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2-[N-(4-{4-[(E)-(2-Hydroxybenzyl­idene)amino]phenoxy}phenyl)carbox­imidoyl]phenol

The mol­ecular structure of the title Schiff base compound, C(26)H(20)N(2)O(3), shows that respective methyl­idene residues are almost coplanar with the adjacent terminal benzene ring owing to the presence of intra­molecular O—H⋯N hydrogen bonds [the N—C—C—C torsion angles are −6.6 (7) and −6.7 (7)°...

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Detalles Bibliográficos
Autores principales: Shahverdizadeh, Gholam Hossein, Tiekink, Edward R. T.
Formato: Texto
Lenguaje:English
Publicado: International Union of Crystallography 2011
Materias:
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3100046/
https://www.ncbi.nlm.nih.gov/pubmed/21754087
http://dx.doi.org/10.1107/S1600536811007847
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author Shahverdizadeh, Gholam Hossein
Tiekink, Edward R. T.
author_facet Shahverdizadeh, Gholam Hossein
Tiekink, Edward R. T.
author_sort Shahverdizadeh, Gholam Hossein
collection PubMed
description The mol­ecular structure of the title Schiff base compound, C(26)H(20)N(2)O(3), shows that respective methyl­idene residues are almost coplanar with the adjacent terminal benzene ring owing to the presence of intra­molecular O—H⋯N hydrogen bonds [the N—C—C—C torsion angles are −6.6 (7) and −6.7 (7)°]. However, twists are exhibited about each methyl­idene and respective benzene ring connected to the central O atom; the dihedral angles formed between the two inner and two outer benzene rings are 54.6 (2) and 45.6 (3)°, respectively. The conformation about each of the C=N bonds [1.285 (5) and 1.295 (5) Å] is E. In the crystal, extensive C—H⋯π contacts involving all benzene rings results in the formation of layers in the ac plane.
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spelling pubmed-31000462011-07-13 2-[N-(4-{4-[(E)-(2-Hydroxybenzyl­idene)amino]phenoxy}phenyl)carbox­imidoyl]phenol Shahverdizadeh, Gholam Hossein Tiekink, Edward R. T. Acta Crystallogr Sect E Struct Rep Online Organic Papers The mol­ecular structure of the title Schiff base compound, C(26)H(20)N(2)O(3), shows that respective methyl­idene residues are almost coplanar with the adjacent terminal benzene ring owing to the presence of intra­molecular O—H⋯N hydrogen bonds [the N—C—C—C torsion angles are −6.6 (7) and −6.7 (7)°]. However, twists are exhibited about each methyl­idene and respective benzene ring connected to the central O atom; the dihedral angles formed between the two inner and two outer benzene rings are 54.6 (2) and 45.6 (3)°, respectively. The conformation about each of the C=N bonds [1.285 (5) and 1.295 (5) Å] is E. In the crystal, extensive C—H⋯π contacts involving all benzene rings results in the formation of layers in the ac plane. International Union of Crystallography 2011-03-05 /pmc/articles/PMC3100046/ /pubmed/21754087 http://dx.doi.org/10.1107/S1600536811007847 Text en © Shahverdizadeh and Tiekink 2011 http://creativecommons.org/licenses/by/2.0/uk/ This is an open-access article distributed under the terms of the Creative Commons Attribution Licence, which permits unrestricted use, distribution, and reproduction in any medium, provided the original authors and source are cited.
spellingShingle Organic Papers
Shahverdizadeh, Gholam Hossein
Tiekink, Edward R. T.
2-[N-(4-{4-[(E)-(2-Hydroxybenzyl­idene)amino]phenoxy}phenyl)carbox­imidoyl]phenol
title 2-[N-(4-{4-[(E)-(2-Hydroxybenzyl­idene)amino]phenoxy}phenyl)carbox­imidoyl]phenol
title_full 2-[N-(4-{4-[(E)-(2-Hydroxybenzyl­idene)amino]phenoxy}phenyl)carbox­imidoyl]phenol
title_fullStr 2-[N-(4-{4-[(E)-(2-Hydroxybenzyl­idene)amino]phenoxy}phenyl)carbox­imidoyl]phenol
title_full_unstemmed 2-[N-(4-{4-[(E)-(2-Hydroxybenzyl­idene)amino]phenoxy}phenyl)carbox­imidoyl]phenol
title_short 2-[N-(4-{4-[(E)-(2-Hydroxybenzyl­idene)amino]phenoxy}phenyl)carbox­imidoyl]phenol
title_sort 2-[n-(4-{4-[(e)-(2-hydroxybenzyl­idene)amino]phenoxy}phenyl)carbox­imidoyl]phenol
topic Organic Papers
url https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3100046/
https://www.ncbi.nlm.nih.gov/pubmed/21754087
http://dx.doi.org/10.1107/S1600536811007847
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