(S,E)-N-Methyl-4-[(S)2,6,6-trimethyl-4-oxocyclo­hex-2-en­yl]but-3-en-2-aminium chloride

The title compound, C(14)H(24)NO(+)·Cl(−), crystallizes with four independent mol­ecules in the asymmetric unit. It was isolated from plant Pachysandra terminalis Siebold & Zucc. The six-membered ring has a conformation close to an envelope. In the crystal, N—H⋯Cl hydrogen-bonding inter­actions...

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Detalles Bibliográficos
Autores principales: Chang, Liu-Shuan, Duan, Hong-Quan
Formato: Online Artículo Texto
Lenguaje:English
Publicado: International Union of Crystallography 2011
Materias:
Organic Papers
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3120307/
https://www.ncbi.nlm.nih.gov/pubmed/21754696
http://dx.doi.org/10.1107/S1600536811015297
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author Chang, Liu-Shuan
Duan, Hong-Quan
author_facet Chang, Liu-Shuan
Duan, Hong-Quan
author_sort Chang, Liu-Shuan
collection PubMed
description The title compound, C(14)H(24)NO(+)·Cl(−), crystallizes with four independent mol­ecules in the asymmetric unit. It was isolated from plant Pachysandra terminalis Siebold & Zucc. The six-membered ring has a conformation close to an envelope. In the crystal, N—H⋯Cl hydrogen-bonding inter­actions exist between secondary ammonium groups and free chloride anions, resulting in a one-dimensional supra­molecular structure oriented along [100]. The crystal studied was found to be a two-component non-merohedral twin with twin law [[Image: see text]00/0[Image: see text]0/101], the fractional contribution of the minor component being approximately 33%.
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spelling pubmed-31203072011-07-13 (S,E)-N-Methyl-4-[(S)2,6,6-trimethyl-4-oxocyclo­hex-2-en­yl]but-3-en-2-aminium chloride Chang, Liu-Shuan Duan, Hong-Quan Acta Crystallogr Sect E Struct Rep Online Organic Papers The title compound, C(14)H(24)NO(+)·Cl(−), crystallizes with four independent mol­ecules in the asymmetric unit. It was isolated from plant Pachysandra terminalis Siebold & Zucc. The six-membered ring has a conformation close to an envelope. In the crystal, N—H⋯Cl hydrogen-bonding inter­actions exist between secondary ammonium groups and free chloride anions, resulting in a one-dimensional supra­molecular structure oriented along [100]. The crystal studied was found to be a two-component non-merohedral twin with twin law [[Image: see text]00/0[Image: see text]0/101], the fractional contribution of the minor component being approximately 33%. International Union of Crystallography 2011-05-07 /pmc/articles/PMC3120307/ /pubmed/21754696 http://dx.doi.org/10.1107/S1600536811015297 Text en © Chang and Duan 2011 http://creativecommons.org/licenses/by/2.0/uk/ This is an open-access article distributed under the terms of the Creative Commons Attribution Licence, which permits unrestricted use, distribution, and reproduction in any medium, provided the original authors and source are cited.
spellingShingle Organic Papers
Chang, Liu-Shuan
Duan, Hong-Quan
(S,E)-N-Methyl-4-[(S)2,6,6-trimethyl-4-oxocyclo­hex-2-en­yl]but-3-en-2-aminium chloride
title (S,E)-N-Methyl-4-[(S)2,6,6-trimethyl-4-oxocyclo­hex-2-en­yl]but-3-en-2-aminium chloride
title_full (S,E)-N-Methyl-4-[(S)2,6,6-trimethyl-4-oxocyclo­hex-2-en­yl]but-3-en-2-aminium chloride
title_fullStr (S,E)-N-Methyl-4-[(S)2,6,6-trimethyl-4-oxocyclo­hex-2-en­yl]but-3-en-2-aminium chloride
title_full_unstemmed (S,E)-N-Methyl-4-[(S)2,6,6-trimethyl-4-oxocyclo­hex-2-en­yl]but-3-en-2-aminium chloride
title_short (S,E)-N-Methyl-4-[(S)2,6,6-trimethyl-4-oxocyclo­hex-2-en­yl]but-3-en-2-aminium chloride
title_sort (s,e)-n-methyl-4-[(s)2,6,6-trimethyl-4-oxocyclo­hex-2-en­yl]but-3-en-2-aminium chloride
topic Organic Papers
url https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3120307/
https://www.ncbi.nlm.nih.gov/pubmed/21754696
http://dx.doi.org/10.1107/S1600536811015297
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AT duanhongquan senmethyl4s266trimethyl4oxocyclohex2enylbut3en2aminiumchloride

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