(3aR,6S,7aR)-7a-Bromo-2-methyl­sulfonyl-1,2,3,6,7,7a-hexa­hydro-3a,6-ep­oxy­isoindole

In the title compound, C(9)H(12)BrNO(3)S, the two tetra­hydro­furan rings adopt envelope conformations, the pyrrolidine ring adopts a half-chair conformation and the six-membered ring is in a boat conformation. In the crystal, weak inter­molecular C—H⋯O hydrogen bonds link the mol­ecules into R (2)...

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Autores principales: Temel, Ersin, Demircan, Aydın, Arslan, Hakan, Büyükgüngör, Orhan
Formato: Online Artículo Texto
Lenguaje:English
Publicado: International Union of Crystallography 2011
Materias:
Organic Papers
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3120297/
https://www.ncbi.nlm.nih.gov/pubmed/21754707
http://dx.doi.org/10.1107/S1600536811015959
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author Temel, Ersin
Demircan, Aydın
Arslan, Hakan
Büyükgüngör, Orhan
author_facet Temel, Ersin
Demircan, Aydın
Arslan, Hakan
Büyükgüngör, Orhan
author_sort Temel, Ersin
collection PubMed
description In the title compound, C(9)H(12)BrNO(3)S, the two tetra­hydro­furan rings adopt envelope conformations, the pyrrolidine ring adopts a half-chair conformation and the six-membered ring is in a boat conformation. In the crystal, weak inter­molecular C—H⋯O hydrogen bonds link the mol­ecules into R (2) (2)(8) and R (2) (2)(14) rings along the b-axis direction.
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spelling pubmed-31202972011-07-13 (3aR,6S,7aR)-7a-Bromo-2-methyl­sulfonyl-1,2,3,6,7,7a-hexa­hydro-3a,6-ep­oxy­isoindole Temel, Ersin Demircan, Aydın Arslan, Hakan Büyükgüngör, Orhan Acta Crystallogr Sect E Struct Rep Online Organic Papers In the title compound, C(9)H(12)BrNO(3)S, the two tetra­hydro­furan rings adopt envelope conformations, the pyrrolidine ring adopts a half-chair conformation and the six-membered ring is in a boat conformation. In the crystal, weak inter­molecular C—H⋯O hydrogen bonds link the mol­ecules into R (2) (2)(8) and R (2) (2)(14) rings along the b-axis direction. International Union of Crystallography 2011-05-07 /pmc/articles/PMC3120297/ /pubmed/21754707 http://dx.doi.org/10.1107/S1600536811015959 Text en © Temel et al. 2011 http://creativecommons.org/licenses/by/2.0/uk/ This is an open-access article distributed under the terms of the Creative Commons Attribution Licence, which permits unrestricted use, distribution, and reproduction in any medium, provided the original authors and source are cited.
spellingShingle Organic Papers
Temel, Ersin
Demircan, Aydın
Arslan, Hakan
Büyükgüngör, Orhan
(3aR,6S,7aR)-7a-Bromo-2-methyl­sulfonyl-1,2,3,6,7,7a-hexa­hydro-3a,6-ep­oxy­isoindole
title (3aR,6S,7aR)-7a-Bromo-2-methyl­sulfonyl-1,2,3,6,7,7a-hexa­hydro-3a,6-ep­oxy­isoindole
title_full (3aR,6S,7aR)-7a-Bromo-2-methyl­sulfonyl-1,2,3,6,7,7a-hexa­hydro-3a,6-ep­oxy­isoindole
title_fullStr (3aR,6S,7aR)-7a-Bromo-2-methyl­sulfonyl-1,2,3,6,7,7a-hexa­hydro-3a,6-ep­oxy­isoindole
title_full_unstemmed (3aR,6S,7aR)-7a-Bromo-2-methyl­sulfonyl-1,2,3,6,7,7a-hexa­hydro-3a,6-ep­oxy­isoindole
title_short (3aR,6S,7aR)-7a-Bromo-2-methyl­sulfonyl-1,2,3,6,7,7a-hexa­hydro-3a,6-ep­oxy­isoindole
title_sort (3ar,6s,7ar)-7a-bromo-2-methyl­sulfonyl-1,2,3,6,7,7a-hexa­hydro-3a,6-ep­oxy­isoindole
topic Organic Papers
url https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3120297/
https://www.ncbi.nlm.nih.gov/pubmed/21754707
http://dx.doi.org/10.1107/S1600536811015959
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