Bis(N,N,N-trimethyl­ethanaminium) bis­(1,4-tetra­selenido-κ(2) Se (1),Se (4))cadmate

The title compound, (EtMe(3)N)(2)[Cd(Se(4))(2)], which has been prepared by reaction of CdI(2), K(2)Se(4) and EtMe(3)NI in dimethyl­formamide, is the first example of a [Cd(Se(4))(2)](2−) anion stabilized by alkyl­ammonium counter-ions. The Cd atom in the complex [Cd(Se(4))(2)](2−) anion is tetra­he...

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Detalles Bibliográficos
Autores principales: Kim, Jaemyeong, Kim, Kang-Woo
Formato: Texto
Lenguaje:English
Publicado: International Union of Crystallography 2011
Materias:
Metal-Organic Papers
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3100066/
https://www.ncbi.nlm.nih.gov/pubmed/21753930
http://dx.doi.org/10.1107/S1600536811007227
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author Kim, Jaemyeong
Kim, Kang-Woo
author_facet Kim, Jaemyeong
Kim, Kang-Woo
author_sort Kim, Jaemyeong
collection PubMed
description The title compound, (EtMe(3)N)(2)[Cd(Se(4))(2)], which has been prepared by reaction of CdI(2), K(2)Se(4) and EtMe(3)NI in dimethyl­formamide, is the first example of a [Cd(Se(4))(2)](2−) anion stabilized by alkyl­ammonium counter-ions. The Cd atom in the complex [Cd(Se(4))(2)](2−) anion is tetra­hedrally coordinated by two chelating tetra­selenide ligands, and both CdSe(4) rings exhibit an envelope conformation.
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spelling pubmed-31000662011-07-13 Bis(N,N,N-trimethyl­ethanaminium) bis­(1,4-tetra­selenido-κ(2) Se (1),Se (4))cadmate Kim, Jaemyeong Kim, Kang-Woo Acta Crystallogr Sect E Struct Rep Online Metal-Organic Papers The title compound, (EtMe(3)N)(2)[Cd(Se(4))(2)], which has been prepared by reaction of CdI(2), K(2)Se(4) and EtMe(3)NI in dimethyl­formamide, is the first example of a [Cd(Se(4))(2)](2−) anion stabilized by alkyl­ammonium counter-ions. The Cd atom in the complex [Cd(Se(4))(2)](2−) anion is tetra­hedrally coordinated by two chelating tetra­selenide ligands, and both CdSe(4) rings exhibit an envelope conformation. International Union of Crystallography 2011-03-02 /pmc/articles/PMC3100066/ /pubmed/21753930 http://dx.doi.org/10.1107/S1600536811007227 Text en © Kim and Kim 2011 http://creativecommons.org/licenses/by/2.0/uk/ This is an open-access article distributed under the terms of the Creative Commons Attribution Licence, which permits unrestricted use, distribution, and reproduction in any medium, provided the original authors and source are cited.
spellingShingle Metal-Organic Papers
Kim, Jaemyeong
Kim, Kang-Woo
Bis(N,N,N-trimethyl­ethanaminium) bis­(1,4-tetra­selenido-κ(2) Se (1),Se (4))cadmate
title Bis(N,N,N-trimethyl­ethanaminium) bis­(1,4-tetra­selenido-κ(2) Se (1),Se (4))cadmate
title_full Bis(N,N,N-trimethyl­ethanaminium) bis­(1,4-tetra­selenido-κ(2) Se (1),Se (4))cadmate
title_fullStr Bis(N,N,N-trimethyl­ethanaminium) bis­(1,4-tetra­selenido-κ(2) Se (1),Se (4))cadmate
title_full_unstemmed Bis(N,N,N-trimethyl­ethanaminium) bis­(1,4-tetra­selenido-κ(2) Se (1),Se (4))cadmate
title_short Bis(N,N,N-trimethyl­ethanaminium) bis­(1,4-tetra­selenido-κ(2) Se (1),Se (4))cadmate
title_sort bis(n,n,n-trimethyl­ethanaminium) bis­(1,4-tetra­selenido-κ(2) se (1),se (4))cadmate
topic Metal-Organic Papers
url https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3100066/
https://www.ncbi.nlm.nih.gov/pubmed/21753930
http://dx.doi.org/10.1107/S1600536811007227
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