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[μ-1,2-Bis(4-pyrid­yl)ethene-κ(2) N:N′]bis­[aqua­(pyridine-2,6-dicarboxyl­ato-κ(3) O (2),N,O (6))copper(II)] dihydrate

In the title dinuclear Cu(II) complex, [Cu(2)(C(7)H(3)NO(4))(2)(C(12)H(10)N(2))(H(2)O)(2)]·2H(2)O, the water-coordinated Cu(II) cation is O,N,O′-chelated by a pyridine-2,6-dicarboxyl­ate (pdc) dianion, and one pyridine N atom from a 1,2-bis­(4-pyrid­yl)ethene ligand coordinates to the Cu(II) cation,...

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Autor principal: Lush, Shie Fu
Formato: Online Artículo Texto
Lenguaje:English
Publicado: International Union of Crystallography 2011
Materias:
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3120317/
https://www.ncbi.nlm.nih.gov/pubmed/21754658
http://dx.doi.org/10.1107/S1600536811018411
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author Lush, Shie Fu
author_facet Lush, Shie Fu
author_sort Lush, Shie Fu
collection PubMed
description In the title dinuclear Cu(II) complex, [Cu(2)(C(7)H(3)NO(4))(2)(C(12)H(10)N(2))(H(2)O)(2)]·2H(2)O, the water-coordinated Cu(II) cation is O,N,O′-chelated by a pyridine-2,6-dicarboxyl­ate (pdc) dianion, and one pyridine N atom from a 1,2-bis­(4-pyrid­yl)ethene ligand coordinates to the Cu(II) cation, completing the CuN(2)O(3) distorted square-pyriamidial geometry. The Cu—O(water) bond [2.388 (4) Å] in the axial direction is much longer than the other Cu—O bonds. The 1,2-bis­(4-pyrid­yl)ethene ligand is located across an inversion center with the mid-point of the C=C bond at the inversion center, and bridges two Cu(II) cations, generating a centrosymmetric dinuclear complex. The crystal structure is stabilized by classical O—H⋯O and weak C—H⋯O hydrogen bonds.
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spelling pubmed-31203172011-07-13 [μ-1,2-Bis(4-pyrid­yl)ethene-κ(2) N:N′]bis­[aqua­(pyridine-2,6-dicarboxyl­ato-κ(3) O (2),N,O (6))copper(II)] dihydrate Lush, Shie Fu Acta Crystallogr Sect E Struct Rep Online Metal-Organic Papers In the title dinuclear Cu(II) complex, [Cu(2)(C(7)H(3)NO(4))(2)(C(12)H(10)N(2))(H(2)O)(2)]·2H(2)O, the water-coordinated Cu(II) cation is O,N,O′-chelated by a pyridine-2,6-dicarboxyl­ate (pdc) dianion, and one pyridine N atom from a 1,2-bis­(4-pyrid­yl)ethene ligand coordinates to the Cu(II) cation, completing the CuN(2)O(3) distorted square-pyriamidial geometry. The Cu—O(water) bond [2.388 (4) Å] in the axial direction is much longer than the other Cu—O bonds. The 1,2-bis­(4-pyrid­yl)ethene ligand is located across an inversion center with the mid-point of the C=C bond at the inversion center, and bridges two Cu(II) cations, generating a centrosymmetric dinuclear complex. The crystal structure is stabilized by classical O—H⋯O and weak C—H⋯O hydrogen bonds. International Union of Crystallography 2011-05-20 /pmc/articles/PMC3120317/ /pubmed/21754658 http://dx.doi.org/10.1107/S1600536811018411 Text en © Shie Fu Lush 2011 http://creativecommons.org/licenses/by/2.0/uk/ This is an open-access article distributed under the terms of the Creative Commons Attribution Licence, which permits unrestricted use, distribution, and reproduction in any medium, provided the original authors and source are cited.
spellingShingle Metal-Organic Papers
Lush, Shie Fu
[μ-1,2-Bis(4-pyrid­yl)ethene-κ(2) N:N′]bis­[aqua­(pyridine-2,6-dicarboxyl­ato-κ(3) O (2),N,O (6))copper(II)] dihydrate
title [μ-1,2-Bis(4-pyrid­yl)ethene-κ(2) N:N′]bis­[aqua­(pyridine-2,6-dicarboxyl­ato-κ(3) O (2),N,O (6))copper(II)] dihydrate
title_full [μ-1,2-Bis(4-pyrid­yl)ethene-κ(2) N:N′]bis­[aqua­(pyridine-2,6-dicarboxyl­ato-κ(3) O (2),N,O (6))copper(II)] dihydrate
title_fullStr [μ-1,2-Bis(4-pyrid­yl)ethene-κ(2) N:N′]bis­[aqua­(pyridine-2,6-dicarboxyl­ato-κ(3) O (2),N,O (6))copper(II)] dihydrate
title_full_unstemmed [μ-1,2-Bis(4-pyrid­yl)ethene-κ(2) N:N′]bis­[aqua­(pyridine-2,6-dicarboxyl­ato-κ(3) O (2),N,O (6))copper(II)] dihydrate
title_short [μ-1,2-Bis(4-pyrid­yl)ethene-κ(2) N:N′]bis­[aqua­(pyridine-2,6-dicarboxyl­ato-κ(3) O (2),N,O (6))copper(II)] dihydrate
title_sort [μ-1,2-bis(4-pyrid­yl)ethene-κ(2) n:n′]bis­[aqua­(pyridine-2,6-dicarboxyl­ato-κ(3) o (2),n,o (6))copper(ii)] dihydrate
topic Metal-Organic Papers
url https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3120317/
https://www.ncbi.nlm.nih.gov/pubmed/21754658
http://dx.doi.org/10.1107/S1600536811018411
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