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Poly[diacetonitrile[μ(3)-difluoro(oxalato)borato]sodium]
The title compound, [Na(C(2)BF(2)O(4))(CH(3)CN)(2)](n), forms infinite two-dimensional layers running parallel to (010). The layers lie across crystallographic mirror planes at y = 1/4 and 3/4. The Na, B and two F atoms reside on these mirror planes. The Na(+) cations are six-coordinate. Two equator...
Autores principales: | , , |
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Formato: | Online Artículo Texto |
Lenguaje: | English |
Publicado: |
International Union of Crystallography
2011
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Materias: | |
Acceso en línea: | https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3120346/ https://www.ncbi.nlm.nih.gov/pubmed/21754586 http://dx.doi.org/10.1107/S1600536811015091 |
Sumario: | The title compound, [Na(C(2)BF(2)O(4))(CH(3)CN)(2)](n), forms infinite two-dimensional layers running parallel to (010). The layers lie across crystallographic mirror planes at y = 1/4 and 3/4. The Na, B and two F atoms reside on these mirror planes. The Na(+) cations are six-coordinate. Two equatorial coordination positions are occupied by acetonitrile molecules. The other two equatorial coordination sites are occupied by the chelating O atoms from the difluoro(oxalato)borate anion (DFOB(−)). The axial coordination sites are occupied by two F atoms from two different DFOB(−) anions. |
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