
language English
publishDate 2011
publisher International Union of Crystallography
record_format MEDLINE/PubMed
spelling pubmed-31000342011-07-13 catena-Poly[[dichloridocobalt(II)]-μ-4,4′-bis­(benzimidazol-1-yl)biphen­yl] Li, Hui Han, Qiuping Yao, Chenzhong Gong, Qiaojuan Wei, Zhuangwei Acta Crystallogr Sect E Struct Rep Online Metal-Organic Papers In the title compound, [CoCl(2)(C(26)H(18)N(4))](n), the Co(II) atom (site symmetry 2) is tetra­hedrally coordinated by two chloride ions and two N atoms from 4,4′-bis­(benzimidazol-1-yl)biphenyl ligands: the complete ligand is generated by crystallographic twofold symmetry. The dihedral angle between the benzene rings is 34.67 (8)° and the angle between the benene ring and the adjacent benzimidazole ring system is 43.26 (10)°. The bridging ligand links the Co(II) atoms into chains propagating in [[Image: see text]01]. International Union of Crystallography 2011-03-26 /pmc/articles/PMC3100034/ /pubmed/21754002 http://dx.doi.org/10.1107/S1600536811010671 Text en © Li et al. 2011 http://creativecommons.org/licenses/by/2.0/uk/ This is an open-access article distributed under the terms of the Creative Commons Attribution Licence, which permits unrestricted use, distribution, and reproduction in any medium, provided the original authors and source are cited.
spellingShingle Metal-Organic Papers
Li, Hui
Han, Qiuping
Yao, Chenzhong
Gong, Qiaojuan
Wei, Zhuangwei
catena-Poly[[dichloridocobalt(II)]-μ-4,4′-bis­(benzimidazol-1-yl)biphen­yl]
title catena-Poly[[dichloridocobalt(II)]-μ-4,4′-bis­(benzimidazol-1-yl)biphen­yl]
title_full catena-Poly[[dichloridocobalt(II)]-μ-4,4′-bis­(benzimidazol-1-yl)biphen­yl]
title_fullStr catena-Poly[[dichloridocobalt(II)]-μ-4,4′-bis­(benzimidazol-1-yl)biphen­yl]
title_full_unstemmed catena-Poly[[dichloridocobalt(II)]-μ-4,4′-bis­(benzimidazol-1-yl)biphen­yl]
title_short catena-Poly[[dichloridocobalt(II)]-μ-4,4′-bis­(benzimidazol-1-yl)biphen­yl]
title_sort catena-poly[[dichloridocobalt(ii)]-μ-4,4′-bis­(benzimidazol-1-yl)biphen­yl]
topic Metal-Organic Papers
url https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3100034/
https://www.ncbi.nlm.nih.gov/pubmed/21754002
http://dx.doi.org/10.1107/S1600536811010671
work_keys_str_mv AT lihui catenapolydichloridocobaltiim44bisbenzimidazol1ylbiphenyl
AT hanqiuping catenapolydichloridocobaltiim44bisbenzimidazol1ylbiphenyl
AT yaochenzhong catenapolydichloridocobaltiim44bisbenzimidazol1ylbiphenyl
AT gongqiaojuan catenapolydichloridocobaltiim44bisbenzimidazol1ylbiphenyl
AT weizhuangwei catenapolydichloridocobaltiim44bisbenzimidazol1ylbiphenyl