Poly[diacetonitrile­[μ(3)-difluoro­(oxalato)borato]sodium]

The title compound, [Na(C(2)BF(2)O(4))(CH(3)CN)(2)](n), forms infinite two-dimensional layers running parallel to (010). The layers lie across crystallographic mirror planes at y = 1/4 and 3/4. The Na, B and two F atoms reside on these mirror planes. The Na(+) cations are six-coordinate. Two equator...

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Detalles Bibliográficos
Autores principales: Allen, Joshua L., Boyle, Paul D., Henderson, Wesley A.
Formato: Online Artículo Texto
Lenguaje:English
Publicado: International Union of Crystallography 2011
Materias:
Metal-Organic Papers
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3120346/
https://www.ncbi.nlm.nih.gov/pubmed/21754586
http://dx.doi.org/10.1107/S1600536811015091
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author Allen, Joshua L.
Boyle, Paul D.
Henderson, Wesley A.
author_facet Allen, Joshua L.
Boyle, Paul D.
Henderson, Wesley A.
author_sort Allen, Joshua L.
collection PubMed
description The title compound, [Na(C(2)BF(2)O(4))(CH(3)CN)(2)](n), forms infinite two-dimensional layers running parallel to (010). The layers lie across crystallographic mirror planes at y = 1/4 and 3/4. The Na, B and two F atoms reside on these mirror planes. The Na(+) cations are six-coordinate. Two equatorial coordination positions are occupied by acetonitrile mol­ecules. The other two equatorial coordination sites are occupied by the chelating O atoms from the difluoro­(oxalato)borate anion (DFOB(−)). The axial coordination sites are occupied by two F atoms from two different DFOB(−) anions.
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spelling pubmed-31203462011-07-13 Poly[diacetonitrile­[μ(3)-difluoro­(oxalato)borato]sodium] Allen, Joshua L. Boyle, Paul D. Henderson, Wesley A. Acta Crystallogr Sect E Struct Rep Online Metal-Organic Papers The title compound, [Na(C(2)BF(2)O(4))(CH(3)CN)(2)](n), forms infinite two-dimensional layers running parallel to (010). The layers lie across crystallographic mirror planes at y = 1/4 and 3/4. The Na, B and two F atoms reside on these mirror planes. The Na(+) cations are six-coordinate. Two equatorial coordination positions are occupied by acetonitrile mol­ecules. The other two equatorial coordination sites are occupied by the chelating O atoms from the difluoro­(oxalato)borate anion (DFOB(−)). The axial coordination sites are occupied by two F atoms from two different DFOB(−) anions. International Union of Crystallography 2011-05-07 /pmc/articles/PMC3120346/ /pubmed/21754586 http://dx.doi.org/10.1107/S1600536811015091 Text en © Allen et al. 2011 http://creativecommons.org/licenses/by/2.0/uk/ This is an open-access article distributed under the terms of the Creative Commons Attribution Licence, which permits unrestricted use, distribution, and reproduction in any medium, provided the original authors and source are cited.
spellingShingle Metal-Organic Papers
Allen, Joshua L.
Boyle, Paul D.
Henderson, Wesley A.
Poly[diacetonitrile­[μ(3)-difluoro­(oxalato)borato]sodium]
title Poly[diacetonitrile­[μ(3)-difluoro­(oxalato)borato]sodium]
title_full Poly[diacetonitrile­[μ(3)-difluoro­(oxalato)borato]sodium]
title_fullStr Poly[diacetonitrile­[μ(3)-difluoro­(oxalato)borato]sodium]
title_full_unstemmed Poly[diacetonitrile­[μ(3)-difluoro­(oxalato)borato]sodium]
title_short Poly[diacetonitrile­[μ(3)-difluoro­(oxalato)borato]sodium]
title_sort poly[diacetonitrile­[μ(3)-difluoro­(oxalato)borato]sodium]
topic Metal-Organic Papers
url https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3120346/
https://www.ncbi.nlm.nih.gov/pubmed/21754586
http://dx.doi.org/10.1107/S1600536811015091
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AT hendersonwesleya polydiacetonitrilem3difluorooxalatoboratosodium

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