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[N′-(5-Chloro-2-oxidobenzyl-κO)-2,4-dihy­droxy­benzohydrazidato-κ(2) N′,O](methanol-κO)dioxidomolybdenum(VI)–4,4′-bipyridine (1/1)

In the title co-crystal, [Mo(C(14)H(9)ClN(2)O(4))O(2)(CH(3)OH)]·C(10)H(8)N(2), the deprotonated Schiff base O,N,O′-chelates to the Mo(VI) atom, the three atoms involved in chelation comprising the fac sites of the octa­hedron surrounding the methanol-coordinated metal atom. The methanol mol­ecule fo...

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Autores principales: Ngan, Ngui Khiong, Wong, Richard Chee Seng, Lo, Kong Mun, Ng, Seik Weng
Formato: Online Artículo Texto
Lenguaje:English
Publicado: International Union of Crystallography 2011
Materias:
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3120353/
https://www.ncbi.nlm.nih.gov/pubmed/21754638
http://dx.doi.org/10.1107/S1600536811017259
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author Ngan, Ngui Khiong
Wong, Richard Chee Seng
Lo, Kong Mun
Ng, Seik Weng
author_facet Ngan, Ngui Khiong
Wong, Richard Chee Seng
Lo, Kong Mun
Ng, Seik Weng
author_sort Ngan, Ngui Khiong
collection PubMed
description In the title co-crystal, [Mo(C(14)H(9)ClN(2)O(4))O(2)(CH(3)OH)]·C(10)H(8)N(2), the deprotonated Schiff base O,N,O′-chelates to the Mo(VI) atom, the three atoms involved in chelation comprising the fac sites of the octa­hedron surrounding the methanol-coordinated metal atom. The methanol mol­ecule forms an O—H⋯N hydrogen bond to an N atom of the 4,4′-bipyridine solvent mol­ecule; the hy­droxy group of the Schiff base forms an O—H⋯N hydrogen bond to the other N atom of another mol­ecule. The two hydrogen bonds leading to the formation of a helical chain running along the b axis.
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spelling pubmed-31203532011-07-13 [N′-(5-Chloro-2-oxidobenzyl-κO)-2,4-dihy­droxy­benzohydrazidato-κ(2) N′,O](methanol-κO)dioxidomolybdenum(VI)–4,4′-bipyridine (1/1) Ngan, Ngui Khiong Wong, Richard Chee Seng Lo, Kong Mun Ng, Seik Weng Acta Crystallogr Sect E Struct Rep Online Metal-Organic Papers In the title co-crystal, [Mo(C(14)H(9)ClN(2)O(4))O(2)(CH(3)OH)]·C(10)H(8)N(2), the deprotonated Schiff base O,N,O′-chelates to the Mo(VI) atom, the three atoms involved in chelation comprising the fac sites of the octa­hedron surrounding the methanol-coordinated metal atom. The methanol mol­ecule forms an O—H⋯N hydrogen bond to an N atom of the 4,4′-bipyridine solvent mol­ecule; the hy­droxy group of the Schiff base forms an O—H⋯N hydrogen bond to the other N atom of another mol­ecule. The two hydrogen bonds leading to the formation of a helical chain running along the b axis. International Union of Crystallography 2011-05-14 /pmc/articles/PMC3120353/ /pubmed/21754638 http://dx.doi.org/10.1107/S1600536811017259 Text en © Ngan et al. 2011 http://creativecommons.org/licenses/by/2.0/uk/ This is an open-access article distributed under the terms of the Creative Commons Attribution Licence, which permits unrestricted use, distribution, and reproduction in any medium, provided the original authors and source are cited.
spellingShingle Metal-Organic Papers
Ngan, Ngui Khiong
Wong, Richard Chee Seng
Lo, Kong Mun
Ng, Seik Weng
[N′-(5-Chloro-2-oxidobenzyl-κO)-2,4-dihy­droxy­benzohydrazidato-κ(2) N′,O](methanol-κO)dioxidomolybdenum(VI)–4,4′-bipyridine (1/1)
title [N′-(5-Chloro-2-oxidobenzyl-κO)-2,4-dihy­droxy­benzohydrazidato-κ(2) N′,O](methanol-κO)dioxidomolybdenum(VI)–4,4′-bipyridine (1/1)
title_full [N′-(5-Chloro-2-oxidobenzyl-κO)-2,4-dihy­droxy­benzohydrazidato-κ(2) N′,O](methanol-κO)dioxidomolybdenum(VI)–4,4′-bipyridine (1/1)
title_fullStr [N′-(5-Chloro-2-oxidobenzyl-κO)-2,4-dihy­droxy­benzohydrazidato-κ(2) N′,O](methanol-κO)dioxidomolybdenum(VI)–4,4′-bipyridine (1/1)
title_full_unstemmed [N′-(5-Chloro-2-oxidobenzyl-κO)-2,4-dihy­droxy­benzohydrazidato-κ(2) N′,O](methanol-κO)dioxidomolybdenum(VI)–4,4′-bipyridine (1/1)
title_short [N′-(5-Chloro-2-oxidobenzyl-κO)-2,4-dihy­droxy­benzohydrazidato-κ(2) N′,O](methanol-κO)dioxidomolybdenum(VI)–4,4′-bipyridine (1/1)
title_sort [n′-(5-chloro-2-oxidobenzyl-κo)-2,4-dihy­droxy­benzohydrazidato-κ(2) n′,o](methanol-κo)dioxidomolybdenum(vi)–4,4′-bipyridine (1/1)
topic Metal-Organic Papers
url https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3120353/
https://www.ncbi.nlm.nih.gov/pubmed/21754638
http://dx.doi.org/10.1107/S1600536811017259
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