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A Study of Solvent Effects in the Solvolysis of Propargyl Chloroformate

The specific rates of solvolysis of propargyl chloroformate (1) are analyzed in 22 solvents of widely varying nucleophilicity and ionizing power values at 25.0°C using the extended Grunwald-Winstein equation. Sensitivities to solvent nucleophilicity (l) of 1.37 and to solvent ionizing power (m) of 0...

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Detalles Bibliográficos
Autores principales:	D'Souza, Malcolm J., Darrington, Anthony M., Kevill, Dennis N.
Formato:	Online Artículo Texto
Lenguaje:	English
Publicado:	International Scholarly Research Network 2011
Materias:	Research Article
Acceso en línea:	https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3111911/ https://www.ncbi.nlm.nih.gov/pubmed/21666878 http://dx.doi.org/10.5402/2011/767141

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