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2-[N-(4-{4-[(E)-(2-Hydroxybenzylidene)amino]phenoxy}phenyl)carboximidoyl]phenol
The molecular structure of the title Schiff base compound, C(26)H(20)N(2)O(3), shows that respective methylidene residues are almost coplanar with the adjacent terminal benzene ring owing to the presence of intramolecular O—H⋯N hydrogen bonds [the N—C—C—C torsion angles are −6.6 (7) and −6.7 (7)°...
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Formato: | Texto |
Lenguaje: | English |
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International Union of Crystallography
2011
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Acceso en línea: | https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3100046/ https://www.ncbi.nlm.nih.gov/pubmed/21754087 http://dx.doi.org/10.1107/S1600536811007847 |
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author | Shahverdizadeh, Gholam Hossein Tiekink, Edward R. T. |
author_facet | Shahverdizadeh, Gholam Hossein Tiekink, Edward R. T. |
author_sort | Shahverdizadeh, Gholam Hossein |
collection | PubMed |
description | The molecular structure of the title Schiff base compound, C(26)H(20)N(2)O(3), shows that respective methylidene residues are almost coplanar with the adjacent terminal benzene ring owing to the presence of intramolecular O—H⋯N hydrogen bonds [the N—C—C—C torsion angles are −6.6 (7) and −6.7 (7)°]. However, twists are exhibited about each methylidene and respective benzene ring connected to the central O atom; the dihedral angles formed between the two inner and two outer benzene rings are 54.6 (2) and 45.6 (3)°, respectively. The conformation about each of the C=N bonds [1.285 (5) and 1.295 (5) Å] is E. In the crystal, extensive C—H⋯π contacts involving all benzene rings results in the formation of layers in the ac plane. |
format | Text |
id | pubmed-3100046 |
institution | National Center for Biotechnology Information |
language | English |
publishDate | 2011 |
publisher | International Union of Crystallography |
record_format | MEDLINE/PubMed |
spelling | pubmed-31000462011-07-13 2-[N-(4-{4-[(E)-(2-Hydroxybenzylidene)amino]phenoxy}phenyl)carboximidoyl]phenol Shahverdizadeh, Gholam Hossein Tiekink, Edward R. T. Acta Crystallogr Sect E Struct Rep Online Organic Papers The molecular structure of the title Schiff base compound, C(26)H(20)N(2)O(3), shows that respective methylidene residues are almost coplanar with the adjacent terminal benzene ring owing to the presence of intramolecular O—H⋯N hydrogen bonds [the N—C—C—C torsion angles are −6.6 (7) and −6.7 (7)°]. However, twists are exhibited about each methylidene and respective benzene ring connected to the central O atom; the dihedral angles formed between the two inner and two outer benzene rings are 54.6 (2) and 45.6 (3)°, respectively. The conformation about each of the C=N bonds [1.285 (5) and 1.295 (5) Å] is E. In the crystal, extensive C—H⋯π contacts involving all benzene rings results in the formation of layers in the ac plane. International Union of Crystallography 2011-03-05 /pmc/articles/PMC3100046/ /pubmed/21754087 http://dx.doi.org/10.1107/S1600536811007847 Text en © Shahverdizadeh and Tiekink 2011 http://creativecommons.org/licenses/by/2.0/uk/ This is an open-access article distributed under the terms of the Creative Commons Attribution Licence, which permits unrestricted use, distribution, and reproduction in any medium, provided the original authors and source are cited. |
spellingShingle | Organic Papers Shahverdizadeh, Gholam Hossein Tiekink, Edward R. T. 2-[N-(4-{4-[(E)-(2-Hydroxybenzylidene)amino]phenoxy}phenyl)carboximidoyl]phenol |
title | 2-[N-(4-{4-[(E)-(2-Hydroxybenzylidene)amino]phenoxy}phenyl)carboximidoyl]phenol |
title_full | 2-[N-(4-{4-[(E)-(2-Hydroxybenzylidene)amino]phenoxy}phenyl)carboximidoyl]phenol |
title_fullStr | 2-[N-(4-{4-[(E)-(2-Hydroxybenzylidene)amino]phenoxy}phenyl)carboximidoyl]phenol |
title_full_unstemmed | 2-[N-(4-{4-[(E)-(2-Hydroxybenzylidene)amino]phenoxy}phenyl)carboximidoyl]phenol |
title_short | 2-[N-(4-{4-[(E)-(2-Hydroxybenzylidene)amino]phenoxy}phenyl)carboximidoyl]phenol |
title_sort | 2-[n-(4-{4-[(e)-(2-hydroxybenzylidene)amino]phenoxy}phenyl)carboximidoyl]phenol |
topic | Organic Papers |
url | https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3100046/ https://www.ncbi.nlm.nih.gov/pubmed/21754087 http://dx.doi.org/10.1107/S1600536811007847 |
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