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A novel planar optical sensor for simultaneous monitoring of oxygen, carbon dioxide, pH and temperature

The first quadruple luminescent sensor is presented which enables simultaneous detection of three chemical parameters and temperature. A multi-layer material is realized and combines two spectrally independent dually sensing systems. The first layer employs ethylcellulose containing the carbon dioxi...

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Autores principales: Borisov, Sergey M., Seifner, Roman, Klimant, Ingo
Formato: Texto
Lenguaje:English
Publicado: Springer-Verlag 2011
Materias:
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3100504/
https://www.ncbi.nlm.nih.gov/pubmed/21221543
http://dx.doi.org/10.1007/s00216-010-4617-4
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author Borisov, Sergey M.
Seifner, Roman
Klimant, Ingo
author_facet Borisov, Sergey M.
Seifner, Roman
Klimant, Ingo
author_sort Borisov, Sergey M.
collection PubMed
description The first quadruple luminescent sensor is presented which enables simultaneous detection of three chemical parameters and temperature. A multi-layer material is realized and combines two spectrally independent dually sensing systems. The first layer employs ethylcellulose containing the carbon dioxide sensing chemistry (fluorescent pH indicator 8-hydroxy-pyrene-1,3,6-trisulfonate (HPTS) and a lipophilic tetraalkylammonium base). The cross-linked polymeric beads stained with a phosphorescent iridium(III) complex are also dispersed in ethylcellulose and serve both for oxygen sensing and as a reference for HPTS. The second (pH/temperature) dually sensing system relies on the use of a pH-sensitive lipophilic seminaphthorhodafluor derivative and luminescent chromium(III)-activated yttrium aluminum borate particles (simultaneously acting as a temperature probe and as a reference for the pH indicator) which are embedded in polyurethane hydrogel layer. A silicone layer is used to spatially separate both dually sensing systems and to insure permeation selectivity for the CO(2)/O(2) layer. The CO(2)/O(2) and the pH/temperature layers are excitable with a blue and a red LED, respectively, and the emissions are isolated with help of optical filters. The measurements are performed at two modulation frequencies for each sensing system and the modified Dual Lifetime Referencing method is used to access the analytical information. The feasibility of the simultaneous four-parameter sensing is demonstrated. However, the practical applicability of the material may be compromised by its high complexity and by the performance of individual indicators. [Figure: see text]
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spelling pubmed-31005042011-07-14 A novel planar optical sensor for simultaneous monitoring of oxygen, carbon dioxide, pH and temperature Borisov, Sergey M. Seifner, Roman Klimant, Ingo Anal Bioanal Chem Original Paper The first quadruple luminescent sensor is presented which enables simultaneous detection of three chemical parameters and temperature. A multi-layer material is realized and combines two spectrally independent dually sensing systems. The first layer employs ethylcellulose containing the carbon dioxide sensing chemistry (fluorescent pH indicator 8-hydroxy-pyrene-1,3,6-trisulfonate (HPTS) and a lipophilic tetraalkylammonium base). The cross-linked polymeric beads stained with a phosphorescent iridium(III) complex are also dispersed in ethylcellulose and serve both for oxygen sensing and as a reference for HPTS. The second (pH/temperature) dually sensing system relies on the use of a pH-sensitive lipophilic seminaphthorhodafluor derivative and luminescent chromium(III)-activated yttrium aluminum borate particles (simultaneously acting as a temperature probe and as a reference for the pH indicator) which are embedded in polyurethane hydrogel layer. A silicone layer is used to spatially separate both dually sensing systems and to insure permeation selectivity for the CO(2)/O(2) layer. The CO(2)/O(2) and the pH/temperature layers are excitable with a blue and a red LED, respectively, and the emissions are isolated with help of optical filters. The measurements are performed at two modulation frequencies for each sensing system and the modified Dual Lifetime Referencing method is used to access the analytical information. The feasibility of the simultaneous four-parameter sensing is demonstrated. However, the practical applicability of the material may be compromised by its high complexity and by the performance of individual indicators. [Figure: see text] Springer-Verlag 2011-01-09 2011 /pmc/articles/PMC3100504/ /pubmed/21221543 http://dx.doi.org/10.1007/s00216-010-4617-4 Text en © The Author(s) 2011 https://creativecommons.org/licenses/by-nc/4.0/This article is distributed under the terms of the Creative Commons Attribution Noncommercial License which permits any noncommercial use, distribution, and reproduction in any medium, provided the original author(s) and source are credited.
spellingShingle Original Paper
Borisov, Sergey M.
Seifner, Roman
Klimant, Ingo
A novel planar optical sensor for simultaneous monitoring of oxygen, carbon dioxide, pH and temperature
title A novel planar optical sensor for simultaneous monitoring of oxygen, carbon dioxide, pH and temperature
title_full A novel planar optical sensor for simultaneous monitoring of oxygen, carbon dioxide, pH and temperature
title_fullStr A novel planar optical sensor for simultaneous monitoring of oxygen, carbon dioxide, pH and temperature
title_full_unstemmed A novel planar optical sensor for simultaneous monitoring of oxygen, carbon dioxide, pH and temperature
title_short A novel planar optical sensor for simultaneous monitoring of oxygen, carbon dioxide, pH and temperature
title_sort novel planar optical sensor for simultaneous monitoring of oxygen, carbon dioxide, ph and temperature
topic Original Paper
url https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3100504/
https://www.ncbi.nlm.nih.gov/pubmed/21221543
http://dx.doi.org/10.1007/s00216-010-4617-4
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