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2-[N-(4-{4-[(E)-(2-Hydroxybenzylidene)amino]phenoxy}phenyl)carboximidoyl]phenol
The molecular structure of the title Schiff base compound, C(26)H(20)N(2)O(3), shows that respective methylidene residues are almost coplanar with the adjacent terminal benzene ring owing to the presence of intramolecular O—H⋯N hydrogen bonds [the N—C—C—C torsion angles are −6.6 (7) and −6.7 (7)°...
Autores principales: | , |
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Formato: | Texto |
Lenguaje: | English |
Publicado: |
International Union of Crystallography
2011
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Materias: | |
Acceso en línea: | https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3100046/ https://www.ncbi.nlm.nih.gov/pubmed/21754087 http://dx.doi.org/10.1107/S1600536811007847 |
Sumario: | The molecular structure of the title Schiff base compound, C(26)H(20)N(2)O(3), shows that respective methylidene residues are almost coplanar with the adjacent terminal benzene ring owing to the presence of intramolecular O—H⋯N hydrogen bonds [the N—C—C—C torsion angles are −6.6 (7) and −6.7 (7)°]. However, twists are exhibited about each methylidene and respective benzene ring connected to the central O atom; the dihedral angles formed between the two inner and two outer benzene rings are 54.6 (2) and 45.6 (3)°, respectively. The conformation about each of the C=N bonds [1.285 (5) and 1.295 (5) Å] is E. In the crystal, extensive C—H⋯π contacts involving all benzene rings results in the formation of layers in the ac plane. |
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