Sequential Au(I)-catalyzed reaction of water with o-acetylenyl-substituted phenyldiazoacetates

The gold(I)-catalyzed reaction of water with o-acetylenyl-substituted phenyldiazoacetates provides 1H-isochromene derivatives in good yields. The reaction follows a catalytic sequence of gold carbene formation/water O–H insertion/alcohol-alkyne cyclization. The gold(I) complex is the only catalyst i...

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Detalles Bibliográficos
Autores principales: Zhou, Lei, Liu, Yizhou, Zhang, Yan, Wang, Jianbo
Formato: Online Artículo Texto
Lenguaje:English
Publicado: Beilstein-Institut 2011
Materias:
Full Research Paper
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3107481/
https://www.ncbi.nlm.nih.gov/pubmed/21647254
http://dx.doi.org/10.3762/bjoc.7.74

Internet

https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3107481/
https://www.ncbi.nlm.nih.gov/pubmed/21647254
http://dx.doi.org/10.3762/bjoc.7.74

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