catena-Poly[[tetra­aqua­[trans-1,2-bis­(4-pyrid­yl)ethene-κ(2) N:N′]nickel(II)] dinitrate]

In the title compound, {[Ni(C(12)H(10)N(2))(H(2)O)(4)](NO(3))(2)}(n), the Ni(II) ion, lying on a crystallographic inversion center, has a distorted octa­hedral coordination sphere comprising four water ligands and two N-atom donors from the trans-related 1,2-bis­(4-pyrid­yl)ethene ligands, which als...

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Detalles Bibliográficos
Autores principales: Hyun, Min Young, Kim, Pan-Gi, Kim, Cheal, Kim, Youngmee
Formato: Texto
Lenguaje:English
Publicado: International Union of Crystallography 2011
Materias:
Metal-Organic Papers
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3100072/
https://www.ncbi.nlm.nih.gov/pubmed/21753926
http://dx.doi.org/10.1107/S1600536811007021
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author Hyun, Min Young
Kim, Pan-Gi
Kim, Cheal
Kim, Youngmee
author_facet Hyun, Min Young
Kim, Pan-Gi
Kim, Cheal
Kim, Youngmee
author_sort Hyun, Min Young
collection PubMed
description In the title compound, {[Ni(C(12)H(10)N(2))(H(2)O)(4)](NO(3))(2)}(n), the Ni(II) ion, lying on a crystallographic inversion center, has a distorted octa­hedral coordination sphere comprising four water ligands and two N-atom donors from the trans-related 1,2-bis­(4-pyrid­yl)ethene ligands, which also have crystallographic inversion symmetry. These ligands bridge the Ni(II) complex units, forming chains extending along the [110] and [[Image: see text]10] directions. The nitrate counter-anions stabilize the crystal structure through water–nitrate O—H⋯O hydrogen bonds.
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spelling pubmed-31000722011-07-13 catena-Poly[[tetra­aqua­[trans-1,2-bis­(4-pyrid­yl)ethene-κ(2) N:N′]nickel(II)] dinitrate] Hyun, Min Young Kim, Pan-Gi Kim, Cheal Kim, Youngmee Acta Crystallogr Sect E Struct Rep Online Metal-Organic Papers In the title compound, {[Ni(C(12)H(10)N(2))(H(2)O)(4)](NO(3))(2)}(n), the Ni(II) ion, lying on a crystallographic inversion center, has a distorted octa­hedral coordination sphere comprising four water ligands and two N-atom donors from the trans-related 1,2-bis­(4-pyrid­yl)ethene ligands, which also have crystallographic inversion symmetry. These ligands bridge the Ni(II) complex units, forming chains extending along the [110] and [[Image: see text]10] directions. The nitrate counter-anions stabilize the crystal structure through water–nitrate O—H⋯O hydrogen bonds. International Union of Crystallography 2011-03-02 /pmc/articles/PMC3100072/ /pubmed/21753926 http://dx.doi.org/10.1107/S1600536811007021 Text en © Hyun et al. 2011 http://creativecommons.org/licenses/by/2.0/uk/ This is an open-access article distributed under the terms of the Creative Commons Attribution Licence, which permits unrestricted use, distribution, and reproduction in any medium, provided the original authors and source are cited.
spellingShingle Metal-Organic Papers
Hyun, Min Young
Kim, Pan-Gi
Kim, Cheal
Kim, Youngmee
catena-Poly[[tetra­aqua­[trans-1,2-bis­(4-pyrid­yl)ethene-κ(2) N:N′]nickel(II)] dinitrate]
title catena-Poly[[tetra­aqua­[trans-1,2-bis­(4-pyrid­yl)ethene-κ(2) N:N′]nickel(II)] dinitrate]
title_full catena-Poly[[tetra­aqua­[trans-1,2-bis­(4-pyrid­yl)ethene-κ(2) N:N′]nickel(II)] dinitrate]
title_fullStr catena-Poly[[tetra­aqua­[trans-1,2-bis­(4-pyrid­yl)ethene-κ(2) N:N′]nickel(II)] dinitrate]
title_full_unstemmed catena-Poly[[tetra­aqua­[trans-1,2-bis­(4-pyrid­yl)ethene-κ(2) N:N′]nickel(II)] dinitrate]
title_short catena-Poly[[tetra­aqua­[trans-1,2-bis­(4-pyrid­yl)ethene-κ(2) N:N′]nickel(II)] dinitrate]
title_sort catena-poly[[tetra­aqua­[trans-1,2-bis­(4-pyrid­yl)ethene-κ(2) n:n′]nickel(ii)] dinitrate]
topic Metal-Organic Papers
url https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3100072/
https://www.ncbi.nlm.nih.gov/pubmed/21753926
http://dx.doi.org/10.1107/S1600536811007021
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AT kimcheal catenapolytetraaquatrans12bis4pyridylethenek2nnnickeliidinitrate
AT kimyoungmee catenapolytetraaquatrans12bis4pyridylethenek2nnnickeliidinitrate

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