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2-[N-(4-{4-[(E)-(2-Hydroxybenzyl­idene)amino]phenoxy}phenyl)carbox­imidoyl]phenol

The mol­ecular structure of the title Schiff base compound, C(26)H(20)N(2)O(3), shows that respective methyl­idene residues are almost coplanar with the adjacent terminal benzene ring owing to the presence of intra­molecular O—H⋯N hydrogen bonds [the N—C—C—C torsion angles are −6.6 (7) and −6.7 (7)°...

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Detalles Bibliográficos
Autores principales: Shahverdizadeh, Gholam Hossein, Tiekink, Edward R. T.
Formato: Texto
Lenguaje:English
Publicado: International Union of Crystallography 2011
Materias:
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3100046/
https://www.ncbi.nlm.nih.gov/pubmed/21754087
http://dx.doi.org/10.1107/S1600536811007847
Descripción
Sumario:The mol­ecular structure of the title Schiff base compound, C(26)H(20)N(2)O(3), shows that respective methyl­idene residues are almost coplanar with the adjacent terminal benzene ring owing to the presence of intra­molecular O—H⋯N hydrogen bonds [the N—C—C—C torsion angles are −6.6 (7) and −6.7 (7)°]. However, twists are exhibited about each methyl­idene and respective benzene ring connected to the central O atom; the dihedral angles formed between the two inner and two outer benzene rings are 54.6 (2) and 45.6 (3)°, respectively. The conformation about each of the C=N bonds [1.285 (5) and 1.295 (5) Å] is E. In the crystal, extensive C—H⋯π contacts involving all benzene rings results in the formation of layers in the ac plane.