(S)-4-(2-Chloro­propan-2-yl)-1-(2,2,2-trichloro­eth­yl)cyclo­hexene

The title compound, C(11)H(16)Cl(4), was synthesized by the reaction of (1S)-β-pinene with triethyl­amine in the presence of ZnCl(2). The cyclo­hexene ring assumes a half-boat conformation. The crystal packing is governed only by van der Waals inter­actions. The structure, which has been refined in...

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Detalles Bibliográficos
Autores principales: Boualy, Brahim, Harrad, Mohamed Anoir, Firdoussi, Larbi El, Ali, Mustapha Ait, Rizzoli, Corrado
Formato: Texto
Lenguaje:English
Publicado: International Union of Crystallography 2011
Materias:
Organic Papers
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3100074/
https://www.ncbi.nlm.nih.gov/pubmed/21754224
http://dx.doi.org/10.1107/S1600536811010257
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author Boualy, Brahim
Harrad, Mohamed Anoir
Firdoussi, Larbi El
Ali, Mustapha Ait
Rizzoli, Corrado
author_facet Boualy, Brahim
Harrad, Mohamed Anoir
Firdoussi, Larbi El
Ali, Mustapha Ait
Rizzoli, Corrado
author_sort Boualy, Brahim
collection PubMed
description The title compound, C(11)H(16)Cl(4), was synthesized by the reaction of (1S)-β-pinene with triethyl­amine in the presence of ZnCl(2). The cyclo­hexene ring assumes a half-boat conformation. The crystal packing is governed only by van der Waals inter­actions. The structure, which has been refined in P2(1), presents a striking P2(1)/m pseudosymmetry.
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spelling pubmed-31000742011-07-13 (S)-4-(2-Chloro­propan-2-yl)-1-(2,2,2-trichloro­eth­yl)cyclo­hexene Boualy, Brahim Harrad, Mohamed Anoir Firdoussi, Larbi El Ali, Mustapha Ait Rizzoli, Corrado Acta Crystallogr Sect E Struct Rep Online Organic Papers The title compound, C(11)H(16)Cl(4), was synthesized by the reaction of (1S)-β-pinene with triethyl­amine in the presence of ZnCl(2). The cyclo­hexene ring assumes a half-boat conformation. The crystal packing is governed only by van der Waals inter­actions. The structure, which has been refined in P2(1), presents a striking P2(1)/m pseudosymmetry. International Union of Crystallography 2011-03-23 /pmc/articles/PMC3100074/ /pubmed/21754224 http://dx.doi.org/10.1107/S1600536811010257 Text en © Boualy et al. 2011 http://creativecommons.org/licenses/by/2.0/uk/ This is an open-access article distributed under the terms of the Creative Commons Attribution Licence, which permits unrestricted use, distribution, and reproduction in any medium, provided the original authors and source are cited.
spellingShingle Organic Papers
Boualy, Brahim
Harrad, Mohamed Anoir
Firdoussi, Larbi El
Ali, Mustapha Ait
Rizzoli, Corrado
(S)-4-(2-Chloro­propan-2-yl)-1-(2,2,2-trichloro­eth­yl)cyclo­hexene
title (S)-4-(2-Chloro­propan-2-yl)-1-(2,2,2-trichloro­eth­yl)cyclo­hexene
title_full (S)-4-(2-Chloro­propan-2-yl)-1-(2,2,2-trichloro­eth­yl)cyclo­hexene
title_fullStr (S)-4-(2-Chloro­propan-2-yl)-1-(2,2,2-trichloro­eth­yl)cyclo­hexene
title_full_unstemmed (S)-4-(2-Chloro­propan-2-yl)-1-(2,2,2-trichloro­eth­yl)cyclo­hexene
title_short (S)-4-(2-Chloro­propan-2-yl)-1-(2,2,2-trichloro­eth­yl)cyclo­hexene
title_sort (s)-4-(2-chloro­propan-2-yl)-1-(2,2,2-trichloro­eth­yl)cyclo­hexene
topic Organic Papers
url https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3100074/
https://www.ncbi.nlm.nih.gov/pubmed/21754224
http://dx.doi.org/10.1107/S1600536811010257
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AT alimustaphaait s42chloropropan2yl1222trichloroethylcyclohexene
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