4-Chloro-N-(2-chloro­phen­yl)benzene­sulfonamide

In the crystal structure of the title compound, C(12)H(9)Cl(2)NO(2)S, the N—C bond in the C—SO(2)—NH—C segment has gauche torsions with respect to the S=O bonds. The mol­ecule is twisted at the S atom with an C—SO(2)—NH—C torsion angle of 57.6 (3)°. The N—H bond is syn to the ortho-chloro group in t...

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Detalles Bibliográficos
Autores principales: Shakuntala, K., Foro, Sabine, Gowda, B. Thimme
Formato: Texto
Lenguaje:English
Publicado: International Union of Crystallography 2011
Materias:
Organic Papers
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3100039/
https://www.ncbi.nlm.nih.gov/pubmed/21754245
http://dx.doi.org/10.1107/S1600536811010828
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author Shakuntala, K.
Foro, Sabine
Gowda, B. Thimme
author_facet Shakuntala, K.
Foro, Sabine
Gowda, B. Thimme
author_sort Shakuntala, K.
collection PubMed
description In the crystal structure of the title compound, C(12)H(9)Cl(2)NO(2)S, the N—C bond in the C—SO(2)—NH—C segment has gauche torsions with respect to the S=O bonds. The mol­ecule is twisted at the S atom with an C—SO(2)—NH—C torsion angle of 57.6 (3)°. The N—H bond is syn to the ortho-chloro group in the anilino benzene ring. The two benzene rings are tilted relative to each other by 84.7 (1)°. The crystal structure features inversion dimers linked by N—H⋯O(S) hydrogen bonds. An intra­molecular N—H⋯Cl hydrogen bond is also observed.
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spelling pubmed-31000392011-07-13 4-Chloro-N-(2-chloro­phen­yl)benzene­sulfonamide Shakuntala, K. Foro, Sabine Gowda, B. Thimme Acta Crystallogr Sect E Struct Rep Online Organic Papers In the crystal structure of the title compound, C(12)H(9)Cl(2)NO(2)S, the N—C bond in the C—SO(2)—NH—C segment has gauche torsions with respect to the S=O bonds. The mol­ecule is twisted at the S atom with an C—SO(2)—NH—C torsion angle of 57.6 (3)°. The N—H bond is syn to the ortho-chloro group in the anilino benzene ring. The two benzene rings are tilted relative to each other by 84.7 (1)°. The crystal structure features inversion dimers linked by N—H⋯O(S) hydrogen bonds. An intra­molecular N—H⋯Cl hydrogen bond is also observed. International Union of Crystallography 2011-03-26 /pmc/articles/PMC3100039/ /pubmed/21754245 http://dx.doi.org/10.1107/S1600536811010828 Text en © Shakuntala et al. 2011 http://creativecommons.org/licenses/by/2.0/uk/ This is an open-access article distributed under the terms of the Creative Commons Attribution Licence, which permits unrestricted use, distribution, and reproduction in any medium, provided the original authors and source are cited.
spellingShingle Organic Papers
Shakuntala, K.
Foro, Sabine
Gowda, B. Thimme
4-Chloro-N-(2-chloro­phen­yl)benzene­sulfonamide
title 4-Chloro-N-(2-chloro­phen­yl)benzene­sulfonamide
title_full 4-Chloro-N-(2-chloro­phen­yl)benzene­sulfonamide
title_fullStr 4-Chloro-N-(2-chloro­phen­yl)benzene­sulfonamide
title_full_unstemmed 4-Chloro-N-(2-chloro­phen­yl)benzene­sulfonamide
title_short 4-Chloro-N-(2-chloro­phen­yl)benzene­sulfonamide
title_sort 4-chloro-n-(2-chloro­phen­yl)benzene­sulfonamide
topic Organic Papers
url https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3100039/
https://www.ncbi.nlm.nih.gov/pubmed/21754245
http://dx.doi.org/10.1107/S1600536811010828
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AT forosabine 4chloron2chlorophenylbenzenesulfonamide
AT gowdabthimme 4chloron2chlorophenylbenzenesulfonamide

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