rac-2-tert-Butyl-2,4,5,6,6-penta­chloro­cyclo­hex-3-en-1-one

The title compound, C(10)H(11)Cl(5)O, is a chiral mol­ecule with two stereogenic centres. However, it crystallizes as a racemate. One of enanti­omers reveals the relative configuration (2S*,5R*). The cyclo­hexene ring adopts a half-chair conformation.

Detalles Bibliográficos
Autores principales: Maharramov, Abel M., Allahverdiyev, Mirza A., Mammadov, Elmar Y., Askerova, Ayten R., Rashidov, Bahruz A.
Formato: Texto
Lenguaje:English
Publicado: International Union of Crystallography 2011
Materias:
Organic Papers
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3100040/
https://www.ncbi.nlm.nih.gov/pubmed/21754158
http://dx.doi.org/10.1107/S160053681100897X
Descripción
Sumario:The title compound, C(10)H(11)Cl(5)O, is a chiral mol­ecule with two stereogenic centres. However, it crystallizes as a racemate. One of enanti­omers reveals the relative configuration (2S*,5R*). The cyclo­hexene ring adopts a half-chair conformation.

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