(Benzene­carbothio­amide-κS)­penta­carbonyl­tungsten(0)

The asymmetric unit of the title complex, [W(C(7)H(7)NS)(CO)(5)], comprises two independent mol­ecules. In each, the W atom is coordinated by five CO groups and the S atom of the benzencarbothioamide ligand in a distorted octa­hedral geometry. The crystal packing can be described as undulating layer...

Descripción completa

Detalles Bibliográficos
Autores principales: Merniz, Salah, Mokhtari, Mahiedine, Bouacida, Sofiane, Ouahab, Lahcène, Mousser, Abdelhamid
Formato: Texto
Lenguaje:English
Publicado: International Union of Crystallography 2011
Materias:
Metal-Organic Papers
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3100038/
https://www.ncbi.nlm.nih.gov/pubmed/21753955
http://dx.doi.org/10.1107/S1600536811008579
_version_ 1782204144549888000
author Merniz, Salah
Mokhtari, Mahiedine
Bouacida, Sofiane
Ouahab, Lahcène
Mousser, Abdelhamid
author_facet Merniz, Salah
Mokhtari, Mahiedine
Bouacida, Sofiane
Ouahab, Lahcène
Mousser, Abdelhamid
author_sort Merniz, Salah
collection PubMed
description The asymmetric unit of the title complex, [W(C(7)H(7)NS)(CO)(5)], comprises two independent mol­ecules. In each, the W atom is coordinated by five CO groups and the S atom of the benzencarbothioamide ligand in a distorted octa­hedral geometry. The crystal packing can be described as undulating layers of W(CO)(5) and benzene­carbothio­amide parallel to (001). In the crystal, components are linked via inter­molecular N—H⋯O and C—H⋯O hydrogen bonds to form a dimeric chains along the [010] direction. Intra­molecular N—H⋯C inter­actions are also observed.
format Text
id pubmed-3100038
institution National Center for Biotechnology Information
language English
publishDate 2011
publisher International Union of Crystallography
record_format MEDLINE/PubMed
spelling pubmed-31000382011-07-13 (Benzene­carbothio­amide-κS)­penta­carbonyl­tungsten(0) Merniz, Salah Mokhtari, Mahiedine Bouacida, Sofiane Ouahab, Lahcène Mousser, Abdelhamid Acta Crystallogr Sect E Struct Rep Online Metal-Organic Papers The asymmetric unit of the title complex, [W(C(7)H(7)NS)(CO)(5)], comprises two independent mol­ecules. In each, the W atom is coordinated by five CO groups and the S atom of the benzencarbothioamide ligand in a distorted octa­hedral geometry. The crystal packing can be described as undulating layers of W(CO)(5) and benzene­carbothio­amide parallel to (001). In the crystal, components are linked via inter­molecular N—H⋯O and C—H⋯O hydrogen bonds to form a dimeric chains along the [010] direction. Intra­molecular N—H⋯C inter­actions are also observed. International Union of Crystallography 2011-03-12 /pmc/articles/PMC3100038/ /pubmed/21753955 http://dx.doi.org/10.1107/S1600536811008579 Text en © Merniz et al. 2011 http://creativecommons.org/licenses/by/2.0/uk/ This is an open-access article distributed under the terms of the Creative Commons Attribution Licence, which permits unrestricted use, distribution, and reproduction in any medium, provided the original authors and source are cited.
spellingShingle Metal-Organic Papers
Merniz, Salah
Mokhtari, Mahiedine
Bouacida, Sofiane
Ouahab, Lahcène
Mousser, Abdelhamid
(Benzene­carbothio­amide-κS)­penta­carbonyl­tungsten(0)
title (Benzene­carbothio­amide-κS)­penta­carbonyl­tungsten(0)
title_full (Benzene­carbothio­amide-κS)­penta­carbonyl­tungsten(0)
title_fullStr (Benzene­carbothio­amide-κS)­penta­carbonyl­tungsten(0)
title_full_unstemmed (Benzene­carbothio­amide-κS)­penta­carbonyl­tungsten(0)
title_short (Benzene­carbothio­amide-κS)­penta­carbonyl­tungsten(0)
title_sort (benzene­carbothio­amide-κs)­penta­carbonyl­tungsten(0)
topic Metal-Organic Papers
url https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3100038/
https://www.ncbi.nlm.nih.gov/pubmed/21753955
http://dx.doi.org/10.1107/S1600536811008579
work_keys_str_mv AT mernizsalah benzenecarbothioamidekspentacarbonyltungsten0
AT mokhtarimahiedine benzenecarbothioamidekspentacarbonyltungsten0
AT bouacidasofiane benzenecarbothioamidekspentacarbonyltungsten0
AT ouahablahcene benzenecarbothioamidekspentacarbonyltungsten0
AT mousserabdelhamid benzenecarbothioamidekspentacarbonyltungsten0

Ejemplares similares