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N (1),N (1)-Dimethylpropane-1,2-diaminium bis(6-carboxypyridine-2-carboxylate) monohydrate
The asymmetric unit of the title proton-transfer compound, C(5)H(16)N(2) (2+)·2C(7)H(4)NO(4) (−)·H(2)O, consists of two mono-deprotonated pyridine-2,6-dicarboxylic acid molecules as anions, viz. (py-2,6-dcH)(−), one diprotonated N (1),N (1)-dimethylpropane-1,2-diamine molecule as a cation, viz...
Autores principales: | , , , , |
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Formato: | Texto |
Lenguaje: | English |
Publicado: |
International Union of Crystallography
2011
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Materias: | |
Acceso en línea: | https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3100043/ https://www.ncbi.nlm.nih.gov/pubmed/21754202 http://dx.doi.org/10.1107/S1600536811009287 |
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author | Aghabozorg, Hossein Foroughian, Mahsa Foroumadi, Alireza Bruno, Giuseppe Amiri Rudbari, Hadi |
author_facet | Aghabozorg, Hossein Foroughian, Mahsa Foroumadi, Alireza Bruno, Giuseppe Amiri Rudbari, Hadi |
author_sort | Aghabozorg, Hossein |
collection | PubMed |
description | The asymmetric unit of the title proton-transfer compound, C(5)H(16)N(2) (2+)·2C(7)H(4)NO(4) (−)·H(2)O, consists of two mono-deprotonated pyridine-2,6-dicarboxylic acid molecules as anions, viz. (py-2,6-dcH)(−), one diprotonated N (1),N (1)-dimethylpropane-1,2-diamine molecule as a cation, viz. (dmpdaH(2))(2+), and one water molecule. The crystal packing shows extensive O—H⋯O, N—H⋯O, N—H⋯N and O—H⋯N and weak intermolecular C—H⋯O hydrogen bonds. These interactions link the (dmpdaH(2))(2+) cation, the (py-2,6-dcH)(−) anions and water molecule and play an important role in the stabilization of crystal packing. |
format | Text |
id | pubmed-3100043 |
institution | National Center for Biotechnology Information |
language | English |
publishDate | 2011 |
publisher | International Union of Crystallography |
record_format | MEDLINE/PubMed |
spelling | pubmed-31000432011-07-13 N (1),N (1)-Dimethylpropane-1,2-diaminium bis(6-carboxypyridine-2-carboxylate) monohydrate Aghabozorg, Hossein Foroughian, Mahsa Foroumadi, Alireza Bruno, Giuseppe Amiri Rudbari, Hadi Acta Crystallogr Sect E Struct Rep Online Organic Papers The asymmetric unit of the title proton-transfer compound, C(5)H(16)N(2) (2+)·2C(7)H(4)NO(4) (−)·H(2)O, consists of two mono-deprotonated pyridine-2,6-dicarboxylic acid molecules as anions, viz. (py-2,6-dcH)(−), one diprotonated N (1),N (1)-dimethylpropane-1,2-diamine molecule as a cation, viz. (dmpdaH(2))(2+), and one water molecule. The crystal packing shows extensive O—H⋯O, N—H⋯O, N—H⋯N and O—H⋯N and weak intermolecular C—H⋯O hydrogen bonds. These interactions link the (dmpdaH(2))(2+) cation, the (py-2,6-dcH)(−) anions and water molecule and play an important role in the stabilization of crystal packing. International Union of Crystallography 2011-03-19 /pmc/articles/PMC3100043/ /pubmed/21754202 http://dx.doi.org/10.1107/S1600536811009287 Text en © Aghabozorg et al. 2011 http://creativecommons.org/licenses/by/2.0/uk/ This is an open-access article distributed under the terms of the Creative Commons Attribution Licence, which permits unrestricted use, distribution, and reproduction in any medium, provided the original authors and source are cited. |
spellingShingle | Organic Papers Aghabozorg, Hossein Foroughian, Mahsa Foroumadi, Alireza Bruno, Giuseppe Amiri Rudbari, Hadi N (1),N (1)-Dimethylpropane-1,2-diaminium bis(6-carboxypyridine-2-carboxylate) monohydrate |
title |
N
(1),N
(1)-Dimethylpropane-1,2-diaminium bis(6-carboxypyridine-2-carboxylate) monohydrate |
title_full |
N
(1),N
(1)-Dimethylpropane-1,2-diaminium bis(6-carboxypyridine-2-carboxylate) monohydrate |
title_fullStr |
N
(1),N
(1)-Dimethylpropane-1,2-diaminium bis(6-carboxypyridine-2-carboxylate) monohydrate |
title_full_unstemmed |
N
(1),N
(1)-Dimethylpropane-1,2-diaminium bis(6-carboxypyridine-2-carboxylate) monohydrate |
title_short |
N
(1),N
(1)-Dimethylpropane-1,2-diaminium bis(6-carboxypyridine-2-carboxylate) monohydrate |
title_sort | n
(1),n
(1)-dimethylpropane-1,2-diaminium bis(6-carboxypyridine-2-carboxylate) monohydrate |
topic | Organic Papers |
url | https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3100043/ https://www.ncbi.nlm.nih.gov/pubmed/21754202 http://dx.doi.org/10.1107/S1600536811009287 |
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