[4-Bromo-N-(pyridin-2-yl­methyl­idene)aniline-κ(2) N,N′]bis­(1,1,1,5,5,5-hexa­fluoro­pentane-2,4-dionato-κ(2) O,O′)nickel(II)

The title compound, [Ni(C(5)HF(6)O(2))(2)(C(12)H(9)BrN(2))], the Ni(II) atom exhibits a pseudo-octa­hedral coordination geometry. The structure packs through C—H⋯Br inter­actions, forming a hydrogen-bonded ladder. There are also strong hydrogen-bonding inter­actions between two of the O atoms of the...

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Detalles Bibliográficos
Autores principales: Harding, Phimphaka, Harding, David J., Soponrat, Nitisastr, Adams, Harry
Formato: Texto
Lenguaje:English
Publicado: International Union of Crystallography 2011
Materias:
Metal-Organic Papers
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3100069/
https://www.ncbi.nlm.nih.gov/pubmed/21753938
http://dx.doi.org/10.1107/S1600536811005599
Descripción
Sumario:The title compound, [Ni(C(5)HF(6)O(2))(2)(C(12)H(9)BrN(2))], the Ni(II) atom exhibits a pseudo-octa­hedral coordination geometry. The structure packs through C—H⋯Br inter­actions, forming a hydrogen-bonded ladder. There are also strong hydrogen-bonding inter­actions between two of the O atoms of the β-diketonate ligands and two H atoms on the pyridine ring of the Schiff base ligand.

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