Bis(N,N,N-trimethyl­ethanaminium) bis­(1,4-tetra­selenido-κ(2) Se (1),Se (4))cadmate

The title compound, (EtMe(3)N)(2)[Cd(Se(4))(2)], which has been prepared by reaction of CdI(2), K(2)Se(4) and EtMe(3)NI in dimethyl­formamide, is the first example of a [Cd(Se(4))(2)](2−) anion stabilized by alkyl­ammonium counter-ions. The Cd atom in the complex [Cd(Se(4))(2)](2−) anion is tetra­he...

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Detalles Bibliográficos
Autores principales: Kim, Jaemyeong, Kim, Kang-Woo
Formato: Texto
Lenguaje:English
Publicado: International Union of Crystallography 2011
Materias:
Metal-Organic Papers
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3100066/
https://www.ncbi.nlm.nih.gov/pubmed/21753930
http://dx.doi.org/10.1107/S1600536811007227
Descripción
Sumario:The title compound, (EtMe(3)N)(2)[Cd(Se(4))(2)], which has been prepared by reaction of CdI(2), K(2)Se(4) and EtMe(3)NI in dimethyl­formamide, is the first example of a [Cd(Se(4))(2)](2−) anion stabilized by alkyl­ammonium counter-ions. The Cd atom in the complex [Cd(Se(4))(2)](2−) anion is tetra­hedrally coordinated by two chelating tetra­selenide ligands, and both CdSe(4) rings exhibit an envelope conformation.

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