Bis[4-(2-hy­droxy­benzyl­idene­amino)­benzoato-κO (1)]tetra­kis­(methanol-κO)cadmium

In the title mononuclear complex, [Cd(C(14)H(10)NO(3))(2)(CH(3)OH)(4)], the Cd(2+) cation is situated on an inversion centre. It exhibits a distorted octa­hedral coordination, defined by two carboxyl­ate O atoms from two monodentate anions and by four O atoms from four methanol mol­ecules. The cryst...

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Detalles Bibliográficos
Autores principales: Wang, Ying, Wang, Xia, Li, Yu-Xian, Yang, Huai-Xia, Liu, Yan-Ju
Formato: Online Artículo Texto
Lenguaje:English
Publicado: International Union of Crystallography 2011
Materias:
Metal-Organic Papers
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3120309/
https://www.ncbi.nlm.nih.gov/pubmed/21754592
http://dx.doi.org/10.1107/S1600536811015364
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author Wang, Ying
Wang, Xia
Li, Yu-Xian
Yang, Huai-Xia
Liu, Yan-Ju
author_facet Wang, Ying
Wang, Xia
Li, Yu-Xian
Yang, Huai-Xia
Liu, Yan-Ju
author_sort Wang, Ying
collection PubMed
description In the title mononuclear complex, [Cd(C(14)H(10)NO(3))(2)(CH(3)OH)(4)], the Cd(2+) cation is situated on an inversion centre. It exhibits a distorted octa­hedral coordination, defined by two carboxyl­ate O atoms from two monodentate anions and by four O atoms from four methanol mol­ecules. The crystal structure comprises intra­molecular O—H⋯O and O—H⋯N, and inter­molecular O—H⋯O hydrogen bonds. The latter help to construct a layered structure extending parallel to (100).
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spelling pubmed-31203092011-07-13 Bis[4-(2-hy­droxy­benzyl­idene­amino)­benzoato-κO (1)]tetra­kis­(methanol-κO)cadmium Wang, Ying Wang, Xia Li, Yu-Xian Yang, Huai-Xia Liu, Yan-Ju Acta Crystallogr Sect E Struct Rep Online Metal-Organic Papers In the title mononuclear complex, [Cd(C(14)H(10)NO(3))(2)(CH(3)OH)(4)], the Cd(2+) cation is situated on an inversion centre. It exhibits a distorted octa­hedral coordination, defined by two carboxyl­ate O atoms from two monodentate anions and by four O atoms from four methanol mol­ecules. The crystal structure comprises intra­molecular O—H⋯O and O—H⋯N, and inter­molecular O—H⋯O hydrogen bonds. The latter help to construct a layered structure extending parallel to (100). International Union of Crystallography 2011-05-07 /pmc/articles/PMC3120309/ /pubmed/21754592 http://dx.doi.org/10.1107/S1600536811015364 Text en © Wang et al. 2011 http://creativecommons.org/licenses/by/2.0/uk/ This is an open-access article distributed under the terms of the Creative Commons Attribution Licence, which permits unrestricted use, distribution, and reproduction in any medium, provided the original authors and source are cited.
spellingShingle Metal-Organic Papers
Wang, Ying
Wang, Xia
Li, Yu-Xian
Yang, Huai-Xia
Liu, Yan-Ju
Bis[4-(2-hy­droxy­benzyl­idene­amino)­benzoato-κO (1)]tetra­kis­(methanol-κO)cadmium
title Bis[4-(2-hy­droxy­benzyl­idene­amino)­benzoato-κO (1)]tetra­kis­(methanol-κO)cadmium
title_full Bis[4-(2-hy­droxy­benzyl­idene­amino)­benzoato-κO (1)]tetra­kis­(methanol-κO)cadmium
title_fullStr Bis[4-(2-hy­droxy­benzyl­idene­amino)­benzoato-κO (1)]tetra­kis­(methanol-κO)cadmium
title_full_unstemmed Bis[4-(2-hy­droxy­benzyl­idene­amino)­benzoato-κO (1)]tetra­kis­(methanol-κO)cadmium
title_short Bis[4-(2-hy­droxy­benzyl­idene­amino)­benzoato-κO (1)]tetra­kis­(methanol-κO)cadmium
title_sort bis[4-(2-hy­droxy­benzyl­idene­amino)­benzoato-κo (1)]tetra­kis­(methanol-κo)cadmium
topic Metal-Organic Papers
url https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3120309/
https://www.ncbi.nlm.nih.gov/pubmed/21754592
http://dx.doi.org/10.1107/S1600536811015364
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