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Bis(μ-2-{[2-(1,3-benzothiazol-2-yl)hydrazinylidene]methyl}-6-methoxyphenolato)bis[dinitratodysprosium(III)] methanol disolvate
In the centrosymmetric dinuclear title compound, [Dy(2)(C(15)H(12)N(3)O(2)S)(2)(NO(3))(4)]·2CH(3)OH, the two Dy(III) atoms are coordinated by two deprotonated 2-{[2-(1,3-benzothiazol-2-yl)hydrazinylidene]methyl}-6-methoxyphenol ligands and four nitrate ions, all of which are chelating. The crys...
Autores principales: | , , , , |
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Formato: | Online Artículo Texto |
Lenguaje: | English |
Publicado: |
International Union of Crystallography
2011
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Materias: | |
Acceso en línea: | https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3120308/ https://www.ncbi.nlm.nih.gov/pubmed/21754674 http://dx.doi.org/10.1107/S1600536811019118 |
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author | Xu, Xuebin Ding, Shuai Shen, Si Tang, Jinkui Liu, Zhiliang |
author_facet | Xu, Xuebin Ding, Shuai Shen, Si Tang, Jinkui Liu, Zhiliang |
author_sort | Xu, Xuebin |
collection | PubMed |
description | In the centrosymmetric dinuclear title compound, [Dy(2)(C(15)H(12)N(3)O(2)S)(2)(NO(3))(4)]·2CH(3)OH, the two Dy(III) atoms are coordinated by two deprotonated 2-{[2-(1,3-benzothiazol-2-yl)hydrazinylidene]methyl}-6-methoxyphenol ligands and four nitrate ions, all of which are chelating. The crystal packing is stabilized by intermolecular N—H⋯O hydrogen bonds and weak O—H⋯O interactions, forming a two-dimensional network parallel to (010). |
format | Online Article Text |
id | pubmed-3120308 |
institution | National Center for Biotechnology Information |
language | English |
publishDate | 2011 |
publisher | International Union of Crystallography |
record_format | MEDLINE/PubMed |
spelling | pubmed-31203082011-07-13 Bis(μ-2-{[2-(1,3-benzothiazol-2-yl)hydrazinylidene]methyl}-6-methoxyphenolato)bis[dinitratodysprosium(III)] methanol disolvate Xu, Xuebin Ding, Shuai Shen, Si Tang, Jinkui Liu, Zhiliang Acta Crystallogr Sect E Struct Rep Online Metal-Organic Papers In the centrosymmetric dinuclear title compound, [Dy(2)(C(15)H(12)N(3)O(2)S)(2)(NO(3))(4)]·2CH(3)OH, the two Dy(III) atoms are coordinated by two deprotonated 2-{[2-(1,3-benzothiazol-2-yl)hydrazinylidene]methyl}-6-methoxyphenol ligands and four nitrate ions, all of which are chelating. The crystal packing is stabilized by intermolecular N—H⋯O hydrogen bonds and weak O—H⋯O interactions, forming a two-dimensional network parallel to (010). International Union of Crystallography 2011-05-25 /pmc/articles/PMC3120308/ /pubmed/21754674 http://dx.doi.org/10.1107/S1600536811019118 Text en © Xu et al. 2011 http://creativecommons.org/licenses/by/2.0/uk/ This is an open-access article distributed under the terms of the Creative Commons Attribution Licence, which permits unrestricted use, distribution, and reproduction in any medium, provided the original authors and source are cited. |
spellingShingle | Metal-Organic Papers Xu, Xuebin Ding, Shuai Shen, Si Tang, Jinkui Liu, Zhiliang Bis(μ-2-{[2-(1,3-benzothiazol-2-yl)hydrazinylidene]methyl}-6-methoxyphenolato)bis[dinitratodysprosium(III)] methanol disolvate |
title | Bis(μ-2-{[2-(1,3-benzothiazol-2-yl)hydrazinylidene]methyl}-6-methoxyphenolato)bis[dinitratodysprosium(III)] methanol disolvate |
title_full | Bis(μ-2-{[2-(1,3-benzothiazol-2-yl)hydrazinylidene]methyl}-6-methoxyphenolato)bis[dinitratodysprosium(III)] methanol disolvate |
title_fullStr | Bis(μ-2-{[2-(1,3-benzothiazol-2-yl)hydrazinylidene]methyl}-6-methoxyphenolato)bis[dinitratodysprosium(III)] methanol disolvate |
title_full_unstemmed | Bis(μ-2-{[2-(1,3-benzothiazol-2-yl)hydrazinylidene]methyl}-6-methoxyphenolato)bis[dinitratodysprosium(III)] methanol disolvate |
title_short | Bis(μ-2-{[2-(1,3-benzothiazol-2-yl)hydrazinylidene]methyl}-6-methoxyphenolato)bis[dinitratodysprosium(III)] methanol disolvate |
title_sort | bis(μ-2-{[2-(1,3-benzothiazol-2-yl)hydrazinylidene]methyl}-6-methoxyphenolato)bis[dinitratodysprosium(iii)] methanol disolvate |
topic | Metal-Organic Papers |
url | https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3120308/ https://www.ncbi.nlm.nih.gov/pubmed/21754674 http://dx.doi.org/10.1107/S1600536811019118 |
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