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[N′-(5-Chloro-2-oxidobenzyl-κO)-2,4-dihydroxybenzohydrazidato-κ(2) N′,O](methanol-κO)dioxidomolybdenum(VI)–4,4′-bipyridine (1/1)
In the title co-crystal, [Mo(C(14)H(9)ClN(2)O(4))O(2)(CH(3)OH)]·C(10)H(8)N(2), the deprotonated Schiff base O,N,O′-chelates to the Mo(VI) atom, the three atoms involved in chelation comprising the fac sites of the octahedron surrounding the methanol-coordinated metal atom. The methanol molecule fo...
Autores principales: | , , , |
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Formato: | Online Artículo Texto |
Lenguaje: | English |
Publicado: |
International Union of Crystallography
2011
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Materias: | |
Acceso en línea: | https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3120353/ https://www.ncbi.nlm.nih.gov/pubmed/21754638 http://dx.doi.org/10.1107/S1600536811017259 |
Sumario: | In the title co-crystal, [Mo(C(14)H(9)ClN(2)O(4))O(2)(CH(3)OH)]·C(10)H(8)N(2), the deprotonated Schiff base O,N,O′-chelates to the Mo(VI) atom, the three atoms involved in chelation comprising the fac sites of the octahedron surrounding the methanol-coordinated metal atom. The methanol molecule forms an O—H⋯N hydrogen bond to an N atom of the 4,4′-bipyridine solvent molecule; the hydroxy group of the Schiff base forms an O—H⋯N hydrogen bond to the other N atom of another molecule. The two hydrogen bonds leading to the formation of a helical chain running along the b axis. |
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