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(E)-6-Bromo-3-{2-[2-(2-chloro­benzyl­idene)hydrazin­yl]thia­zol-5-yl}-2H-chromen-2-one dimethyl sulfoxide monosolvate

In the title compound C(19)H(11)N(3)O(2)SClBr·C(2)H(6)OS, the mol­ecule adopts an E configuration about the central C=N double bond. The chromene ring system and the thia­zole ring are approximately planar, with maximum deviations of 0.027 (2) and 0.003 (1) Å, respectively. The central thia­zole rin...

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Autores principales: Arshad, Afsheen, Osman, Hasnah, Lam, Chan Kit, Hemamalini, Madhukar, Fun, Hoong-Kun
Formato: Texto
Lenguaje:English
Publicado: International Union of Crystallography 2011
Materias:
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3100073/
https://www.ncbi.nlm.nih.gov/pubmed/21754028
http://dx.doi.org/10.1107/S1600536811011160
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author Arshad, Afsheen
Osman, Hasnah
Lam, Chan Kit
Hemamalini, Madhukar
Fun, Hoong-Kun
author_facet Arshad, Afsheen
Osman, Hasnah
Lam, Chan Kit
Hemamalini, Madhukar
Fun, Hoong-Kun
author_sort Arshad, Afsheen
collection PubMed
description In the title compound C(19)H(11)N(3)O(2)SClBr·C(2)H(6)OS, the mol­ecule adopts an E configuration about the central C=N double bond. The chromene ring system and the thia­zole ring are approximately planar, with maximum deviations of 0.027 (2) and 0.003 (1) Å, respectively. The central thia­zole ring makes dihedral angles of 21.82 (9) and 5.88 (7)° with the chloro-substituted phenyl ring and the chromene ring, respectively. In the crystal, mol­ecules are connected via N—H⋯O, N—H⋯S and C—H⋯O hydrogen bonds, forming supra­molecular chains along the c axis. An intra­molecular C—H⋯O hydrogen bond occurs. π–π inter­actions are observed between the thia­zole and phenyl rings [centroid–centroid distance = 3.6293 (10) Å]. A short Br⋯Cl contact of 3.37 (6) Å also occurs.
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spelling pubmed-31000732011-07-13 (E)-6-Bromo-3-{2-[2-(2-chloro­benzyl­idene)hydrazin­yl]thia­zol-5-yl}-2H-chromen-2-one dimethyl sulfoxide monosolvate Arshad, Afsheen Osman, Hasnah Lam, Chan Kit Hemamalini, Madhukar Fun, Hoong-Kun Acta Crystallogr Sect E Struct Rep Online Organic Papers In the title compound C(19)H(11)N(3)O(2)SClBr·C(2)H(6)OS, the mol­ecule adopts an E configuration about the central C=N double bond. The chromene ring system and the thia­zole ring are approximately planar, with maximum deviations of 0.027 (2) and 0.003 (1) Å, respectively. The central thia­zole ring makes dihedral angles of 21.82 (9) and 5.88 (7)° with the chloro-substituted phenyl ring and the chromene ring, respectively. In the crystal, mol­ecules are connected via N—H⋯O, N—H⋯S and C—H⋯O hydrogen bonds, forming supra­molecular chains along the c axis. An intra­molecular C—H⋯O hydrogen bond occurs. π–π inter­actions are observed between the thia­zole and phenyl rings [centroid–centroid distance = 3.6293 (10) Å]. A short Br⋯Cl contact of 3.37 (6) Å also occurs. International Union of Crystallography 2011-03-31 /pmc/articles/PMC3100073/ /pubmed/21754028 http://dx.doi.org/10.1107/S1600536811011160 Text en © Arshad et al. 2011 http://creativecommons.org/licenses/by/2.0/uk/ This is an open-access article distributed under the terms of the Creative Commons Attribution Licence, which permits unrestricted use, distribution, and reproduction in any medium, provided the original authors and source are cited.
spellingShingle Organic Papers
Arshad, Afsheen
Osman, Hasnah
Lam, Chan Kit
Hemamalini, Madhukar
Fun, Hoong-Kun
(E)-6-Bromo-3-{2-[2-(2-chloro­benzyl­idene)hydrazin­yl]thia­zol-5-yl}-2H-chromen-2-one dimethyl sulfoxide monosolvate
title (E)-6-Bromo-3-{2-[2-(2-chloro­benzyl­idene)hydrazin­yl]thia­zol-5-yl}-2H-chromen-2-one dimethyl sulfoxide monosolvate
title_full (E)-6-Bromo-3-{2-[2-(2-chloro­benzyl­idene)hydrazin­yl]thia­zol-5-yl}-2H-chromen-2-one dimethyl sulfoxide monosolvate
title_fullStr (E)-6-Bromo-3-{2-[2-(2-chloro­benzyl­idene)hydrazin­yl]thia­zol-5-yl}-2H-chromen-2-one dimethyl sulfoxide monosolvate
title_full_unstemmed (E)-6-Bromo-3-{2-[2-(2-chloro­benzyl­idene)hydrazin­yl]thia­zol-5-yl}-2H-chromen-2-one dimethyl sulfoxide monosolvate
title_short (E)-6-Bromo-3-{2-[2-(2-chloro­benzyl­idene)hydrazin­yl]thia­zol-5-yl}-2H-chromen-2-one dimethyl sulfoxide monosolvate
title_sort (e)-6-bromo-3-{2-[2-(2-chloro­benzyl­idene)hydrazin­yl]thia­zol-5-yl}-2h-chromen-2-one dimethyl sulfoxide monosolvate
topic Organic Papers
url https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3100073/
https://www.ncbi.nlm.nih.gov/pubmed/21754028
http://dx.doi.org/10.1107/S1600536811011160
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