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Diaqua­[5,5′-dicarb­oxy-2,2′-(ethane-1,2-di­yl)bis­(1H-imidazole-4-carboxyl­ato)]cobalt(II)

In the title complex, [Co(C(12)H(8)N(4)O(8))(H(2)O)(2)], the Co(II) atom is coordinated by two N and two O atoms of the tetra­dentate 5,5′-dicarb­oxy-2,2′-(ethane-1,2-di­yl)bis­(1H-imidazole-4-carboxy­l­ate) anion. The slightly distorted octa­hedral coordination environment is completed by the O ato...

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Autores principales: Wang, Ying, Gao, Xin-Lian
Formato: Online Artículo Texto
Lenguaje:English
Publicado: International Union of Crystallography 2011
Materias:
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3120334/
https://www.ncbi.nlm.nih.gov/pubmed/21754687
http://dx.doi.org/10.1107/S1600536811019672
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author Wang, Ying
Gao, Xin-Lian
author_facet Wang, Ying
Gao, Xin-Lian
author_sort Wang, Ying
collection PubMed
description In the title complex, [Co(C(12)H(8)N(4)O(8))(H(2)O)(2)], the Co(II) atom is coordinated by two N and two O atoms of the tetra­dentate 5,5′-dicarb­oxy-2,2′-(ethane-1,2-di­yl)bis­(1H-imidazole-4-carboxy­l­ate) anion. The slightly distorted octa­hedral coordination environment is completed by the O atoms of two water mol­ecules in axial positions. An intra­molecular O—H⋯O hydrogen bond between the carb­oxy and carboxyl­ate groups stabilizes the mol­ecular configuration. Adjacent mol­ecules are linked through O—H⋯O and N—H⋯O hydrogen bonds between the carb­oxy/carboxyl­ate groups, water mol­ecules and imidazole fragments into a three-dimensional network.
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spelling pubmed-31203342011-07-13 Diaqua­[5,5′-dicarb­oxy-2,2′-(ethane-1,2-di­yl)bis­(1H-imidazole-4-carboxyl­ato)]cobalt(II) Wang, Ying Gao, Xin-Lian Acta Crystallogr Sect E Struct Rep Online Metal-Organic Papers In the title complex, [Co(C(12)H(8)N(4)O(8))(H(2)O)(2)], the Co(II) atom is coordinated by two N and two O atoms of the tetra­dentate 5,5′-dicarb­oxy-2,2′-(ethane-1,2-di­yl)bis­(1H-imidazole-4-carboxy­l­ate) anion. The slightly distorted octa­hedral coordination environment is completed by the O atoms of two water mol­ecules in axial positions. An intra­molecular O—H⋯O hydrogen bond between the carb­oxy and carboxyl­ate groups stabilizes the mol­ecular configuration. Adjacent mol­ecules are linked through O—H⋯O and N—H⋯O hydrogen bonds between the carb­oxy/carboxyl­ate groups, water mol­ecules and imidazole fragments into a three-dimensional network. International Union of Crystallography 2011-05-28 /pmc/articles/PMC3120334/ /pubmed/21754687 http://dx.doi.org/10.1107/S1600536811019672 Text en © Wang and Gao 2011 http://creativecommons.org/licenses/by/2.0/uk/ This is an open-access article distributed under the terms of the Creative Commons Attribution Licence, which permits unrestricted use, distribution, and reproduction in any medium, provided the original authors and source are cited.
spellingShingle Metal-Organic Papers
Wang, Ying
Gao, Xin-Lian
Diaqua­[5,5′-dicarb­oxy-2,2′-(ethane-1,2-di­yl)bis­(1H-imidazole-4-carboxyl­ato)]cobalt(II)
title Diaqua­[5,5′-dicarb­oxy-2,2′-(ethane-1,2-di­yl)bis­(1H-imidazole-4-carboxyl­ato)]cobalt(II)
title_full Diaqua­[5,5′-dicarb­oxy-2,2′-(ethane-1,2-di­yl)bis­(1H-imidazole-4-carboxyl­ato)]cobalt(II)
title_fullStr Diaqua­[5,5′-dicarb­oxy-2,2′-(ethane-1,2-di­yl)bis­(1H-imidazole-4-carboxyl­ato)]cobalt(II)
title_full_unstemmed Diaqua­[5,5′-dicarb­oxy-2,2′-(ethane-1,2-di­yl)bis­(1H-imidazole-4-carboxyl­ato)]cobalt(II)
title_short Diaqua­[5,5′-dicarb­oxy-2,2′-(ethane-1,2-di­yl)bis­(1H-imidazole-4-carboxyl­ato)]cobalt(II)
title_sort diaqua­[5,5′-dicarb­oxy-2,2′-(ethane-1,2-di­yl)bis­(1h-imidazole-4-carboxyl­ato)]cobalt(ii)
topic Metal-Organic Papers
url https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3120334/
https://www.ncbi.nlm.nih.gov/pubmed/21754687
http://dx.doi.org/10.1107/S1600536811019672
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