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[N′-(3,5-Diiodo-2-oxidobenzylidene-κO)-4-methylbenzohydrazidato-κ(2) N′,O](methanol-κO)(methanolato-κO)oxidovanadium(V)
In the title molecule, [V(C(15)H(10)I(2)N(2)O(2))(CH(3)O)O(CH(3)OH)], the V(V) atom is coordinated by one N and two O atoms from an N′-(3,5-diiodo-2-oxidobenzylidene-κO)-4-methylbenzohydrazidate (L) ligand, one oxide O atom, one methanolate [V—O = 1.761 (3) Å] and one methanol [V—O = 2.383 (4)...
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Formato: | Texto |
Lenguaje: | English |
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International Union of Crystallography
2011
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Acceso en línea: | https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3100050/ https://www.ncbi.nlm.nih.gov/pubmed/21753994 http://dx.doi.org/10.1107/S1600536811010385 |
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author | Liu, Lin |
author_facet | Liu, Lin |
author_sort | Liu, Lin |
collection | PubMed |
description | In the title molecule, [V(C(15)H(10)I(2)N(2)O(2))(CH(3)O)O(CH(3)OH)], the V(V) atom is coordinated by one N and two O atoms from an N′-(3,5-diiodo-2-oxidobenzylidene-κO)-4-methylbenzohydrazidate (L) ligand, one oxide O atom, one methanolate [V—O = 1.761 (3) Å] and one methanol [V—O = 2.383 (4) Å] O atom in a distorted octahedral geometry. In the L ligand, the two benzene rings are nearly parallel, forming a dihedral angle of 2.0 (1)°. In the crystal, intermolecular O—H⋯N hydrogen bonds link pairs of molecules into centrosymmetric dimers which exhibit π–π interactions between the aromatic rings [centroid–centroid distance = 3.677 (5) Å]. |
format | Text |
id | pubmed-3100050 |
institution | National Center for Biotechnology Information |
language | English |
publishDate | 2011 |
publisher | International Union of Crystallography |
record_format | MEDLINE/PubMed |
spelling | pubmed-31000502011-07-13 [N′-(3,5-Diiodo-2-oxidobenzylidene-κO)-4-methylbenzohydrazidato-κ(2) N′,O](methanol-κO)(methanolato-κO)oxidovanadium(V) Liu, Lin Acta Crystallogr Sect E Struct Rep Online Metal-Organic Papers In the title molecule, [V(C(15)H(10)I(2)N(2)O(2))(CH(3)O)O(CH(3)OH)], the V(V) atom is coordinated by one N and two O atoms from an N′-(3,5-diiodo-2-oxidobenzylidene-κO)-4-methylbenzohydrazidate (L) ligand, one oxide O atom, one methanolate [V—O = 1.761 (3) Å] and one methanol [V—O = 2.383 (4) Å] O atom in a distorted octahedral geometry. In the L ligand, the two benzene rings are nearly parallel, forming a dihedral angle of 2.0 (1)°. In the crystal, intermolecular O—H⋯N hydrogen bonds link pairs of molecules into centrosymmetric dimers which exhibit π–π interactions between the aromatic rings [centroid–centroid distance = 3.677 (5) Å]. International Union of Crystallography 2011-03-26 /pmc/articles/PMC3100050/ /pubmed/21753994 http://dx.doi.org/10.1107/S1600536811010385 Text en © Lin Liu 2011 http://creativecommons.org/licenses/by/2.0/uk/ This is an open-access article distributed under the terms of the Creative Commons Attribution Licence, which permits unrestricted use, distribution, and reproduction in any medium, provided the original authors and source are cited. |
spellingShingle | Metal-Organic Papers Liu, Lin [N′-(3,5-Diiodo-2-oxidobenzylidene-κO)-4-methylbenzohydrazidato-κ(2) N′,O](methanol-κO)(methanolato-κO)oxidovanadium(V) |
title | [N′-(3,5-Diiodo-2-oxidobenzylidene-κO)-4-methylbenzohydrazidato-κ(2)
N′,O](methanol-κO)(methanolato-κO)oxidovanadium(V) |
title_full | [N′-(3,5-Diiodo-2-oxidobenzylidene-κO)-4-methylbenzohydrazidato-κ(2)
N′,O](methanol-κO)(methanolato-κO)oxidovanadium(V) |
title_fullStr | [N′-(3,5-Diiodo-2-oxidobenzylidene-κO)-4-methylbenzohydrazidato-κ(2)
N′,O](methanol-κO)(methanolato-κO)oxidovanadium(V) |
title_full_unstemmed | [N′-(3,5-Diiodo-2-oxidobenzylidene-κO)-4-methylbenzohydrazidato-κ(2)
N′,O](methanol-κO)(methanolato-κO)oxidovanadium(V) |
title_short | [N′-(3,5-Diiodo-2-oxidobenzylidene-κO)-4-methylbenzohydrazidato-κ(2)
N′,O](methanol-κO)(methanolato-κO)oxidovanadium(V) |
title_sort | [n′-(3,5-diiodo-2-oxidobenzylidene-κo)-4-methylbenzohydrazidato-κ(2)
n′,o](methanol-κo)(methanolato-κo)oxidovanadium(v) |
topic | Metal-Organic Papers |
url | https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3100050/ https://www.ncbi.nlm.nih.gov/pubmed/21753994 http://dx.doi.org/10.1107/S1600536811010385 |
work_keys_str_mv | AT liulin n35diiodo2oxidobenzylideneko4methylbenzohydrazidatok2nomethanolkomethanolatokooxidovanadiumv |