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Chlorido(1H-imidazole-κN (3))bis(triphenylphosphane-κP)copper(I)
In the title complex, [CuCl(C(3)H(4)N(2))(C(18)H(15)P)(2)], the coordination geometry around Cu(I) is distorted tetrahedral formed by two triphenylphosphane ligands, an imidazole ligand and a chloride group. An intramolecular C—H⋯Cl interaction occurs. The crystal packing is stabilized by inter...
Autores principales: | , , |
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Formato: | Online Artículo Texto |
Lenguaje: | English |
Publicado: |
International Union of Crystallography
2011
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Materias: | |
Acceso en línea: | https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3120300/ https://www.ncbi.nlm.nih.gov/pubmed/21754651 http://dx.doi.org/10.1107/S1600536811017752 |
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author | Hossaini Sadr, Moayad Kia, Reza Soltani, Behzad |
author_facet | Hossaini Sadr, Moayad Kia, Reza Soltani, Behzad |
author_sort | Hossaini Sadr, Moayad |
collection | PubMed |
description | In the title complex, [CuCl(C(3)H(4)N(2))(C(18)H(15)P)(2)], the coordination geometry around Cu(I) is distorted tetrahedral formed by two triphenylphosphane ligands, an imidazole ligand and a chloride group. An intramolecular C—H⋯Cl interaction occurs. The crystal packing is stabilized by intermolecular N—H⋯Cl hydrogen bonds, which form an extended chain parallel to [010]. |
format | Online Article Text |
id | pubmed-3120300 |
institution | National Center for Biotechnology Information |
language | English |
publishDate | 2011 |
publisher | International Union of Crystallography |
record_format | MEDLINE/PubMed |
spelling | pubmed-31203002011-07-13 Chlorido(1H-imidazole-κN (3))bis(triphenylphosphane-κP)copper(I) Hossaini Sadr, Moayad Kia, Reza Soltani, Behzad Acta Crystallogr Sect E Struct Rep Online Metal-Organic Papers In the title complex, [CuCl(C(3)H(4)N(2))(C(18)H(15)P)(2)], the coordination geometry around Cu(I) is distorted tetrahedral formed by two triphenylphosphane ligands, an imidazole ligand and a chloride group. An intramolecular C—H⋯Cl interaction occurs. The crystal packing is stabilized by intermolecular N—H⋯Cl hydrogen bonds, which form an extended chain parallel to [010]. International Union of Crystallography 2011-05-20 /pmc/articles/PMC3120300/ /pubmed/21754651 http://dx.doi.org/10.1107/S1600536811017752 Text en © Hossaini Sadr et al. 2011 http://creativecommons.org/licenses/by/2.0/uk/ This is an open-access article distributed under the terms of the Creative Commons Attribution Licence, which permits unrestricted use, distribution, and reproduction in any medium, provided the original authors and source are cited. |
spellingShingle | Metal-Organic Papers Hossaini Sadr, Moayad Kia, Reza Soltani, Behzad Chlorido(1H-imidazole-κN (3))bis(triphenylphosphane-κP)copper(I) |
title | Chlorido(1H-imidazole-κN
(3))bis(triphenylphosphane-κP)copper(I) |
title_full | Chlorido(1H-imidazole-κN
(3))bis(triphenylphosphane-κP)copper(I) |
title_fullStr | Chlorido(1H-imidazole-κN
(3))bis(triphenylphosphane-κP)copper(I) |
title_full_unstemmed | Chlorido(1H-imidazole-κN
(3))bis(triphenylphosphane-κP)copper(I) |
title_short | Chlorido(1H-imidazole-κN
(3))bis(triphenylphosphane-κP)copper(I) |
title_sort | chlorido(1h-imidazole-κn
(3))bis(triphenylphosphane-κp)copper(i) |
topic | Metal-Organic Papers |
url | https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3120300/ https://www.ncbi.nlm.nih.gov/pubmed/21754651 http://dx.doi.org/10.1107/S1600536811017752 |
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