rac-2-tert-Butyl-2,4,5,6,6-penta­chloro­cyclo­hex-3-en-1-one

The title compound, C(10)H(11)Cl(5)O, is a chiral mol­ecule with two stereogenic centres. However, it crystallizes as a racemate. One of enanti­omers reveals the relative configuration (2S*,5R*). The cyclo­hexene ring adopts a half-chair conformation.

Detalles Bibliográficos
Autores principales: Maharramov, Abel M., Allahverdiyev, Mirza A., Mammadov, Elmar Y., Askerova, Ayten R., Rashidov, Bahruz A.
Formato: Texto
Lenguaje:English
Publicado: International Union of Crystallography 2011
Materias:
Organic Papers
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3100040/
https://www.ncbi.nlm.nih.gov/pubmed/21754158
http://dx.doi.org/10.1107/S160053681100897X
_version_ 1782204145019650048
author Maharramov, Abel M.
Allahverdiyev, Mirza A.
Mammadov, Elmar Y.
Askerova, Ayten R.
Rashidov, Bahruz A.
author_facet Maharramov, Abel M.
Allahverdiyev, Mirza A.
Mammadov, Elmar Y.
Askerova, Ayten R.
Rashidov, Bahruz A.
author_sort Maharramov, Abel M.
collection PubMed
description The title compound, C(10)H(11)Cl(5)O, is a chiral mol­ecule with two stereogenic centres. However, it crystallizes as a racemate. One of enanti­omers reveals the relative configuration (2S*,5R*). The cyclo­hexene ring adopts a half-chair conformation.
format Text
id pubmed-3100040
institution National Center for Biotechnology Information
language English
publishDate 2011
publisher International Union of Crystallography
record_format MEDLINE/PubMed
spelling pubmed-31000402011-07-13 rac-2-tert-Butyl-2,4,5,6,6-penta­chloro­cyclo­hex-3-en-1-one Maharramov, Abel M. Allahverdiyev, Mirza A. Mammadov, Elmar Y. Askerova, Ayten R. Rashidov, Bahruz A. Acta Crystallogr Sect E Struct Rep Online Organic Papers The title compound, C(10)H(11)Cl(5)O, is a chiral mol­ecule with two stereogenic centres. However, it crystallizes as a racemate. One of enanti­omers reveals the relative configuration (2S*,5R*). The cyclo­hexene ring adopts a half-chair conformation. International Union of Crystallography 2011-03-15 /pmc/articles/PMC3100040/ /pubmed/21754158 http://dx.doi.org/10.1107/S160053681100897X Text en © Maharramov et al. 2011 http://creativecommons.org/licenses/by/2.0/uk/ This is an open-access article distributed under the terms of the Creative Commons Attribution Licence, which permits unrestricted use, distribution, and reproduction in any medium, provided the original authors and source are cited.
spellingShingle Organic Papers
Maharramov, Abel M.
Allahverdiyev, Mirza A.
Mammadov, Elmar Y.
Askerova, Ayten R.
Rashidov, Bahruz A.
rac-2-tert-Butyl-2,4,5,6,6-penta­chloro­cyclo­hex-3-en-1-one
title rac-2-tert-Butyl-2,4,5,6,6-penta­chloro­cyclo­hex-3-en-1-one
title_full rac-2-tert-Butyl-2,4,5,6,6-penta­chloro­cyclo­hex-3-en-1-one
title_fullStr rac-2-tert-Butyl-2,4,5,6,6-penta­chloro­cyclo­hex-3-en-1-one
title_full_unstemmed rac-2-tert-Butyl-2,4,5,6,6-penta­chloro­cyclo­hex-3-en-1-one
title_short rac-2-tert-Butyl-2,4,5,6,6-penta­chloro­cyclo­hex-3-en-1-one
title_sort rac-2-tert-butyl-2,4,5,6,6-penta­chloro­cyclo­hex-3-en-1-one
topic Organic Papers
url https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3100040/
https://www.ncbi.nlm.nih.gov/pubmed/21754158
http://dx.doi.org/10.1107/S160053681100897X
work_keys_str_mv AT maharramovabelm rac2tertbutyl24566pentachlorocyclohex3en1one
AT allahverdiyevmirzaa rac2tertbutyl24566pentachlorocyclohex3en1one
AT mammadovelmary rac2tertbutyl24566pentachlorocyclohex3en1one
AT askerovaaytenr rac2tertbutyl24566pentachlorocyclohex3en1one
AT rashidovbahruza rac2tertbutyl24566pentachlorocyclohex3en1one

Ejemplares similares