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[μ-1,2-Bis(4-pyridyl)ethene-κ(2) N:N′]bis[aqua(pyridine-2,6-dicarboxylato-κ(3) O (2),N,O (6))copper(II)] dihydrate
In the title dinuclear Cu(II) complex, [Cu(2)(C(7)H(3)NO(4))(2)(C(12)H(10)N(2))(H(2)O)(2)]·2H(2)O, the water-coordinated Cu(II) cation is O,N,O′-chelated by a pyridine-2,6-dicarboxylate (pdc) dianion, and one pyridine N atom from a 1,2-bis(4-pyridyl)ethene ligand coordinates to the Cu(II) cation,...
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Formato: | Online Artículo Texto |
Lenguaje: | English |
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International Union of Crystallography
2011
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Acceso en línea: | https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3120317/ https://www.ncbi.nlm.nih.gov/pubmed/21754658 http://dx.doi.org/10.1107/S1600536811018411 |
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author | Lush, Shie Fu |
author_facet | Lush, Shie Fu |
author_sort | Lush, Shie Fu |
collection | PubMed |
description | In the title dinuclear Cu(II) complex, [Cu(2)(C(7)H(3)NO(4))(2)(C(12)H(10)N(2))(H(2)O)(2)]·2H(2)O, the water-coordinated Cu(II) cation is O,N,O′-chelated by a pyridine-2,6-dicarboxylate (pdc) dianion, and one pyridine N atom from a 1,2-bis(4-pyridyl)ethene ligand coordinates to the Cu(II) cation, completing the CuN(2)O(3) distorted square-pyriamidial geometry. The Cu—O(water) bond [2.388 (4) Å] in the axial direction is much longer than the other Cu—O bonds. The 1,2-bis(4-pyridyl)ethene ligand is located across an inversion center with the mid-point of the C=C bond at the inversion center, and bridges two Cu(II) cations, generating a centrosymmetric dinuclear complex. The crystal structure is stabilized by classical O—H⋯O and weak C—H⋯O hydrogen bonds. |
format | Online Article Text |
id | pubmed-3120317 |
institution | National Center for Biotechnology Information |
language | English |
publishDate | 2011 |
publisher | International Union of Crystallography |
record_format | MEDLINE/PubMed |
spelling | pubmed-31203172011-07-13 [μ-1,2-Bis(4-pyridyl)ethene-κ(2) N:N′]bis[aqua(pyridine-2,6-dicarboxylato-κ(3) O (2),N,O (6))copper(II)] dihydrate Lush, Shie Fu Acta Crystallogr Sect E Struct Rep Online Metal-Organic Papers In the title dinuclear Cu(II) complex, [Cu(2)(C(7)H(3)NO(4))(2)(C(12)H(10)N(2))(H(2)O)(2)]·2H(2)O, the water-coordinated Cu(II) cation is O,N,O′-chelated by a pyridine-2,6-dicarboxylate (pdc) dianion, and one pyridine N atom from a 1,2-bis(4-pyridyl)ethene ligand coordinates to the Cu(II) cation, completing the CuN(2)O(3) distorted square-pyriamidial geometry. The Cu—O(water) bond [2.388 (4) Å] in the axial direction is much longer than the other Cu—O bonds. The 1,2-bis(4-pyridyl)ethene ligand is located across an inversion center with the mid-point of the C=C bond at the inversion center, and bridges two Cu(II) cations, generating a centrosymmetric dinuclear complex. The crystal structure is stabilized by classical O—H⋯O and weak C—H⋯O hydrogen bonds. International Union of Crystallography 2011-05-20 /pmc/articles/PMC3120317/ /pubmed/21754658 http://dx.doi.org/10.1107/S1600536811018411 Text en © Shie Fu Lush 2011 http://creativecommons.org/licenses/by/2.0/uk/ This is an open-access article distributed under the terms of the Creative Commons Attribution Licence, which permits unrestricted use, distribution, and reproduction in any medium, provided the original authors and source are cited. |
spellingShingle | Metal-Organic Papers Lush, Shie Fu [μ-1,2-Bis(4-pyridyl)ethene-κ(2) N:N′]bis[aqua(pyridine-2,6-dicarboxylato-κ(3) O (2),N,O (6))copper(II)] dihydrate |
title | [μ-1,2-Bis(4-pyridyl)ethene-κ(2)
N:N′]bis[aqua(pyridine-2,6-dicarboxylato-κ(3)
O
(2),N,O
(6))copper(II)] dihydrate |
title_full | [μ-1,2-Bis(4-pyridyl)ethene-κ(2)
N:N′]bis[aqua(pyridine-2,6-dicarboxylato-κ(3)
O
(2),N,O
(6))copper(II)] dihydrate |
title_fullStr | [μ-1,2-Bis(4-pyridyl)ethene-κ(2)
N:N′]bis[aqua(pyridine-2,6-dicarboxylato-κ(3)
O
(2),N,O
(6))copper(II)] dihydrate |
title_full_unstemmed | [μ-1,2-Bis(4-pyridyl)ethene-κ(2)
N:N′]bis[aqua(pyridine-2,6-dicarboxylato-κ(3)
O
(2),N,O
(6))copper(II)] dihydrate |
title_short | [μ-1,2-Bis(4-pyridyl)ethene-κ(2)
N:N′]bis[aqua(pyridine-2,6-dicarboxylato-κ(3)
O
(2),N,O
(6))copper(II)] dihydrate |
title_sort | [μ-1,2-bis(4-pyridyl)ethene-κ(2)
n:n′]bis[aqua(pyridine-2,6-dicarboxylato-κ(3)
o
(2),n,o
(6))copper(ii)] dihydrate |
topic | Metal-Organic Papers |
url | https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3120317/ https://www.ncbi.nlm.nih.gov/pubmed/21754658 http://dx.doi.org/10.1107/S1600536811018411 |
work_keys_str_mv | AT lushshiefu m12bis4pyridylethenek2nnbisaquapyridine26dicarboxylatok3o2no6copperiidihydrate |