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cis-Bis(2,2′-bipyrimidine-κ(2) N (1),N (1′))dibromidomanganese(II) nitro­methane monosolvate

The asymmetric unit of the title compound, [MnBr(2)(C(8)H(6)N(4))(2)]·CH(3)NO(2), contains one half of a neutral Mn(II) complex and one half of a nitro­methane solvent mol­ecule, the complete mol­ecules being generated by the application of twofold symmetry. In the complex, the Mn(II) ion has a dist...

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Detalles Bibliográficos
Autor principal: Ha, Kwang
Formato: Texto
Lenguaje:English
Publicado: International Union of Crystallography 2011
Materias:
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3100068/
https://www.ncbi.nlm.nih.gov/pubmed/21753988
http://dx.doi.org/10.1107/S1600536811010075
Descripción
Sumario:The asymmetric unit of the title compound, [MnBr(2)(C(8)H(6)N(4))(2)]·CH(3)NO(2), contains one half of a neutral Mn(II) complex and one half of a nitro­methane solvent mol­ecule, the complete mol­ecules being generated by the application of twofold symmetry. In the complex, the Mn(II) ion has a distorted cis-Br(2)N(4) octa­hedral coordination geometry defined by four N atoms of the two chelating 2,2′-bipyrimidine ligands and two Br(−) ions. There are intra- and inter­molecular C—H⋯Br and C—H⋯N contacts.