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Bis(2-methylbenzoato-κ(2) O,O′)(1,10′-phenanthroline-κ(2) N,N′)copper(II)
In the title compound, [Cu(C(8)H(7)O(2))(2)(C(12)H(8)N(2))], the Cu(II) atom assumes a distorted octahedral coordination geometry, chelated by two N atoms from the 1,10′-phenanthroline ligand and four O atoms from two 2-methylbenzoate anions. A significant Jahn–Teller distortion is observed with t...
Autores principales: | , , |
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Formato: | Online Artículo Texto |
Lenguaje: | English |
Publicado: |
International Union of Crystallography
2011
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Materias: | |
Acceso en línea: | https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3120328/ https://www.ncbi.nlm.nih.gov/pubmed/21754662 http://dx.doi.org/10.1107/S1600536811018162 |
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author | Ni, Sheng-Liang Zhou, Feng Qi, Jin-Li |
author_facet | Ni, Sheng-Liang Zhou, Feng Qi, Jin-Li |
author_sort | Ni, Sheng-Liang |
collection | PubMed |
description | In the title compound, [Cu(C(8)H(7)O(2))(2)(C(12)H(8)N(2))], the Cu(II) atom assumes a distorted octahedral coordination geometry, chelated by two N atoms from the 1,10′-phenanthroline ligand and four O atoms from two 2-methylbenzoate anions. A significant Jahn–Teller distortion is observed with two axial Cu—O distances significantly longer than those in the equatorial CuO(2)N(2) plane. In the crystal, π–π stacking interactions, with centroid–centroid distances of 3.547 (3) or 3.728 (3) Å between the phenanthroline rings, form layers parallel to (011). |
format | Online Article Text |
id | pubmed-3120328 |
institution | National Center for Biotechnology Information |
language | English |
publishDate | 2011 |
publisher | International Union of Crystallography |
record_format | MEDLINE/PubMed |
spelling | pubmed-31203282011-07-13 Bis(2-methylbenzoato-κ(2) O,O′)(1,10′-phenanthroline-κ(2) N,N′)copper(II) Ni, Sheng-Liang Zhou, Feng Qi, Jin-Li Acta Crystallogr Sect E Struct Rep Online Metal-Organic Papers In the title compound, [Cu(C(8)H(7)O(2))(2)(C(12)H(8)N(2))], the Cu(II) atom assumes a distorted octahedral coordination geometry, chelated by two N atoms from the 1,10′-phenanthroline ligand and four O atoms from two 2-methylbenzoate anions. A significant Jahn–Teller distortion is observed with two axial Cu—O distances significantly longer than those in the equatorial CuO(2)N(2) plane. In the crystal, π–π stacking interactions, with centroid–centroid distances of 3.547 (3) or 3.728 (3) Å between the phenanthroline rings, form layers parallel to (011). International Union of Crystallography 2011-05-20 /pmc/articles/PMC3120328/ /pubmed/21754662 http://dx.doi.org/10.1107/S1600536811018162 Text en © Ni et al. 2011 http://creativecommons.org/licenses/by/2.0/uk/ This is an open-access article distributed under the terms of the Creative Commons Attribution Licence, which permits unrestricted use, distribution, and reproduction in any medium, provided the original authors and source are cited. |
spellingShingle | Metal-Organic Papers Ni, Sheng-Liang Zhou, Feng Qi, Jin-Li Bis(2-methylbenzoato-κ(2) O,O′)(1,10′-phenanthroline-κ(2) N,N′)copper(II) |
title | Bis(2-methylbenzoato-κ(2)
O,O′)(1,10′-phenanthroline-κ(2)
N,N′)copper(II) |
title_full | Bis(2-methylbenzoato-κ(2)
O,O′)(1,10′-phenanthroline-κ(2)
N,N′)copper(II) |
title_fullStr | Bis(2-methylbenzoato-κ(2)
O,O′)(1,10′-phenanthroline-κ(2)
N,N′)copper(II) |
title_full_unstemmed | Bis(2-methylbenzoato-κ(2)
O,O′)(1,10′-phenanthroline-κ(2)
N,N′)copper(II) |
title_short | Bis(2-methylbenzoato-κ(2)
O,O′)(1,10′-phenanthroline-κ(2)
N,N′)copper(II) |
title_sort | bis(2-methylbenzoato-κ(2)
o,o′)(1,10′-phenanthroline-κ(2)
n,n′)copper(ii) |
topic | Metal-Organic Papers |
url | https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3120328/ https://www.ncbi.nlm.nih.gov/pubmed/21754662 http://dx.doi.org/10.1107/S1600536811018162 |
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