3-[(E)-(4-Chloro­benzyl­idene)amino]-1-phenyl­thio­urea

In the title compound, C(14)H(12)ClN(3)S, the dihedral angle between the terminal benzene rings is 56.6 (2)°; the benzene rings lie to the same side of the mol­ecule. The major twist in the mol­ecule occurs around the C(ar)—N bond (ar is aromatic) [C—N—C—C = 49.9 (5)°]. The configuration about the N...

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Autores principales: Dzulkifli, Nur Nadia, Farina, Yang, Yamin, Bohari M., Baba, Ibrahim, Tiekink, Edward R. T.
Formato: Texto
Lenguaje:English
Publicado: International Union of Crystallography 2011
Materias:
Organic Papers
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3100056/
https://www.ncbi.nlm.nih.gov/pubmed/21754150
http://dx.doi.org/10.1107/S1600536811008920
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author Dzulkifli, Nur Nadia
Farina, Yang
Yamin, Bohari M.
Baba, Ibrahim
Tiekink, Edward R. T.
author_facet Dzulkifli, Nur Nadia
Farina, Yang
Yamin, Bohari M.
Baba, Ibrahim
Tiekink, Edward R. T.
author_sort Dzulkifli, Nur Nadia
collection PubMed
description In the title compound, C(14)H(12)ClN(3)S, the dihedral angle between the terminal benzene rings is 56.6 (2)°; the benzene rings lie to the same side of the mol­ecule. The major twist in the mol­ecule occurs around the C(ar)—N bond (ar is aromatic) [C—N—C—C = 49.9 (5)°]. The configuration about the N=C bond [1.271 (4) Å] is E. The amine H atoms lie on opposite sides of the mol­ecule with one forming an intra­molecular N—H⋯N(imine) hydrogen bond and an S(5) ring. In the crystal, centrosymmetric dimers are formed via {⋯HNC=S}(2) synthons.
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spelling pubmed-31000562011-07-13 3-[(E)-(4-Chloro­benzyl­idene)amino]-1-phenyl­thio­urea Dzulkifli, Nur Nadia Farina, Yang Yamin, Bohari M. Baba, Ibrahim Tiekink, Edward R. T. Acta Crystallogr Sect E Struct Rep Online Organic Papers In the title compound, C(14)H(12)ClN(3)S, the dihedral angle between the terminal benzene rings is 56.6 (2)°; the benzene rings lie to the same side of the mol­ecule. The major twist in the mol­ecule occurs around the C(ar)—N bond (ar is aromatic) [C—N—C—C = 49.9 (5)°]. The configuration about the N=C bond [1.271 (4) Å] is E. The amine H atoms lie on opposite sides of the mol­ecule with one forming an intra­molecular N—H⋯N(imine) hydrogen bond and an S(5) ring. In the crystal, centrosymmetric dimers are formed via {⋯HNC=S}(2) synthons. International Union of Crystallography 2011-03-12 /pmc/articles/PMC3100056/ /pubmed/21754150 http://dx.doi.org/10.1107/S1600536811008920 Text en © Dzulkifli et al. 2011 http://creativecommons.org/licenses/by/2.0/uk/ This is an open-access article distributed under the terms of the Creative Commons Attribution Licence, which permits unrestricted use, distribution, and reproduction in any medium, provided the original authors and source are cited.
spellingShingle Organic Papers
Dzulkifli, Nur Nadia
Farina, Yang
Yamin, Bohari M.
Baba, Ibrahim
Tiekink, Edward R. T.
3-[(E)-(4-Chloro­benzyl­idene)amino]-1-phenyl­thio­urea
title 3-[(E)-(4-Chloro­benzyl­idene)amino]-1-phenyl­thio­urea
title_full 3-[(E)-(4-Chloro­benzyl­idene)amino]-1-phenyl­thio­urea
title_fullStr 3-[(E)-(4-Chloro­benzyl­idene)amino]-1-phenyl­thio­urea
title_full_unstemmed 3-[(E)-(4-Chloro­benzyl­idene)amino]-1-phenyl­thio­urea
title_short 3-[(E)-(4-Chloro­benzyl­idene)amino]-1-phenyl­thio­urea
title_sort 3-[(e)-(4-chloro­benzyl­idene)amino]-1-phenyl­thio­urea
topic Organic Papers
url https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3100056/
https://www.ncbi.nlm.nih.gov/pubmed/21754150
http://dx.doi.org/10.1107/S1600536811008920
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