Tris(morpholinium) hexa-μ(3)-hydroxido-hexa-μ(2)-oxido-dodeca­oxidohexa­molybdenum(VI)chromate(III) tetra­hydrate

In the title organic–inorganic hybrid compound, (C(4)H(10)NO)(3)[H(6)CrMo(6)O(24)]·4H(2)O, the Anderson-type [H(6)CrMo(6)O(24)](3−) polyoxoanion is centrosymmetric, with the Cr(III) ion lying on an inversion center. One of the two crystallographiclly independent morpholinium cations is half-occupied...

Descripción completa

Detalles Bibliográficos
Autores principales: Yang, Yan-Yan, Song, Yu, Liu, Li-Ye, Qu, Xiao-Shu
Formato: Online Artículo Texto
Lenguaje:English
Publicado: International Union of Crystallography 2011
Materias:
Metal-Organic Papers
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3120305/
https://www.ncbi.nlm.nih.gov/pubmed/21754659
http://dx.doi.org/10.1107/S1600536811018149
_version_ 1782206649104072704
author Yang, Yan-Yan
Song, Yu
Liu, Li-Ye
Qu, Xiao-Shu
author_facet Yang, Yan-Yan
Song, Yu
Liu, Li-Ye
Qu, Xiao-Shu
author_sort Yang, Yan-Yan
collection PubMed
description In the title organic–inorganic hybrid compound, (C(4)H(10)NO)(3)[H(6)CrMo(6)O(24)]·4H(2)O, the Anderson-type [H(6)CrMo(6)O(24)](3−) polyoxoanion is centrosymmetric, with the Cr(III) ion lying on an inversion center. One of the two crystallographiclly independent morpholinium cations is half-occupied. Inter­molecular N—H⋯O and O—H⋯O hydrogen bonds link the cations, polyoxoanions and uncoordinated water mol­ecules.
format Online
Article
Text
id pubmed-3120305
institution National Center for Biotechnology Information
language English
publishDate 2011
publisher International Union of Crystallography
record_format MEDLINE/PubMed
spelling pubmed-31203052011-07-13 Tris(morpholinium) hexa-μ(3)-hydroxido-hexa-μ(2)-oxido-dodeca­oxidohexa­molybdenum(VI)chromate(III) tetra­hydrate Yang, Yan-Yan Song, Yu Liu, Li-Ye Qu, Xiao-Shu Acta Crystallogr Sect E Struct Rep Online Metal-Organic Papers In the title organic–inorganic hybrid compound, (C(4)H(10)NO)(3)[H(6)CrMo(6)O(24)]·4H(2)O, the Anderson-type [H(6)CrMo(6)O(24)](3−) polyoxoanion is centrosymmetric, with the Cr(III) ion lying on an inversion center. One of the two crystallographiclly independent morpholinium cations is half-occupied. Inter­molecular N—H⋯O and O—H⋯O hydrogen bonds link the cations, polyoxoanions and uncoordinated water mol­ecules. International Union of Crystallography 2011-05-20 /pmc/articles/PMC3120305/ /pubmed/21754659 http://dx.doi.org/10.1107/S1600536811018149 Text en © Yang et al. 2011 http://creativecommons.org/licenses/by/2.0/uk/ This is an open-access article distributed under the terms of the Creative Commons Attribution Licence, which permits unrestricted use, distribution, and reproduction in any medium, provided the original authors and source are cited.
spellingShingle Metal-Organic Papers
Yang, Yan-Yan
Song, Yu
Liu, Li-Ye
Qu, Xiao-Shu
Tris(morpholinium) hexa-μ(3)-hydroxido-hexa-μ(2)-oxido-dodeca­oxidohexa­molybdenum(VI)chromate(III) tetra­hydrate
title Tris(morpholinium) hexa-μ(3)-hydroxido-hexa-μ(2)-oxido-dodeca­oxidohexa­molybdenum(VI)chromate(III) tetra­hydrate
title_full Tris(morpholinium) hexa-μ(3)-hydroxido-hexa-μ(2)-oxido-dodeca­oxidohexa­molybdenum(VI)chromate(III) tetra­hydrate
title_fullStr Tris(morpholinium) hexa-μ(3)-hydroxido-hexa-μ(2)-oxido-dodeca­oxidohexa­molybdenum(VI)chromate(III) tetra­hydrate
title_full_unstemmed Tris(morpholinium) hexa-μ(3)-hydroxido-hexa-μ(2)-oxido-dodeca­oxidohexa­molybdenum(VI)chromate(III) tetra­hydrate
title_short Tris(morpholinium) hexa-μ(3)-hydroxido-hexa-μ(2)-oxido-dodeca­oxidohexa­molybdenum(VI)chromate(III) tetra­hydrate
title_sort tris(morpholinium) hexa-μ(3)-hydroxido-hexa-μ(2)-oxido-dodeca­oxidohexa­molybdenum(vi)chromate(iii) tetra­hydrate
topic Metal-Organic Papers
url https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3120305/
https://www.ncbi.nlm.nih.gov/pubmed/21754659
http://dx.doi.org/10.1107/S1600536811018149
work_keys_str_mv AT yangyanyan trismorpholiniumhexam3hydroxidohexam2oxidododecaoxidohexamolybdenumvichromateiiitetrahydrate
AT songyu trismorpholiniumhexam3hydroxidohexam2oxidododecaoxidohexamolybdenumvichromateiiitetrahydrate
AT liuliye trismorpholiniumhexam3hydroxidohexam2oxidododecaoxidohexamolybdenumvichromateiiitetrahydrate
AT quxiaoshu trismorpholiniumhexam3hydroxidohexam2oxidododecaoxidohexamolybdenumvichromateiiitetrahydrate

Ejemplares similares