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N (1),N (1)-Dimethyl­propane-1,2-diaminium bis­(6-carb­oxy­pyridine-2-carboxyl­ate) monohydrate

The asymmetric unit of the title proton-transfer compound, C(5)H(16)N(2) (2+)·2C(7)H(4)NO(4) (−)·H(2)O, consists of two mono-deproton­ated pyridine-2,6-dicarb­oxy­lic acid mol­ecules as anions, viz. (py-2,6-dcH)(−), one diprotonated N (1),N (1)-dimethyl­propane-1,2-diamine mol­ecule as a cation, viz...

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Autores principales: Aghabozorg, Hossein, Foroughian, Mahsa, Foroumadi, Alireza, Bruno, Giuseppe, Amiri Rudbari, Hadi
Formato: Texto
Lenguaje:English
Publicado: International Union of Crystallography 2011
Materias:
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3100043/
https://www.ncbi.nlm.nih.gov/pubmed/21754202
http://dx.doi.org/10.1107/S1600536811009287
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author Aghabozorg, Hossein
Foroughian, Mahsa
Foroumadi, Alireza
Bruno, Giuseppe
Amiri Rudbari, Hadi
author_facet Aghabozorg, Hossein
Foroughian, Mahsa
Foroumadi, Alireza
Bruno, Giuseppe
Amiri Rudbari, Hadi
author_sort Aghabozorg, Hossein
collection PubMed
description The asymmetric unit of the title proton-transfer compound, C(5)H(16)N(2) (2+)·2C(7)H(4)NO(4) (−)·H(2)O, consists of two mono-deproton­ated pyridine-2,6-dicarb­oxy­lic acid mol­ecules as anions, viz. (py-2,6-dcH)(−), one diprotonated N (1),N (1)-dimethyl­propane-1,2-diamine mol­ecule as a cation, viz. (dmpdaH(2))(2+), and one water mol­ecule. The crystal packing shows extensive O—H⋯O, N—H⋯O, N—H⋯N and O—H⋯N and weak inter­molecular C—H⋯O hydrogen bonds. These inter­actions link the (dmpdaH(2))(2+) cation, the (py-2,6-dcH)(−) anions and water mol­ecule and play an important role in the stabilization of crystal packing.
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spelling pubmed-31000432011-07-13 N (1),N (1)-Dimethyl­propane-1,2-diaminium bis­(6-carb­oxy­pyridine-2-carboxyl­ate) monohydrate Aghabozorg, Hossein Foroughian, Mahsa Foroumadi, Alireza Bruno, Giuseppe Amiri Rudbari, Hadi Acta Crystallogr Sect E Struct Rep Online Organic Papers The asymmetric unit of the title proton-transfer compound, C(5)H(16)N(2) (2+)·2C(7)H(4)NO(4) (−)·H(2)O, consists of two mono-deproton­ated pyridine-2,6-dicarb­oxy­lic acid mol­ecules as anions, viz. (py-2,6-dcH)(−), one diprotonated N (1),N (1)-dimethyl­propane-1,2-diamine mol­ecule as a cation, viz. (dmpdaH(2))(2+), and one water mol­ecule. The crystal packing shows extensive O—H⋯O, N—H⋯O, N—H⋯N and O—H⋯N and weak inter­molecular C—H⋯O hydrogen bonds. These inter­actions link the (dmpdaH(2))(2+) cation, the (py-2,6-dcH)(−) anions and water mol­ecule and play an important role in the stabilization of crystal packing. International Union of Crystallography 2011-03-19 /pmc/articles/PMC3100043/ /pubmed/21754202 http://dx.doi.org/10.1107/S1600536811009287 Text en © Aghabozorg et al. 2011 http://creativecommons.org/licenses/by/2.0/uk/ This is an open-access article distributed under the terms of the Creative Commons Attribution Licence, which permits unrestricted use, distribution, and reproduction in any medium, provided the original authors and source are cited.
spellingShingle Organic Papers
Aghabozorg, Hossein
Foroughian, Mahsa
Foroumadi, Alireza
Bruno, Giuseppe
Amiri Rudbari, Hadi
N (1),N (1)-Dimethyl­propane-1,2-diaminium bis­(6-carb­oxy­pyridine-2-carboxyl­ate) monohydrate
title N (1),N (1)-Dimethyl­propane-1,2-diaminium bis­(6-carb­oxy­pyridine-2-carboxyl­ate) monohydrate
title_full N (1),N (1)-Dimethyl­propane-1,2-diaminium bis­(6-carb­oxy­pyridine-2-carboxyl­ate) monohydrate
title_fullStr N (1),N (1)-Dimethyl­propane-1,2-diaminium bis­(6-carb­oxy­pyridine-2-carboxyl­ate) monohydrate
title_full_unstemmed N (1),N (1)-Dimethyl­propane-1,2-diaminium bis­(6-carb­oxy­pyridine-2-carboxyl­ate) monohydrate
title_short N (1),N (1)-Dimethyl­propane-1,2-diaminium bis­(6-carb­oxy­pyridine-2-carboxyl­ate) monohydrate
title_sort n (1),n (1)-dimethyl­propane-1,2-diaminium bis­(6-carb­oxy­pyridine-2-carboxyl­ate) monohydrate
topic Organic Papers
url https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3100043/
https://www.ncbi.nlm.nih.gov/pubmed/21754202
http://dx.doi.org/10.1107/S1600536811009287
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