Cargando…

Synthesis, Characterization, Crystal Structure, and Biological Studies of a Cadmium(II) Complex with a Tridentate Ligand 4′-Chloro-2,2′:6′,2′′-Terpyridine

A new Cd(II) complex with the ligand 4′-chloro-2,2′6′,2′′-terpyridine (Cltpy), [Cd(Cltpy)(I)(2)], has been synthesized and characterized by CHN elemental analysis, (1)H-NMR, (13)C-NMR, and IR spectroscopy and structurally analyzed by X-ray single-crystal diffraction. The single-crystal X-ray analyse...

Descripción completa

Detalles Bibliográficos
Autores principales: Saghatforoush, L. A., Valencia, L., Chalabian, F., Ghammamy, Sh.
Formato: Online Artículo Texto
Lenguaje:English
Publicado: Hindawi Publishing Corporation 2011
Materias:
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3119424/
https://www.ncbi.nlm.nih.gov/pubmed/21738495
http://dx.doi.org/10.1155/2011/803292
_version_ 1782206570538467328
author Saghatforoush, L. A.
Valencia, L.
Chalabian, F.
Ghammamy, Sh.
author_facet Saghatforoush, L. A.
Valencia, L.
Chalabian, F.
Ghammamy, Sh.
author_sort Saghatforoush, L. A.
collection PubMed
description A new Cd(II) complex with the ligand 4′-chloro-2,2′6′,2′′-terpyridine (Cltpy), [Cd(Cltpy)(I)(2)], has been synthesized and characterized by CHN elemental analysis, (1)H-NMR, (13)C-NMR, and IR spectroscopy and structurally analyzed by X-ray single-crystal diffraction. The single-crystal X-ray analyses show that the coordination number in complex is five with three terpyridine (Cltpy) N-donor atoms and two iodine atoms. The antibacterial activities of Cltpy and its Cd(II) complex are tested against different bacteria.
format Online
Article
Text
id pubmed-3119424
institution National Center for Biotechnology Information
language English
publishDate 2011
publisher Hindawi Publishing Corporation
record_format MEDLINE/PubMed
spelling pubmed-31194242011-07-07 Synthesis, Characterization, Crystal Structure, and Biological Studies of a Cadmium(II) Complex with a Tridentate Ligand 4′-Chloro-2,2′:6′,2′′-Terpyridine Saghatforoush, L. A. Valencia, L. Chalabian, F. Ghammamy, Sh. Bioinorg Chem Appl Research Article A new Cd(II) complex with the ligand 4′-chloro-2,2′6′,2′′-terpyridine (Cltpy), [Cd(Cltpy)(I)(2)], has been synthesized and characterized by CHN elemental analysis, (1)H-NMR, (13)C-NMR, and IR spectroscopy and structurally analyzed by X-ray single-crystal diffraction. The single-crystal X-ray analyses show that the coordination number in complex is five with three terpyridine (Cltpy) N-donor atoms and two iodine atoms. The antibacterial activities of Cltpy and its Cd(II) complex are tested against different bacteria. Hindawi Publishing Corporation 2011 2011-05-25 /pmc/articles/PMC3119424/ /pubmed/21738495 http://dx.doi.org/10.1155/2011/803292 Text en Copyright © 2011 L. A. Saghatforoush et al. https://creativecommons.org/licenses/by/3.0/ This is an open access article distributed under the Creative Commons Attribution License, which permits unrestricted use, distribution, and reproduction in any medium, provided the original work is properly cited.
spellingShingle Research Article
Saghatforoush, L. A.
Valencia, L.
Chalabian, F.
Ghammamy, Sh.
Synthesis, Characterization, Crystal Structure, and Biological Studies of a Cadmium(II) Complex with a Tridentate Ligand 4′-Chloro-2,2′:6′,2′′-Terpyridine
title Synthesis, Characterization, Crystal Structure, and Biological Studies of a Cadmium(II) Complex with a Tridentate Ligand 4′-Chloro-2,2′:6′,2′′-Terpyridine
title_full Synthesis, Characterization, Crystal Structure, and Biological Studies of a Cadmium(II) Complex with a Tridentate Ligand 4′-Chloro-2,2′:6′,2′′-Terpyridine
title_fullStr Synthesis, Characterization, Crystal Structure, and Biological Studies of a Cadmium(II) Complex with a Tridentate Ligand 4′-Chloro-2,2′:6′,2′′-Terpyridine
title_full_unstemmed Synthesis, Characterization, Crystal Structure, and Biological Studies of a Cadmium(II) Complex with a Tridentate Ligand 4′-Chloro-2,2′:6′,2′′-Terpyridine
title_short Synthesis, Characterization, Crystal Structure, and Biological Studies of a Cadmium(II) Complex with a Tridentate Ligand 4′-Chloro-2,2′:6′,2′′-Terpyridine
title_sort synthesis, characterization, crystal structure, and biological studies of a cadmium(ii) complex with a tridentate ligand 4′-chloro-2,2′:6′,2′′-terpyridine
topic Research Article
url https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3119424/
https://www.ncbi.nlm.nih.gov/pubmed/21738495
http://dx.doi.org/10.1155/2011/803292
work_keys_str_mv AT saghatforoushla synthesischaracterizationcrystalstructureandbiologicalstudiesofacadmiumiicomplexwithatridentateligand4chloro2262terpyridine
AT valencial synthesischaracterizationcrystalstructureandbiologicalstudiesofacadmiumiicomplexwithatridentateligand4chloro2262terpyridine
AT chalabianf synthesischaracterizationcrystalstructureandbiologicalstudiesofacadmiumiicomplexwithatridentateligand4chloro2262terpyridine
AT ghammamysh synthesischaracterizationcrystalstructureandbiologicalstudiesofacadmiumiicomplexwithatridentateligand4chloro2262terpyridine