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Diaqua[5,5′-dicarboxy-2,2′-(ethane-1,2-diyl)bis(1H-imidazole-4-carboxylato)]cobalt(II)
In the title complex, [Co(C(12)H(8)N(4)O(8))(H(2)O)(2)], the Co(II) atom is coordinated by two N and two O atoms of the tetradentate 5,5′-dicarboxy-2,2′-(ethane-1,2-diyl)bis(1H-imidazole-4-carboxylate) anion. The slightly distorted octahedral coordination environment is completed by the O ato...
Autores principales: | , |
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Formato: | Online Artículo Texto |
Lenguaje: | English |
Publicado: |
International Union of Crystallography
2011
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Materias: | |
Acceso en línea: | https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3120334/ https://www.ncbi.nlm.nih.gov/pubmed/21754687 http://dx.doi.org/10.1107/S1600536811019672 |
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author | Wang, Ying Gao, Xin-Lian |
author_facet | Wang, Ying Gao, Xin-Lian |
author_sort | Wang, Ying |
collection | PubMed |
description | In the title complex, [Co(C(12)H(8)N(4)O(8))(H(2)O)(2)], the Co(II) atom is coordinated by two N and two O atoms of the tetradentate 5,5′-dicarboxy-2,2′-(ethane-1,2-diyl)bis(1H-imidazole-4-carboxylate) anion. The slightly distorted octahedral coordination environment is completed by the O atoms of two water molecules in axial positions. An intramolecular O—H⋯O hydrogen bond between the carboxy and carboxylate groups stabilizes the molecular configuration. Adjacent molecules are linked through O—H⋯O and N—H⋯O hydrogen bonds between the carboxy/carboxylate groups, water molecules and imidazole fragments into a three-dimensional network. |
format | Online Article Text |
id | pubmed-3120334 |
institution | National Center for Biotechnology Information |
language | English |
publishDate | 2011 |
publisher | International Union of Crystallography |
record_format | MEDLINE/PubMed |
spelling | pubmed-31203342011-07-13 Diaqua[5,5′-dicarboxy-2,2′-(ethane-1,2-diyl)bis(1H-imidazole-4-carboxylato)]cobalt(II) Wang, Ying Gao, Xin-Lian Acta Crystallogr Sect E Struct Rep Online Metal-Organic Papers In the title complex, [Co(C(12)H(8)N(4)O(8))(H(2)O)(2)], the Co(II) atom is coordinated by two N and two O atoms of the tetradentate 5,5′-dicarboxy-2,2′-(ethane-1,2-diyl)bis(1H-imidazole-4-carboxylate) anion. The slightly distorted octahedral coordination environment is completed by the O atoms of two water molecules in axial positions. An intramolecular O—H⋯O hydrogen bond between the carboxy and carboxylate groups stabilizes the molecular configuration. Adjacent molecules are linked through O—H⋯O and N—H⋯O hydrogen bonds between the carboxy/carboxylate groups, water molecules and imidazole fragments into a three-dimensional network. International Union of Crystallography 2011-05-28 /pmc/articles/PMC3120334/ /pubmed/21754687 http://dx.doi.org/10.1107/S1600536811019672 Text en © Wang and Gao 2011 http://creativecommons.org/licenses/by/2.0/uk/ This is an open-access article distributed under the terms of the Creative Commons Attribution Licence, which permits unrestricted use, distribution, and reproduction in any medium, provided the original authors and source are cited. |
spellingShingle | Metal-Organic Papers Wang, Ying Gao, Xin-Lian Diaqua[5,5′-dicarboxy-2,2′-(ethane-1,2-diyl)bis(1H-imidazole-4-carboxylato)]cobalt(II) |
title | Diaqua[5,5′-dicarboxy-2,2′-(ethane-1,2-diyl)bis(1H-imidazole-4-carboxylato)]cobalt(II) |
title_full | Diaqua[5,5′-dicarboxy-2,2′-(ethane-1,2-diyl)bis(1H-imidazole-4-carboxylato)]cobalt(II) |
title_fullStr | Diaqua[5,5′-dicarboxy-2,2′-(ethane-1,2-diyl)bis(1H-imidazole-4-carboxylato)]cobalt(II) |
title_full_unstemmed | Diaqua[5,5′-dicarboxy-2,2′-(ethane-1,2-diyl)bis(1H-imidazole-4-carboxylato)]cobalt(II) |
title_short | Diaqua[5,5′-dicarboxy-2,2′-(ethane-1,2-diyl)bis(1H-imidazole-4-carboxylato)]cobalt(II) |
title_sort | diaqua[5,5′-dicarboxy-2,2′-(ethane-1,2-diyl)bis(1h-imidazole-4-carboxylato)]cobalt(ii) |
topic | Metal-Organic Papers |
url | https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3120334/ https://www.ncbi.nlm.nih.gov/pubmed/21754687 http://dx.doi.org/10.1107/S1600536811019672 |
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