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Bis(2-methyl­benzoato-κ(2) O,O′)(1,10′-phenanthroline-κ(2) N,N′)copper(II)

In the title compound, [Cu(C(8)H(7)O(2))(2)(C(12)H(8)N(2))], the Cu(II) atom assumes a distorted octa­hedral coordination geometry, chelated by two N atoms from the 1,10′-phenanthroline ligand and four O atoms from two 2-methyl­benzoate anions. A significant Jahn–Teller distortion is observed with t...

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Detalles Bibliográficos
Autores principales: Ni, Sheng-Liang, Zhou, Feng, Qi, Jin-Li
Formato: Online Artículo Texto
Lenguaje:English
Publicado: International Union of Crystallography 2011
Materias:
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3120328/
https://www.ncbi.nlm.nih.gov/pubmed/21754662
http://dx.doi.org/10.1107/S1600536811018162
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author Ni, Sheng-Liang
Zhou, Feng
Qi, Jin-Li
author_facet Ni, Sheng-Liang
Zhou, Feng
Qi, Jin-Li
author_sort Ni, Sheng-Liang
collection PubMed
description In the title compound, [Cu(C(8)H(7)O(2))(2)(C(12)H(8)N(2))], the Cu(II) atom assumes a distorted octa­hedral coordination geometry, chelated by two N atoms from the 1,10′-phenanthroline ligand and four O atoms from two 2-methyl­benzoate anions. A significant Jahn–Teller distortion is observed with two axial Cu—O distances significantly longer than those in the equatorial CuO(2)N(2) plane. In the crystal, π–π stacking inter­actions, with centroid–centroid distances of 3.547 (3) or 3.728 (3) Å between the phenanthroline rings, form layers parallel to (011).
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spelling pubmed-31203282011-07-13 Bis(2-methyl­benzoato-κ(2) O,O′)(1,10′-phenanthroline-κ(2) N,N′)copper(II) Ni, Sheng-Liang Zhou, Feng Qi, Jin-Li Acta Crystallogr Sect E Struct Rep Online Metal-Organic Papers In the title compound, [Cu(C(8)H(7)O(2))(2)(C(12)H(8)N(2))], the Cu(II) atom assumes a distorted octa­hedral coordination geometry, chelated by two N atoms from the 1,10′-phenanthroline ligand and four O atoms from two 2-methyl­benzoate anions. A significant Jahn–Teller distortion is observed with two axial Cu—O distances significantly longer than those in the equatorial CuO(2)N(2) plane. In the crystal, π–π stacking inter­actions, with centroid–centroid distances of 3.547 (3) or 3.728 (3) Å between the phenanthroline rings, form layers parallel to (011). International Union of Crystallography 2011-05-20 /pmc/articles/PMC3120328/ /pubmed/21754662 http://dx.doi.org/10.1107/S1600536811018162 Text en © Ni et al. 2011 http://creativecommons.org/licenses/by/2.0/uk/ This is an open-access article distributed under the terms of the Creative Commons Attribution Licence, which permits unrestricted use, distribution, and reproduction in any medium, provided the original authors and source are cited.
spellingShingle Metal-Organic Papers
Ni, Sheng-Liang
Zhou, Feng
Qi, Jin-Li
Bis(2-methyl­benzoato-κ(2) O,O′)(1,10′-phenanthroline-κ(2) N,N′)copper(II)
title Bis(2-methyl­benzoato-κ(2) O,O′)(1,10′-phenanthroline-κ(2) N,N′)copper(II)
title_full Bis(2-methyl­benzoato-κ(2) O,O′)(1,10′-phenanthroline-κ(2) N,N′)copper(II)
title_fullStr Bis(2-methyl­benzoato-κ(2) O,O′)(1,10′-phenanthroline-κ(2) N,N′)copper(II)
title_full_unstemmed Bis(2-methyl­benzoato-κ(2) O,O′)(1,10′-phenanthroline-κ(2) N,N′)copper(II)
title_short Bis(2-methyl­benzoato-κ(2) O,O′)(1,10′-phenanthroline-κ(2) N,N′)copper(II)
title_sort bis(2-methyl­benzoato-κ(2) o,o′)(1,10′-phenanthroline-κ(2) n,n′)copper(ii)
topic Metal-Organic Papers
url https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3120328/
https://www.ncbi.nlm.nih.gov/pubmed/21754662
http://dx.doi.org/10.1107/S1600536811018162
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