Poly[(μ-2-hy­droxy-3,5-dinitro­benzoato)rubidium]

The asymmetric unit of the title compound, [Rb(C(7)H(3)N(2)O(7))](n), comprises an Rb(+) cation and a 3,5-dinitro­salicylate ligand. The Rb(+) cation is 10-coordinated by O atoms from eight 3,5-dinitro­salicylate anions and is linked by three μ(2)-O atoms, forming a zigzag chain along the b-axis dir...

Descripción completa

Detalles Bibliográficos
Autor principal: Meng, Yan
Formato: Texto
Lenguaje:English
Publicado: International Union of Crystallography 2011
Materias:
Metal-Organic Papers
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3100035/
https://www.ncbi.nlm.nih.gov/pubmed/21753973
http://dx.doi.org/10.1107/S1600536811008476
_version_ 1782204143838953472
author Meng, Yan
author_facet Meng, Yan
author_sort Meng, Yan
collection PubMed
description The asymmetric unit of the title compound, [Rb(C(7)H(3)N(2)O(7))](n), comprises an Rb(+) cation and a 3,5-dinitro­salicylate ligand. The Rb(+) cation is 10-coordinated by O atoms from eight 3,5-dinitro­salicylate anions and is linked by three μ(2)-O atoms, forming a zigzag chain along the b-axis direction, which is further linked by the phenyl groups, giving the three-dimensional framework. The crystal structure involves intra-anionic O—H⋯O hydrogen bonds and strong π–π stacking inter­actions [centroid-centroid distance = 3.6755 (7) Å].
format Text
id pubmed-3100035
institution National Center for Biotechnology Information
language English
publishDate 2011
publisher International Union of Crystallography
record_format MEDLINE/PubMed
spelling pubmed-31000352011-07-13 Poly[(μ-2-hy­droxy-3,5-dinitro­benzoato)rubidium] Meng, Yan Acta Crystallogr Sect E Struct Rep Online Metal-Organic Papers The asymmetric unit of the title compound, [Rb(C(7)H(3)N(2)O(7))](n), comprises an Rb(+) cation and a 3,5-dinitro­salicylate ligand. The Rb(+) cation is 10-coordinated by O atoms from eight 3,5-dinitro­salicylate anions and is linked by three μ(2)-O atoms, forming a zigzag chain along the b-axis direction, which is further linked by the phenyl groups, giving the three-dimensional framework. The crystal structure involves intra-anionic O—H⋯O hydrogen bonds and strong π–π stacking inter­actions [centroid-centroid distance = 3.6755 (7) Å]. International Union of Crystallography 2011-03-15 /pmc/articles/PMC3100035/ /pubmed/21753973 http://dx.doi.org/10.1107/S1600536811008476 Text en © Yan Meng 2011 http://creativecommons.org/licenses/by/2.0/uk/ This is an open-access article distributed under the terms of the Creative Commons Attribution Licence, which permits unrestricted use, distribution, and reproduction in any medium, provided the original authors and source are cited.
spellingShingle Metal-Organic Papers
Meng, Yan
Poly[(μ-2-hy­droxy-3,5-dinitro­benzoato)rubidium]
title Poly[(μ-2-hy­droxy-3,5-dinitro­benzoato)rubidium]
title_full Poly[(μ-2-hy­droxy-3,5-dinitro­benzoato)rubidium]
title_fullStr Poly[(μ-2-hy­droxy-3,5-dinitro­benzoato)rubidium]
title_full_unstemmed Poly[(μ-2-hy­droxy-3,5-dinitro­benzoato)rubidium]
title_short Poly[(μ-2-hy­droxy-3,5-dinitro­benzoato)rubidium]
title_sort poly[(μ-2-hy­droxy-3,5-dinitro­benzoato)rubidium]
topic Metal-Organic Papers
url https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3100035/
https://www.ncbi.nlm.nih.gov/pubmed/21753973
http://dx.doi.org/10.1107/S1600536811008476
work_keys_str_mv AT mengyan polym2hydroxy35dinitrobenzoatorubidium

Ejemplares similares