Aqua­[2-(2-pyrid­yl)-1,8-naphthyridine-κ(2) N (1),N (2)](2,2′:6′,2′′-terpyridine-κ(3) N,N′,N′′)ruthenium(II) bis­(hexa­fluorido­phosphate) acetone sesquisolvate

The asymmetric unit of the title compound, [Ru(C(13)H(9)N(3))(C(15)H(11)N(3))(H(2)O)](PF(6))(2)·1.5C(3)H(6)O, consists of two crystallographically independent Ru(II) complexes. Each complex is approximately octa­hedral with the Ru(II) atom bound by an N,N′-coordinated 2-(2-pyrid­yl)-1,8-naphthyridin...

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Detalles Bibliográficos
Autores principales: Oyama, Dai, Yuzuriya, Kazumi, Takase, Tsugiko
Formato: Online Artículo Texto
Lenguaje:English
Publicado: International Union of Crystallography 2011
Materias:
Metal-Organic Papers
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3120306/
https://www.ncbi.nlm.nih.gov/pubmed/21754631
http://dx.doi.org/10.1107/S1600536811016485
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author Oyama, Dai
Yuzuriya, Kazumi
Takase, Tsugiko
author_facet Oyama, Dai
Yuzuriya, Kazumi
Takase, Tsugiko
author_sort Oyama, Dai
collection PubMed
description The asymmetric unit of the title compound, [Ru(C(13)H(9)N(3))(C(15)H(11)N(3))(H(2)O)](PF(6))(2)·1.5C(3)H(6)O, consists of two crystallographically independent Ru(II) complexes. Each complex is approximately octa­hedral with the Ru(II) atom bound by an N,N′-coordinated 2-(2-pyrid­yl)-1,8-naphthyridine (pynp) ligand, a meridional 2,2′:6′,2′′-terpyridine (tpy) ligand and one aqua ligand. The tpy ligand is coordinated in a planar tridentate fashion with the central N atom closest to the Ru(II) atom. The aqua ligand is trans to the pyridine N atom of pynp. The long Ru—O distances [2.150 (5) and 2.138 (5) Å] are typical for aqua ligands in polypyridyl ruthenium complexes. In the crystal, both intra­molecular O—H⋯N and inter­molecular O—H⋯O hydrogen bonds are observed.
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spelling pubmed-31203062011-07-13 Aqua­[2-(2-pyrid­yl)-1,8-naphthyridine-κ(2) N (1),N (2)](2,2′:6′,2′′-terpyridine-κ(3) N,N′,N′′)ruthenium(II) bis­(hexa­fluorido­phosphate) acetone sesquisolvate Oyama, Dai Yuzuriya, Kazumi Takase, Tsugiko Acta Crystallogr Sect E Struct Rep Online Metal-Organic Papers The asymmetric unit of the title compound, [Ru(C(13)H(9)N(3))(C(15)H(11)N(3))(H(2)O)](PF(6))(2)·1.5C(3)H(6)O, consists of two crystallographically independent Ru(II) complexes. Each complex is approximately octa­hedral with the Ru(II) atom bound by an N,N′-coordinated 2-(2-pyrid­yl)-1,8-naphthyridine (pynp) ligand, a meridional 2,2′:6′,2′′-terpyridine (tpy) ligand and one aqua ligand. The tpy ligand is coordinated in a planar tridentate fashion with the central N atom closest to the Ru(II) atom. The aqua ligand is trans to the pyridine N atom of pynp. The long Ru—O distances [2.150 (5) and 2.138 (5) Å] are typical for aqua ligands in polypyridyl ruthenium complexes. In the crystal, both intra­molecular O—H⋯N and inter­molecular O—H⋯O hydrogen bonds are observed. International Union of Crystallography 2011-05-11 /pmc/articles/PMC3120306/ /pubmed/21754631 http://dx.doi.org/10.1107/S1600536811016485 Text en © Oyama et al. 2011 http://creativecommons.org/licenses/by/2.0/uk/ This is an open-access article distributed under the terms of the Creative Commons Attribution Licence, which permits unrestricted use, distribution, and reproduction in any medium, provided the original authors and source are cited.
spellingShingle Metal-Organic Papers
Oyama, Dai
Yuzuriya, Kazumi
Takase, Tsugiko
Aqua­[2-(2-pyrid­yl)-1,8-naphthyridine-κ(2) N (1),N (2)](2,2′:6′,2′′-terpyridine-κ(3) N,N′,N′′)ruthenium(II) bis­(hexa­fluorido­phosphate) acetone sesquisolvate
title Aqua­[2-(2-pyrid­yl)-1,8-naphthyridine-κ(2) N (1),N (2)](2,2′:6′,2′′-terpyridine-κ(3) N,N′,N′′)ruthenium(II) bis­(hexa­fluorido­phosphate) acetone sesquisolvate
title_full Aqua­[2-(2-pyrid­yl)-1,8-naphthyridine-κ(2) N (1),N (2)](2,2′:6′,2′′-terpyridine-κ(3) N,N′,N′′)ruthenium(II) bis­(hexa­fluorido­phosphate) acetone sesquisolvate
title_fullStr Aqua­[2-(2-pyrid­yl)-1,8-naphthyridine-κ(2) N (1),N (2)](2,2′:6′,2′′-terpyridine-κ(3) N,N′,N′′)ruthenium(II) bis­(hexa­fluorido­phosphate) acetone sesquisolvate
title_full_unstemmed Aqua­[2-(2-pyrid­yl)-1,8-naphthyridine-κ(2) N (1),N (2)](2,2′:6′,2′′-terpyridine-κ(3) N,N′,N′′)ruthenium(II) bis­(hexa­fluorido­phosphate) acetone sesquisolvate
title_short Aqua­[2-(2-pyrid­yl)-1,8-naphthyridine-κ(2) N (1),N (2)](2,2′:6′,2′′-terpyridine-κ(3) N,N′,N′′)ruthenium(II) bis­(hexa­fluorido­phosphate) acetone sesquisolvate
title_sort aqua­[2-(2-pyrid­yl)-1,8-naphthyridine-κ(2) n (1),n (2)](2,2′:6′,2′′-terpyridine-κ(3) n,n′,n′′)ruthenium(ii) bis­(hexa­fluorido­phosphate) acetone sesquisolvate
topic Metal-Organic Papers
url https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3120306/
https://www.ncbi.nlm.nih.gov/pubmed/21754631
http://dx.doi.org/10.1107/S1600536811016485
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AT yuzuriyakazumi aqua22pyridyl18naphthyridinek2n1n22262terpyridinek3nnnrutheniumiibishexafluoridophosphateacetonesesquisolvate
AT takasetsugiko aqua22pyridyl18naphthyridinek2n1n22262terpyridinek3nnnrutheniumiibishexafluoridophosphateacetonesesquisolvate

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