21-(4-Methyl­phenyl­sulfon­yl)-4,7,13,16-tetra­oxa-1,10,21-triaza­bicyclo­[8.8.5]tricosane-19,23-dione: an N-tosyl­ated macrobicyclic dilactam

The macrobicyclic title compound, C(23)H(35)N(3)O(8)S, contains two tertiary amide bridgehead N atoms and a toluene­sulfonamide N atom in the center of the five-atom bridging strand. The mol­ecule has a central cavity that is defined by the 18-membered ring identified by the N(2)O(4) donor atom set...

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Detalles Bibliográficos
Autores principales: Ellis, Trevor K., Clayton, Stephen M., Powell, Douglas R., Taylor, Richard W.
Formato: Online Artículo Texto
Lenguaje:English
Publicado: International Union of Crystallography 2011
Materias:
Organic Papers
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3120313/
https://www.ncbi.nlm.nih.gov/pubmed/21754893
http://dx.doi.org/10.1107/S1600536811018873
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author Ellis, Trevor K.
Clayton, Stephen M.
Powell, Douglas R.
Taylor, Richard W.
author_facet Ellis, Trevor K.
Clayton, Stephen M.
Powell, Douglas R.
Taylor, Richard W.
author_sort Ellis, Trevor K.
collection PubMed
description The macrobicyclic title compound, C(23)H(35)N(3)O(8)S, contains two tertiary amide bridgehead N atoms and a toluene­sulfonamide N atom in the center of the five-atom bridging strand. The mol­ecule has a central cavity that is defined by the 18-membered ring identified by the N(2)O(4) donor atom set and two 15-membered rings with N(3)O(2) donor atom sets. The toluene­sulfonamide N atom adopts an exo orientation with respect to the central cavity, and the tosyl group is oriented on one side of the aza-bridging strand that connects the bridgehead N atoms.
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spelling pubmed-31203132011-07-13 21-(4-Methyl­phenyl­sulfon­yl)-4,7,13,16-tetra­oxa-1,10,21-triaza­bicyclo­[8.8.5]tricosane-19,23-dione: an N-tosyl­ated macrobicyclic dilactam Ellis, Trevor K. Clayton, Stephen M. Powell, Douglas R. Taylor, Richard W. Acta Crystallogr Sect E Struct Rep Online Organic Papers The macrobicyclic title compound, C(23)H(35)N(3)O(8)S, contains two tertiary amide bridgehead N atoms and a toluene­sulfonamide N atom in the center of the five-atom bridging strand. The mol­ecule has a central cavity that is defined by the 18-membered ring identified by the N(2)O(4) donor atom set and two 15-membered rings with N(3)O(2) donor atom sets. The toluene­sulfonamide N atom adopts an exo orientation with respect to the central cavity, and the tosyl group is oriented on one side of the aza-bridging strand that connects the bridgehead N atoms. International Union of Crystallography 2011-05-28 /pmc/articles/PMC3120313/ /pubmed/21754893 http://dx.doi.org/10.1107/S1600536811018873 Text en © Ellis et al. 2011 http://creativecommons.org/licenses/by/2.0/uk/ This is an open-access article distributed under the terms of the Creative Commons Attribution Licence, which permits unrestricted use, distribution, and reproduction in any medium, provided the original authors and source are cited.
spellingShingle Organic Papers
Ellis, Trevor K.
Clayton, Stephen M.
Powell, Douglas R.
Taylor, Richard W.
21-(4-Methyl­phenyl­sulfon­yl)-4,7,13,16-tetra­oxa-1,10,21-triaza­bicyclo­[8.8.5]tricosane-19,23-dione: an N-tosyl­ated macrobicyclic dilactam
title 21-(4-Methyl­phenyl­sulfon­yl)-4,7,13,16-tetra­oxa-1,10,21-triaza­bicyclo­[8.8.5]tricosane-19,23-dione: an N-tosyl­ated macrobicyclic dilactam
title_full 21-(4-Methyl­phenyl­sulfon­yl)-4,7,13,16-tetra­oxa-1,10,21-triaza­bicyclo­[8.8.5]tricosane-19,23-dione: an N-tosyl­ated macrobicyclic dilactam
title_fullStr 21-(4-Methyl­phenyl­sulfon­yl)-4,7,13,16-tetra­oxa-1,10,21-triaza­bicyclo­[8.8.5]tricosane-19,23-dione: an N-tosyl­ated macrobicyclic dilactam
title_full_unstemmed 21-(4-Methyl­phenyl­sulfon­yl)-4,7,13,16-tetra­oxa-1,10,21-triaza­bicyclo­[8.8.5]tricosane-19,23-dione: an N-tosyl­ated macrobicyclic dilactam
title_short 21-(4-Methyl­phenyl­sulfon­yl)-4,7,13,16-tetra­oxa-1,10,21-triaza­bicyclo­[8.8.5]tricosane-19,23-dione: an N-tosyl­ated macrobicyclic dilactam
title_sort 21-(4-methyl­phenyl­sulfon­yl)-4,7,13,16-tetra­oxa-1,10,21-triaza­bicyclo­[8.8.5]tricosane-19,23-dione: an n-tosyl­ated macrobicyclic dilactam
topic Organic Papers
url https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3120313/
https://www.ncbi.nlm.nih.gov/pubmed/21754893
http://dx.doi.org/10.1107/S1600536811018873
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