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[N′-(3,5-Diiodo-2-oxidobenzyl­idene-κO)-4-methyl­benzohydrazidato-κ(2) N′,O](methanol-κO)(methano­lato-κO)oxidovanadium(V)

In the title mol­ecule, [V(C(15)H(10)I(2)N(2)O(2))(CH(3)O)O(CH(3)OH)], the V(V) atom is coordinated by one N and two O atoms from an N′-(3,5-diiodo-2-oxidobenzyl­idene-κO)-4-methyl­benzo­hydra­zidate (L) ligand, one oxide O atom, one methano­late [V—O = 1.761 (3) Å] and one methanol [V—O = 2.383 (4)...

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Detalles Bibliográficos
Autor principal: Liu, Lin
Formato: Texto
Lenguaje:English
Publicado: International Union of Crystallography 2011
Materias:
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3100050/
https://www.ncbi.nlm.nih.gov/pubmed/21753994
http://dx.doi.org/10.1107/S1600536811010385
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author Liu, Lin
author_facet Liu, Lin
author_sort Liu, Lin
collection PubMed
description In the title mol­ecule, [V(C(15)H(10)I(2)N(2)O(2))(CH(3)O)O(CH(3)OH)], the V(V) atom is coordinated by one N and two O atoms from an N′-(3,5-diiodo-2-oxidobenzyl­idene-κO)-4-methyl­benzo­hydra­zidate (L) ligand, one oxide O atom, one methano­late [V—O = 1.761 (3) Å] and one methanol [V—O = 2.383 (4) Å] O atom in a distorted octa­hedral geometry. In the L ligand, the two benzene rings are nearly parallel, forming a dihedral angle of 2.0 (1)°. In the crystal, inter­molecular O—H⋯N hydrogen bonds link pairs of mol­ecules into centrosymmetric dimers which exhibit π–π inter­actions between the aromatic rings [centroid–centroid distance = 3.677 (5) Å].
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spelling pubmed-31000502011-07-13 [N′-(3,5-Diiodo-2-oxidobenzyl­idene-κO)-4-methyl­benzohydrazidato-κ(2) N′,O](methanol-κO)(methano­lato-κO)oxidovanadium(V) Liu, Lin Acta Crystallogr Sect E Struct Rep Online Metal-Organic Papers In the title mol­ecule, [V(C(15)H(10)I(2)N(2)O(2))(CH(3)O)O(CH(3)OH)], the V(V) atom is coordinated by one N and two O atoms from an N′-(3,5-diiodo-2-oxidobenzyl­idene-κO)-4-methyl­benzo­hydra­zidate (L) ligand, one oxide O atom, one methano­late [V—O = 1.761 (3) Å] and one methanol [V—O = 2.383 (4) Å] O atom in a distorted octa­hedral geometry. In the L ligand, the two benzene rings are nearly parallel, forming a dihedral angle of 2.0 (1)°. In the crystal, inter­molecular O—H⋯N hydrogen bonds link pairs of mol­ecules into centrosymmetric dimers which exhibit π–π inter­actions between the aromatic rings [centroid–centroid distance = 3.677 (5) Å]. International Union of Crystallography 2011-03-26 /pmc/articles/PMC3100050/ /pubmed/21753994 http://dx.doi.org/10.1107/S1600536811010385 Text en © Lin Liu 2011 http://creativecommons.org/licenses/by/2.0/uk/ This is an open-access article distributed under the terms of the Creative Commons Attribution Licence, which permits unrestricted use, distribution, and reproduction in any medium, provided the original authors and source are cited.
spellingShingle Metal-Organic Papers
Liu, Lin
[N′-(3,5-Diiodo-2-oxidobenzyl­idene-κO)-4-methyl­benzohydrazidato-κ(2) N′,O](methanol-κO)(methano­lato-κO)oxidovanadium(V)
title [N′-(3,5-Diiodo-2-oxidobenzyl­idene-κO)-4-methyl­benzohydrazidato-κ(2) N′,O](methanol-κO)(methano­lato-κO)oxidovanadium(V)
title_full [N′-(3,5-Diiodo-2-oxidobenzyl­idene-κO)-4-methyl­benzohydrazidato-κ(2) N′,O](methanol-κO)(methano­lato-κO)oxidovanadium(V)
title_fullStr [N′-(3,5-Diiodo-2-oxidobenzyl­idene-κO)-4-methyl­benzohydrazidato-κ(2) N′,O](methanol-κO)(methano­lato-κO)oxidovanadium(V)
title_full_unstemmed [N′-(3,5-Diiodo-2-oxidobenzyl­idene-κO)-4-methyl­benzohydrazidato-κ(2) N′,O](methanol-κO)(methano­lato-κO)oxidovanadium(V)
title_short [N′-(3,5-Diiodo-2-oxidobenzyl­idene-κO)-4-methyl­benzohydrazidato-κ(2) N′,O](methanol-κO)(methano­lato-κO)oxidovanadium(V)
title_sort [n′-(3,5-diiodo-2-oxidobenzyl­idene-κo)-4-methyl­benzohydrazidato-κ(2) n′,o](methanol-κo)(methano­lato-κo)oxidovanadium(v)
topic Metal-Organic Papers
url https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3100050/
https://www.ncbi.nlm.nih.gov/pubmed/21753994
http://dx.doi.org/10.1107/S1600536811010385
work_keys_str_mv AT liulin n35diiodo2oxidobenzylideneko4methylbenzohydrazidatok2nomethanolkomethanolatokooxidovanadiumv