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Kinetic evaluation of the solvolysis of isobutyl chloro- and chlorothioformate esters
The specific rates of solvolysis of isobutyl chloroformate (1) are reported at 40.0 °C and those for isobutyl chlorothioformate (2) are reported at 25.0 °C, in a variety of pure and binary aqueous organic mixtures with wide ranging nucleophilicity and ionizing power. For 1, we also report the first-...
Autores principales: | D’Souza, Malcolm J, McAneny, Matthew J, Kevill, Dennis N, Kyong, Jin Burm, Choi, Song Hee |
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Formato: | Online Artículo Texto |
Lenguaje: | English |
Publicado: |
Beilstein-Institut
2011
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Materias: | |
Acceso en línea: | https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3107482/ https://www.ncbi.nlm.nih.gov/pubmed/21647255 http://dx.doi.org/10.3762/bjoc.7.62 |
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