Cargando…
Di-μ-benzoato-κ(3) O,O′:O;κ(3) O:O,O′-bis[(benzoato-κ(2) O,O′)(1,10-phenanthroline-κ(2) N,N′)lead(II)]
In the centrosymmetric dinuclear title compound, [Pb(2)(C(7)H(5)O(2))(4)(C(12)H(8)N(2))(2)], two Pb(2+) ions are connected by two tridentate bridging benzoate anions. The Pb(2+) ion is seven-coordinated by five O atoms from three benzoate anions and two N atoms from the 1,10-phenanthroline ligands....
| Autores principales: | , , |
|---|---|
| Formato: | Online Artículo Texto |
| Lenguaje: | English |
| Publicado: |
International Union of Crystallography
2011
|
| Materias: | |
| Acceso en línea: | https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3120329/ https://www.ncbi.nlm.nih.gov/pubmed/21754661 http://dx.doi.org/10.1107/S160053681101840X |
| _version_ | 1782206654582882304 |
|---|---|
| author | Li, Hong-Jin Gao, Zhu-Qing Gu, Jin-Zhong |
| author_facet | Li, Hong-Jin Gao, Zhu-Qing Gu, Jin-Zhong |
| author_sort | Li, Hong-Jin |
| collection | PubMed |
| description | In the centrosymmetric dinuclear title compound, [Pb(2)(C(7)H(5)O(2))(4)(C(12)H(8)N(2))(2)], two Pb(2+) ions are connected by two tridentate bridging benzoate anions. The Pb(2+) ion is seven-coordinated by five O atoms from three benzoate anions and two N atoms from the 1,10-phenanthroline ligands. The benzoate anions adopt two different coordination modes, one bidentate–chelating and one tridentate bridging–chelating. The three-dimensional supramolecular framework is achieved by intermolecular π–π stacking interactions, with a shortest centroid–centroid distance of 3.617 (4) Å. |
| format | Online Article Text |
| id | pubmed-3120329 |
| institution | National Center for Biotechnology Information |
| language | English |
| publishDate | 2011 |
| publisher | International Union of Crystallography |
| record_format | MEDLINE/PubMed |
| spelling | pubmed-31203292011-07-13 Di-μ-benzoato-κ(3) O,O′:O;κ(3) O:O,O′-bis[(benzoato-κ(2) O,O′)(1,10-phenanthroline-κ(2) N,N′)lead(II)] Li, Hong-Jin Gao, Zhu-Qing Gu, Jin-Zhong Acta Crystallogr Sect E Struct Rep Online Metal-Organic Papers In the centrosymmetric dinuclear title compound, [Pb(2)(C(7)H(5)O(2))(4)(C(12)H(8)N(2))(2)], two Pb(2+) ions are connected by two tridentate bridging benzoate anions. The Pb(2+) ion is seven-coordinated by five O atoms from three benzoate anions and two N atoms from the 1,10-phenanthroline ligands. The benzoate anions adopt two different coordination modes, one bidentate–chelating and one tridentate bridging–chelating. The three-dimensional supramolecular framework is achieved by intermolecular π–π stacking interactions, with a shortest centroid–centroid distance of 3.617 (4) Å. International Union of Crystallography 2011-05-20 /pmc/articles/PMC3120329/ /pubmed/21754661 http://dx.doi.org/10.1107/S160053681101840X Text en © Li et al. 2011 http://creativecommons.org/licenses/by/2.0/uk/ This is an open-access article distributed under the terms of the Creative Commons Attribution Licence, which permits unrestricted use, distribution, and reproduction in any medium, provided the original authors and source are cited. |
| spellingShingle | Metal-Organic Papers Li, Hong-Jin Gao, Zhu-Qing Gu, Jin-Zhong Di-μ-benzoato-κ(3) O,O′:O;κ(3) O:O,O′-bis[(benzoato-κ(2) O,O′)(1,10-phenanthroline-κ(2) N,N′)lead(II)] |
| title | Di-μ-benzoato-κ(3)
O,O′:O;κ(3)
O:O,O′-bis[(benzoato-κ(2)
O,O′)(1,10-phenanthroline-κ(2)
N,N′)lead(II)] |
| title_full | Di-μ-benzoato-κ(3)
O,O′:O;κ(3)
O:O,O′-bis[(benzoato-κ(2)
O,O′)(1,10-phenanthroline-κ(2)
N,N′)lead(II)] |
| title_fullStr | Di-μ-benzoato-κ(3)
O,O′:O;κ(3)
O:O,O′-bis[(benzoato-κ(2)
O,O′)(1,10-phenanthroline-κ(2)
N,N′)lead(II)] |
| title_full_unstemmed | Di-μ-benzoato-κ(3)
O,O′:O;κ(3)
O:O,O′-bis[(benzoato-κ(2)
O,O′)(1,10-phenanthroline-κ(2)
N,N′)lead(II)] |
| title_short | Di-μ-benzoato-κ(3)
O,O′:O;κ(3)
O:O,O′-bis[(benzoato-κ(2)
O,O′)(1,10-phenanthroline-κ(2)
N,N′)lead(II)] |
| title_sort | di-μ-benzoato-κ(3)
o,o′:o;κ(3)
o:o,o′-bis[(benzoato-κ(2)
o,o′)(1,10-phenanthroline-κ(2)
n,n′)lead(ii)] |
| topic | Metal-Organic Papers |
| url | https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3120329/ https://www.ncbi.nlm.nih.gov/pubmed/21754661 http://dx.doi.org/10.1107/S160053681101840X |
| work_keys_str_mv | AT lihongjin dimbenzoatok3oook3ooobisbenzoatok2oo110phenanthrolinek2nnleadii AT gaozhuqing dimbenzoatok3oook3ooobisbenzoatok2oo110phenanthrolinek2nnleadii AT gujinzhong dimbenzoatok3oook3ooobisbenzoatok2oo110phenanthrolinek2nnleadii |