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[μ-1,2-Bis(4-pyridyl)ethene-κ(2) N:N′]bis[aqua(pyridine-2,6-dicarboxylato-κ(3) O (2),N,O (6))copper(II)] dihydrate
In the title dinuclear Cu(II) complex, [Cu(2)(C(7)H(3)NO(4))(2)(C(12)H(10)N(2))(H(2)O)(2)]·2H(2)O, the water-coordinated Cu(II) cation is O,N,O′-chelated by a pyridine-2,6-dicarboxylate (pdc) dianion, and one pyridine N atom from a 1,2-bis(4-pyridyl)ethene ligand coordinates to the Cu(II) cation,...
Autor principal: | |
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Formato: | Online Artículo Texto |
Lenguaje: | English |
Publicado: |
International Union of Crystallography
2011
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Materias: | |
Acceso en línea: | https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3120317/ https://www.ncbi.nlm.nih.gov/pubmed/21754658 http://dx.doi.org/10.1107/S1600536811018411 |
Sumario: | In the title dinuclear Cu(II) complex, [Cu(2)(C(7)H(3)NO(4))(2)(C(12)H(10)N(2))(H(2)O)(2)]·2H(2)O, the water-coordinated Cu(II) cation is O,N,O′-chelated by a pyridine-2,6-dicarboxylate (pdc) dianion, and one pyridine N atom from a 1,2-bis(4-pyridyl)ethene ligand coordinates to the Cu(II) cation, completing the CuN(2)O(3) distorted square-pyriamidial geometry. The Cu—O(water) bond [2.388 (4) Å] in the axial direction is much longer than the other Cu—O bonds. The 1,2-bis(4-pyridyl)ethene ligand is located across an inversion center with the mid-point of the C=C bond at the inversion center, and bridges two Cu(II) cations, generating a centrosymmetric dinuclear complex. The crystal structure is stabilized by classical O—H⋯O and weak C—H⋯O hydrogen bonds. |
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