Sequential Au(I)-catalyzed reaction of water with o-acetylenyl-substituted phenyldiazoacetates

The gold(I)-catalyzed reaction of water with o-acetylenyl-substituted phenyldiazoacetates provides 1H-isochromene derivatives in good yields. The reaction follows a catalytic sequence of gold carbene formation/water O–H insertion/alcohol-alkyne cyclization. The gold(I) complex is the only catalyst i...

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Detalles Bibliográficos
Autores principales: Zhou, Lei, Liu, Yizhou, Zhang, Yan, Wang, Jianbo
Formato: Online Artículo Texto
Lenguaje:English
Publicado: Beilstein-Institut 2011
Materias:
Full Research Paper
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3107481/
https://www.ncbi.nlm.nih.gov/pubmed/21647254
http://dx.doi.org/10.3762/bjoc.7.74
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author Zhou, Lei
Liu, Yizhou
Zhang, Yan
Wang, Jianbo
author_facet Zhou, Lei
Liu, Yizhou
Zhang, Yan
Wang, Jianbo
author_sort Zhou, Lei
collection PubMed
description The gold(I)-catalyzed reaction of water with o-acetylenyl-substituted phenyldiazoacetates provides 1H-isochromene derivatives in good yields. The reaction follows a catalytic sequence of gold carbene formation/water O–H insertion/alcohol-alkyne cyclization. The gold(I) complex is the only catalyst in each of these steps.
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spelling pubmed-31074812011-06-06 Sequential Au(I)-catalyzed reaction of water with o-acetylenyl-substituted phenyldiazoacetates Zhou, Lei Liu, Yizhou Zhang, Yan Wang, Jianbo Beilstein J Org Chem Full Research Paper The gold(I)-catalyzed reaction of water with o-acetylenyl-substituted phenyldiazoacetates provides 1H-isochromene derivatives in good yields. The reaction follows a catalytic sequence of gold carbene formation/water O–H insertion/alcohol-alkyne cyclization. The gold(I) complex is the only catalyst in each of these steps. Beilstein-Institut 2011-05-18 /pmc/articles/PMC3107481/ /pubmed/21647254 http://dx.doi.org/10.3762/bjoc.7.74 Text en Copyright © 2011, Zhou et al. https://creativecommons.org/licenses/by/2.0https://www.beilstein-journals.org/bjoc/termsThis is an Open Access article under the terms of the Creative Commons Attribution License (https://creativecommons.org/licenses/by/2.0), which permits unrestricted use, distribution, and reproduction in any medium, provided the original work is properly cited. The license is subject to the Beilstein Journal of Organic Chemistry terms and conditions: (https://www.beilstein-journals.org/bjoc/terms)
spellingShingle Full Research Paper
Zhou, Lei
Liu, Yizhou
Zhang, Yan
Wang, Jianbo
Sequential Au(I)-catalyzed reaction of water with o-acetylenyl-substituted phenyldiazoacetates
title Sequential Au(I)-catalyzed reaction of water with o-acetylenyl-substituted phenyldiazoacetates
title_full Sequential Au(I)-catalyzed reaction of water with o-acetylenyl-substituted phenyldiazoacetates
title_fullStr Sequential Au(I)-catalyzed reaction of water with o-acetylenyl-substituted phenyldiazoacetates
title_full_unstemmed Sequential Au(I)-catalyzed reaction of water with o-acetylenyl-substituted phenyldiazoacetates
title_short Sequential Au(I)-catalyzed reaction of water with o-acetylenyl-substituted phenyldiazoacetates
title_sort sequential au(i)-catalyzed reaction of water with o-acetylenyl-substituted phenyldiazoacetates
topic Full Research Paper
url https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3107481/
https://www.ncbi.nlm.nih.gov/pubmed/21647254
http://dx.doi.org/10.3762/bjoc.7.74
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