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Poly[diimidazole-μ(4)-oxalato-μ(2)-oxalato-dicopper(II)]
The title compound, [Cu(2)(C(2)O(4))(2)(C(3)H(4)N(2))(2)](n), was obtained as an unexpected product under hydrothermal conditions. The Cu(II) atom is in a Jahn–Teller-distorted octahedral environment formed by one imidazole N atom and five O atoms from three oxalate anions. The two independent oxa...
Autores principales: | , |
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Formato: | Online Artículo Texto |
Lenguaje: | English |
Publicado: |
International Union of Crystallography
2011
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Materias: | |
Acceso en línea: | https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3120292/ https://www.ncbi.nlm.nih.gov/pubmed/21754588 http://dx.doi.org/10.1107/S1600536811015777 |
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author | Jin, Zhu-Nian Lin, Hong |
author_facet | Jin, Zhu-Nian Lin, Hong |
author_sort | Jin, Zhu-Nian |
collection | PubMed |
description | The title compound, [Cu(2)(C(2)O(4))(2)(C(3)H(4)N(2))(2)](n), was obtained as an unexpected product under hydrothermal conditions. The Cu(II) atom is in a Jahn–Teller-distorted octahedral environment formed by one imidazole N atom and five O atoms from three oxalate anions. The two independent oxalate anions are situated on centres of inversion and coordinate to the Cu(II) atom in two different modes, viz. bidentate and monodentate. The bidentate anions bridge two Cu(II) atoms, whereas the monodentate anions bridge four Cu(II) atoms, leading to a layered arrangement parallel to (100). These layers are further linked into a final three-dimensional network structure via intermolecular N—H⋯O hydrogen bonds. The title compound is isotypic with the Zn analogue. |
format | Online Article Text |
id | pubmed-3120292 |
institution | National Center for Biotechnology Information |
language | English |
publishDate | 2011 |
publisher | International Union of Crystallography |
record_format | MEDLINE/PubMed |
spelling | pubmed-31202922011-07-13 Poly[diimidazole-μ(4)-oxalato-μ(2)-oxalato-dicopper(II)] Jin, Zhu-Nian Lin, Hong Acta Crystallogr Sect E Struct Rep Online Metal-Organic Papers The title compound, [Cu(2)(C(2)O(4))(2)(C(3)H(4)N(2))(2)](n), was obtained as an unexpected product under hydrothermal conditions. The Cu(II) atom is in a Jahn–Teller-distorted octahedral environment formed by one imidazole N atom and five O atoms from three oxalate anions. The two independent oxalate anions are situated on centres of inversion and coordinate to the Cu(II) atom in two different modes, viz. bidentate and monodentate. The bidentate anions bridge two Cu(II) atoms, whereas the monodentate anions bridge four Cu(II) atoms, leading to a layered arrangement parallel to (100). These layers are further linked into a final three-dimensional network structure via intermolecular N—H⋯O hydrogen bonds. The title compound is isotypic with the Zn analogue. International Union of Crystallography 2011-05-07 /pmc/articles/PMC3120292/ /pubmed/21754588 http://dx.doi.org/10.1107/S1600536811015777 Text en © Jin and Lin 2011 http://creativecommons.org/licenses/by/2.0/uk/ This is an open-access article distributed under the terms of the Creative Commons Attribution Licence, which permits unrestricted use, distribution, and reproduction in any medium, provided the original authors and source are cited. |
spellingShingle | Metal-Organic Papers Jin, Zhu-Nian Lin, Hong Poly[diimidazole-μ(4)-oxalato-μ(2)-oxalato-dicopper(II)] |
title | Poly[diimidazole-μ(4)-oxalato-μ(2)-oxalato-dicopper(II)] |
title_full | Poly[diimidazole-μ(4)-oxalato-μ(2)-oxalato-dicopper(II)] |
title_fullStr | Poly[diimidazole-μ(4)-oxalato-μ(2)-oxalato-dicopper(II)] |
title_full_unstemmed | Poly[diimidazole-μ(4)-oxalato-μ(2)-oxalato-dicopper(II)] |
title_short | Poly[diimidazole-μ(4)-oxalato-μ(2)-oxalato-dicopper(II)] |
title_sort | poly[diimidazole-μ(4)-oxalato-μ(2)-oxalato-dicopper(ii)] |
topic | Metal-Organic Papers |
url | https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3120292/ https://www.ncbi.nlm.nih.gov/pubmed/21754588 http://dx.doi.org/10.1107/S1600536811015777 |
work_keys_str_mv | AT jinzhunian polydiimidazolem4oxalatom2oxalatodicopperii AT linhong polydiimidazolem4oxalatom2oxalatodicopperii |