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(Acetyl­acetonato)dibromido[2,2-diphenyl­hydrazin-1-ido(1−)][2,2-diphenyl­hydrazin-1-ido(2−)]molybdenum(VI)

In the title compound, [MoBr(2)(C(12)H(11)N(2))(C(12)H(10)N(2))(C(5)H(7)O(2))], the Mo(VI) atom is six-coordinated in a distorted octa­hedral geometry by two N atoms from the diphenyl­hydrazide(1−) and diphenyl­hydrazide(2−) ligands, two O atoms from a bidentate acetyl­acetonate ligand and two Br(−)...

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Autores principales: Bustos, Carlos, Alvarez-Thon, Luis, Ibañez, Andrés, Sánchez, Christian
Formato: Online Artículo Texto
Lenguaje:English
Publicado: International Union of Crystallography 2011
Materias:
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3120344/
https://www.ncbi.nlm.nih.gov/pubmed/21754584
http://dx.doi.org/10.1107/S1600536811015881
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author Bustos, Carlos
Alvarez-Thon, Luis
Ibañez, Andrés
Sánchez, Christian
author_facet Bustos, Carlos
Alvarez-Thon, Luis
Ibañez, Andrés
Sánchez, Christian
author_sort Bustos, Carlos
collection PubMed
description In the title compound, [MoBr(2)(C(12)H(11)N(2))(C(12)H(10)N(2))(C(5)H(7)O(2))], the Mo(VI) atom is six-coordinated in a distorted octa­hedral geometry by two N atoms from the diphenyl­hydrazide(1−) and diphenyl­hydrazide(2−) ligands, two O atoms from a bidentate acetyl­acetonate ligand and two Br(−) ions. The mol­ecules form an inversion dimer via a pair of weak C—H⋯O hydrogen bonds and a π–π stacking inter­action with a centroid–centroid distance of 3.7401 (12) Å. Weak intra­molecular C—H⋯Br inter­actions and an intra­molecular π–π stacking inter­action with a centroid–centroid distance of 3.8118 (15) Å are also observed.
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spelling pubmed-31203442011-07-13 (Acetyl­acetonato)dibromido[2,2-diphenyl­hydrazin-1-ido(1−)][2,2-diphenyl­hydrazin-1-ido(2−)]molybdenum(VI) Bustos, Carlos Alvarez-Thon, Luis Ibañez, Andrés Sánchez, Christian Acta Crystallogr Sect E Struct Rep Online Metal-Organic Papers In the title compound, [MoBr(2)(C(12)H(11)N(2))(C(12)H(10)N(2))(C(5)H(7)O(2))], the Mo(VI) atom is six-coordinated in a distorted octa­hedral geometry by two N atoms from the diphenyl­hydrazide(1−) and diphenyl­hydrazide(2−) ligands, two O atoms from a bidentate acetyl­acetonate ligand and two Br(−) ions. The mol­ecules form an inversion dimer via a pair of weak C—H⋯O hydrogen bonds and a π–π stacking inter­action with a centroid–centroid distance of 3.7401 (12) Å. Weak intra­molecular C—H⋯Br inter­actions and an intra­molecular π–π stacking inter­action with a centroid–centroid distance of 3.8118 (15) Å are also observed. International Union of Crystallography 2011-05-07 /pmc/articles/PMC3120344/ /pubmed/21754584 http://dx.doi.org/10.1107/S1600536811015881 Text en © Bustos et al. 2011 http://creativecommons.org/licenses/by/2.0/uk/ This is an open-access article distributed under the terms of the Creative Commons Attribution Licence, which permits unrestricted use, distribution, and reproduction in any medium, provided the original authors and source are cited.
spellingShingle Metal-Organic Papers
Bustos, Carlos
Alvarez-Thon, Luis
Ibañez, Andrés
Sánchez, Christian
(Acetyl­acetonato)dibromido[2,2-diphenyl­hydrazin-1-ido(1−)][2,2-diphenyl­hydrazin-1-ido(2−)]molybdenum(VI)
title (Acetyl­acetonato)dibromido[2,2-diphenyl­hydrazin-1-ido(1−)][2,2-diphenyl­hydrazin-1-ido(2−)]molybdenum(VI)
title_full (Acetyl­acetonato)dibromido[2,2-diphenyl­hydrazin-1-ido(1−)][2,2-diphenyl­hydrazin-1-ido(2−)]molybdenum(VI)
title_fullStr (Acetyl­acetonato)dibromido[2,2-diphenyl­hydrazin-1-ido(1−)][2,2-diphenyl­hydrazin-1-ido(2−)]molybdenum(VI)
title_full_unstemmed (Acetyl­acetonato)dibromido[2,2-diphenyl­hydrazin-1-ido(1−)][2,2-diphenyl­hydrazin-1-ido(2−)]molybdenum(VI)
title_short (Acetyl­acetonato)dibromido[2,2-diphenyl­hydrazin-1-ido(1−)][2,2-diphenyl­hydrazin-1-ido(2−)]molybdenum(VI)
title_sort (acetyl­acetonato)dibromido[2,2-diphenyl­hydrazin-1-ido(1−)][2,2-diphenyl­hydrazin-1-ido(2−)]molybdenum(vi)
topic Metal-Organic Papers
url https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3120344/
https://www.ncbi.nlm.nih.gov/pubmed/21754584
http://dx.doi.org/10.1107/S1600536811015881
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