Bis(2-amino­pyridinium) 5,5′-disulfanediylbis(1,3,4-thia­diazole-2-thiol­ate) monohydrate

In the crystal of the title compound, 2C(5)H(7)N(2) (+)·C(4)N(4)S(6) (2−)·H(2)O, inter­molecular N—H⋯S and N—H⋯N hydrogen bonds link four cations and two dianions into a centrosymmetric cluster. The crystal packing is further consolidated by π–π inter­actions between the five- and six-membered rings...

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Detalles Bibliográficos
Autores principales: Zhao, Pusu, Guo, Zhiyan, Xiao, Hailian
Formato: Texto
Lenguaje:English
Publicado: International Union of Crystallography 2011
Materias:
Organic Papers
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3100049/
https://www.ncbi.nlm.nih.gov/pubmed/21754119
http://dx.doi.org/10.1107/S1600536811008336
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author Zhao, Pusu
Guo, Zhiyan
Xiao, Hailian
author_facet Zhao, Pusu
Guo, Zhiyan
Xiao, Hailian
author_sort Zhao, Pusu
collection PubMed
description In the crystal of the title compound, 2C(5)H(7)N(2) (+)·C(4)N(4)S(6) (2−)·H(2)O, inter­molecular N—H⋯S and N—H⋯N hydrogen bonds link four cations and two dianions into a centrosymmetric cluster. The crystal packing is further consolidated by π–π inter­actions between the five- and six-membered rings of neighbouring clusters [centroid–centroid distances = 3.692 (3), 3.718 (3), 3.660 (3) and 3.696 (3) Å] and via O—H⋯N, O—H⋯S and N—H⋯O hydrogen bonds involving the uncoordinated water mol­ecules.
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spelling pubmed-31000492011-07-13 Bis(2-amino­pyridinium) 5,5′-disulfanediylbis(1,3,4-thia­diazole-2-thiol­ate) monohydrate Zhao, Pusu Guo, Zhiyan Xiao, Hailian Acta Crystallogr Sect E Struct Rep Online Organic Papers In the crystal of the title compound, 2C(5)H(7)N(2) (+)·C(4)N(4)S(6) (2−)·H(2)O, inter­molecular N—H⋯S and N—H⋯N hydrogen bonds link four cations and two dianions into a centrosymmetric cluster. The crystal packing is further consolidated by π–π inter­actions between the five- and six-membered rings of neighbouring clusters [centroid–centroid distances = 3.692 (3), 3.718 (3), 3.660 (3) and 3.696 (3) Å] and via O—H⋯N, O—H⋯S and N—H⋯O hydrogen bonds involving the uncoordinated water mol­ecules. International Union of Crystallography 2011-03-12 /pmc/articles/PMC3100049/ /pubmed/21754119 http://dx.doi.org/10.1107/S1600536811008336 Text en © Zhao et al. 2011 http://creativecommons.org/licenses/by/2.0/uk/ This is an open-access article distributed under the terms of the Creative Commons Attribution Licence, which permits unrestricted use, distribution, and reproduction in any medium, provided the original authors and source are cited.
spellingShingle Organic Papers
Zhao, Pusu
Guo, Zhiyan
Xiao, Hailian
Bis(2-amino­pyridinium) 5,5′-disulfanediylbis(1,3,4-thia­diazole-2-thiol­ate) monohydrate
title Bis(2-amino­pyridinium) 5,5′-disulfanediylbis(1,3,4-thia­diazole-2-thiol­ate) monohydrate
title_full Bis(2-amino­pyridinium) 5,5′-disulfanediylbis(1,3,4-thia­diazole-2-thiol­ate) monohydrate
title_fullStr Bis(2-amino­pyridinium) 5,5′-disulfanediylbis(1,3,4-thia­diazole-2-thiol­ate) monohydrate
title_full_unstemmed Bis(2-amino­pyridinium) 5,5′-disulfanediylbis(1,3,4-thia­diazole-2-thiol­ate) monohydrate
title_short Bis(2-amino­pyridinium) 5,5′-disulfanediylbis(1,3,4-thia­diazole-2-thiol­ate) monohydrate
title_sort bis(2-amino­pyridinium) 5,5′-disulfanediylbis(1,3,4-thia­diazole-2-thiol­ate) monohydrate
topic Organic Papers
url https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3100049/
https://www.ncbi.nlm.nih.gov/pubmed/21754119
http://dx.doi.org/10.1107/S1600536811008336
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AT guozhiyan bis2aminopyridinium55disulfanediylbis134thiadiazole2thiolatemonohydrate
AT xiaohailian bis2aminopyridinium55disulfanediylbis134thiadiazole2thiolatemonohydrate

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