Bis(1,3-dimesitylimidazol­yl)gold(I) 2,4,8,10-tetra­phenyl-1,3,5,7,9,11-hexa­oxa-2,4,8,10-tetra­bora-6-borataspiro­[5.5]undeca­ne

The Au(I) atom in the title compound, [Au(C(21)H(24)N(2))(2)](C(24)H(20)B(5)O(6)), adopts a slightly distorted linear AuC(2) coordination geometry arising from its coordination by two mesitylenic N-heterocyclic carbene ligands, forming an overall cationic complex. The dihedral angle between the imid...

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Detalles Bibliográficos
Autores principales: Möhlmann, Lennart, Wendt, Ola F., Johnson, Magnus T.
Formato: Online Artículo Texto
Lenguaje:English
Publicado: International Union of Crystallography 2011
Materias:
Metal-Organic Papers
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3120302/
https://www.ncbi.nlm.nih.gov/pubmed/21754618
http://dx.doi.org/10.1107/S1600536811016357
Descripción
Sumario:The Au(I) atom in the title compound, [Au(C(21)H(24)N(2))(2)](C(24)H(20)B(5)O(6)), adopts a slightly distorted linear AuC(2) coordination geometry arising from its coordination by two mesitylenic N-heterocyclic carbene ligands, forming an overall cationic complex. The dihedral angle between the imidazole rings is 57.3 (6)°. In the crystal, the components are linked by weak C—H⋯O hydrogen bonds.

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