Bis[4-(2-hy­droxy­benzyl­idene­amino)­benzoato-κO (1)]tetra­kis­(methanol-κO)cadmium

In the title mononuclear complex, [Cd(C(14)H(10)NO(3))(2)(CH(3)OH)(4)], the Cd(2+) cation is situated on an inversion centre. It exhibits a distorted octa­hedral coordination, defined by two carboxyl­ate O atoms from two monodentate anions and by four O atoms from four methanol mol­ecules. The cryst...

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Detalles Bibliográficos
Autores principales: Wang, Ying, Wang, Xia, Li, Yu-Xian, Yang, Huai-Xia, Liu, Yan-Ju
Formato: Online Artículo Texto
Lenguaje:English
Publicado: International Union of Crystallography 2011
Materias:
Metal-Organic Papers
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3120309/
https://www.ncbi.nlm.nih.gov/pubmed/21754592
http://dx.doi.org/10.1107/S1600536811015364
Descripción
Sumario:In the title mononuclear complex, [Cd(C(14)H(10)NO(3))(2)(CH(3)OH)(4)], the Cd(2+) cation is situated on an inversion centre. It exhibits a distorted octa­hedral coordination, defined by two carboxyl­ate O atoms from two monodentate anions and by four O atoms from four methanol mol­ecules. The crystal structure comprises intra­molecular O—H⋯O and O—H⋯N, and inter­molecular O—H⋯O hydrogen bonds. The latter help to construct a layered structure extending parallel to (100).

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