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Poly[diimidazole-μ(4)-oxalato-μ(2)-oxalato-dicopper(II)]

The title compound, [Cu(2)(C(2)O(4))(2)(C(3)H(4)N(2))(2)](n), was obtained as an unexpected product under hydro­thermal conditions. The Cu(II) atom is in a Jahn–Teller-distorted octa­hedral environment formed by one imidazole N atom and five O atoms from three oxalate anions. The two independent oxa...

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Detalles Bibliográficos
Autores principales: Jin, Zhu-Nian, Lin, Hong
Formato: Online Artículo Texto
Lenguaje:English
Publicado: International Union of Crystallography 2011
Materias:
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3120292/
https://www.ncbi.nlm.nih.gov/pubmed/21754588
http://dx.doi.org/10.1107/S1600536811015777
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author Jin, Zhu-Nian
Lin, Hong
author_facet Jin, Zhu-Nian
Lin, Hong
author_sort Jin, Zhu-Nian
collection PubMed
description The title compound, [Cu(2)(C(2)O(4))(2)(C(3)H(4)N(2))(2)](n), was obtained as an unexpected product under hydro­thermal conditions. The Cu(II) atom is in a Jahn–Teller-distorted octa­hedral environment formed by one imidazole N atom and five O atoms from three oxalate anions. The two independent oxalate anions are situated on centres of inversion and coordinate to the Cu(II) atom in two different modes, viz. bidentate and monodentate. The bidentate anions bridge two Cu(II) atoms, whereas the monodentate anions bridge four Cu(II) atoms, leading to a layered arrangement parallel to (100). These layers are further linked into a final three-dimensional network structure via inter­molecular N—H⋯O hydrogen bonds. The title compound is isotypic with the Zn analogue.
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spelling pubmed-31202922011-07-13 Poly[diimidazole-μ(4)-oxalato-μ(2)-oxalato-dicopper(II)] Jin, Zhu-Nian Lin, Hong Acta Crystallogr Sect E Struct Rep Online Metal-Organic Papers The title compound, [Cu(2)(C(2)O(4))(2)(C(3)H(4)N(2))(2)](n), was obtained as an unexpected product under hydro­thermal conditions. The Cu(II) atom is in a Jahn–Teller-distorted octa­hedral environment formed by one imidazole N atom and five O atoms from three oxalate anions. The two independent oxalate anions are situated on centres of inversion and coordinate to the Cu(II) atom in two different modes, viz. bidentate and monodentate. The bidentate anions bridge two Cu(II) atoms, whereas the monodentate anions bridge four Cu(II) atoms, leading to a layered arrangement parallel to (100). These layers are further linked into a final three-dimensional network structure via inter­molecular N—H⋯O hydrogen bonds. The title compound is isotypic with the Zn analogue. International Union of Crystallography 2011-05-07 /pmc/articles/PMC3120292/ /pubmed/21754588 http://dx.doi.org/10.1107/S1600536811015777 Text en © Jin and Lin 2011 http://creativecommons.org/licenses/by/2.0/uk/ This is an open-access article distributed under the terms of the Creative Commons Attribution Licence, which permits unrestricted use, distribution, and reproduction in any medium, provided the original authors and source are cited.
spellingShingle Metal-Organic Papers
Jin, Zhu-Nian
Lin, Hong
Poly[diimidazole-μ(4)-oxalato-μ(2)-oxalato-dicopper(II)]
title Poly[diimidazole-μ(4)-oxalato-μ(2)-oxalato-dicopper(II)]
title_full Poly[diimidazole-μ(4)-oxalato-μ(2)-oxalato-dicopper(II)]
title_fullStr Poly[diimidazole-μ(4)-oxalato-μ(2)-oxalato-dicopper(II)]
title_full_unstemmed Poly[diimidazole-μ(4)-oxalato-μ(2)-oxalato-dicopper(II)]
title_short Poly[diimidazole-μ(4)-oxalato-μ(2)-oxalato-dicopper(II)]
title_sort poly[diimidazole-μ(4)-oxalato-μ(2)-oxalato-dicopper(ii)]
topic Metal-Organic Papers
url https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3120292/
https://www.ncbi.nlm.nih.gov/pubmed/21754588
http://dx.doi.org/10.1107/S1600536811015777
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