(Z)-N-(2-Chloro­benzyl­idene)aniline N-oxide

In the title compound, C(13)H(10)ClNO, the central C—N bond has considerable double-bond character and the N—O bond indicates a formal negative charge on the O atom. The mol­ecule is stabilized by an intra­molecular C—H⋯O hydrogen bond. The geometry about the C=N bond is Z [C—C—N—O torsion angle = −...

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Detalles Bibliográficos
Autores principales: Fu, Ying, Liu, Yanhua, Yang, Yanshou, Chen, Yaojuan
Formato: Online Artículo Texto
Lenguaje:English
Publicado: International Union of Crystallography 2011
Materias:
Organic Papers
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3120351/
https://www.ncbi.nlm.nih.gov/pubmed/21754718
http://dx.doi.org/10.1107/S1600536811015923
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author Fu, Ying
Liu, Yanhua
Yang, Yanshou
Chen, Yaojuan
author_facet Fu, Ying
Liu, Yanhua
Yang, Yanshou
Chen, Yaojuan
author_sort Fu, Ying
collection PubMed
description In the title compound, C(13)H(10)ClNO, the central C—N bond has considerable double-bond character and the N—O bond indicates a formal negative charge on the O atom. The mol­ecule is stabilized by an intra­molecular C—H⋯O hydrogen bond. The geometry about the C=N bond is Z [C—C—N—O torsion angle = −4.2 (3)°] and the phenyl and benzene rings are trans-oriented around the C=N bond. The phenyl and benzene rings make a dihedral angle of 56.99 (2)°.
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spelling pubmed-31203512011-07-13 (Z)-N-(2-Chloro­benzyl­idene)aniline N-oxide Fu, Ying Liu, Yanhua Yang, Yanshou Chen, Yaojuan Acta Crystallogr Sect E Struct Rep Online Organic Papers In the title compound, C(13)H(10)ClNO, the central C—N bond has considerable double-bond character and the N—O bond indicates a formal negative charge on the O atom. The mol­ecule is stabilized by an intra­molecular C—H⋯O hydrogen bond. The geometry about the C=N bond is Z [C—C—N—O torsion angle = −4.2 (3)°] and the phenyl and benzene rings are trans-oriented around the C=N bond. The phenyl and benzene rings make a dihedral angle of 56.99 (2)°. International Union of Crystallography 2011-05-07 /pmc/articles/PMC3120351/ /pubmed/21754718 http://dx.doi.org/10.1107/S1600536811015923 Text en © Fu et al. 2011 http://creativecommons.org/licenses/by/2.0/uk/ This is an open-access article distributed under the terms of the Creative Commons Attribution Licence, which permits unrestricted use, distribution, and reproduction in any medium, provided the original authors and source are cited.
spellingShingle Organic Papers
Fu, Ying
Liu, Yanhua
Yang, Yanshou
Chen, Yaojuan
(Z)-N-(2-Chloro­benzyl­idene)aniline N-oxide
title (Z)-N-(2-Chloro­benzyl­idene)aniline N-oxide
title_full (Z)-N-(2-Chloro­benzyl­idene)aniline N-oxide
title_fullStr (Z)-N-(2-Chloro­benzyl­idene)aniline N-oxide
title_full_unstemmed (Z)-N-(2-Chloro­benzyl­idene)aniline N-oxide
title_short (Z)-N-(2-Chloro­benzyl­idene)aniline N-oxide
title_sort (z)-n-(2-chloro­benzyl­idene)aniline n-oxide
topic Organic Papers
url https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3120351/
https://www.ncbi.nlm.nih.gov/pubmed/21754718
http://dx.doi.org/10.1107/S1600536811015923
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AT liuyanhua zn2chlorobenzylideneanilinenoxide
AT yangyanshou zn2chlorobenzylideneanilinenoxide
AT chenyaojuan zn2chlorobenzylideneanilinenoxide

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