Cargando…

Chlorido(1H-imidazole-κN (3))bis­(triphenyl­phosphane-κP)copper(I)

In the title complex, [CuCl(C(3)H(4)N(2))(C(18)H(15)P)(2)], the coordination geometry around Cu(I) is distorted tetra­hedral formed by two triphenyl­phosphane ligands, an imidazole ligand and a chloride group. An intra­molecular C—H⋯Cl inter­action occurs. The crystal packing is stabilized by inter­...

Descripción completa

Detalles Bibliográficos
Autores principales: Hossaini Sadr, Moayad, Kia, Reza, Soltani, Behzad
Formato: Online Artículo Texto
Lenguaje:English
Publicado: International Union of Crystallography 2011
Materias:
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3120300/
https://www.ncbi.nlm.nih.gov/pubmed/21754651
http://dx.doi.org/10.1107/S1600536811017752
_version_ 1782206647968464896
author Hossaini Sadr, Moayad
Kia, Reza
Soltani, Behzad
author_facet Hossaini Sadr, Moayad
Kia, Reza
Soltani, Behzad
author_sort Hossaini Sadr, Moayad
collection PubMed
description In the title complex, [CuCl(C(3)H(4)N(2))(C(18)H(15)P)(2)], the coordination geometry around Cu(I) is distorted tetra­hedral formed by two triphenyl­phosphane ligands, an imidazole ligand and a chloride group. An intra­molecular C—H⋯Cl inter­action occurs. The crystal packing is stabilized by inter­molecular N—H⋯Cl hydrogen bonds, which form an extended chain parallel to [010].
format Online
Article
Text
id pubmed-3120300
institution National Center for Biotechnology Information
language English
publishDate 2011
publisher International Union of Crystallography
record_format MEDLINE/PubMed
spelling pubmed-31203002011-07-13 Chlorido(1H-imidazole-κN (3))bis­(triphenyl­phosphane-κP)copper(I) Hossaini Sadr, Moayad Kia, Reza Soltani, Behzad Acta Crystallogr Sect E Struct Rep Online Metal-Organic Papers In the title complex, [CuCl(C(3)H(4)N(2))(C(18)H(15)P)(2)], the coordination geometry around Cu(I) is distorted tetra­hedral formed by two triphenyl­phosphane ligands, an imidazole ligand and a chloride group. An intra­molecular C—H⋯Cl inter­action occurs. The crystal packing is stabilized by inter­molecular N—H⋯Cl hydrogen bonds, which form an extended chain parallel to [010]. International Union of Crystallography 2011-05-20 /pmc/articles/PMC3120300/ /pubmed/21754651 http://dx.doi.org/10.1107/S1600536811017752 Text en © Hossaini Sadr et al. 2011 http://creativecommons.org/licenses/by/2.0/uk/ This is an open-access article distributed under the terms of the Creative Commons Attribution Licence, which permits unrestricted use, distribution, and reproduction in any medium, provided the original authors and source are cited.
spellingShingle Metal-Organic Papers
Hossaini Sadr, Moayad
Kia, Reza
Soltani, Behzad
Chlorido(1H-imidazole-κN (3))bis­(triphenyl­phosphane-κP)copper(I)
title Chlorido(1H-imidazole-κN (3))bis­(triphenyl­phosphane-κP)copper(I)
title_full Chlorido(1H-imidazole-κN (3))bis­(triphenyl­phosphane-κP)copper(I)
title_fullStr Chlorido(1H-imidazole-κN (3))bis­(triphenyl­phosphane-κP)copper(I)
title_full_unstemmed Chlorido(1H-imidazole-κN (3))bis­(triphenyl­phosphane-κP)copper(I)
title_short Chlorido(1H-imidazole-κN (3))bis­(triphenyl­phosphane-κP)copper(I)
title_sort chlorido(1h-imidazole-κn (3))bis­(triphenyl­phosphane-κp)copper(i)
topic Metal-Organic Papers
url https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3120300/
https://www.ncbi.nlm.nih.gov/pubmed/21754651
http://dx.doi.org/10.1107/S1600536811017752
work_keys_str_mv AT hossainisadrmoayad chlorido1himidazolekn3bistriphenylphosphanekpcopperi
AT kiareza chlorido1himidazolekn3bistriphenylphosphanekpcopperi
AT soltanibehzad chlorido1himidazolekn3bistriphenylphosphanekpcopperi