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[N′-(5-Chloro-2-oxidobenzyl-κO)-2,4-dihydroxybenzohydrazidato-κ(2) N′,O](methanol-κO)dioxidomolybdenum(VI)–4,4′-bipyridine (1/1)
In the title co-crystal, [Mo(C(14)H(9)ClN(2)O(4))O(2)(CH(3)OH)]·C(10)H(8)N(2), the deprotonated Schiff base O,N,O′-chelates to the Mo(VI) atom, the three atoms involved in chelation comprising the fac sites of the octahedron surrounding the methanol-coordinated metal atom. The methanol molecule fo...
Autores principales: | , , , |
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Formato: | Online Artículo Texto |
Lenguaje: | English |
Publicado: |
International Union of Crystallography
2011
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Materias: | |
Acceso en línea: | https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3120353/ https://www.ncbi.nlm.nih.gov/pubmed/21754638 http://dx.doi.org/10.1107/S1600536811017259 |
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author | Ngan, Ngui Khiong Wong, Richard Chee Seng Lo, Kong Mun Ng, Seik Weng |
author_facet | Ngan, Ngui Khiong Wong, Richard Chee Seng Lo, Kong Mun Ng, Seik Weng |
author_sort | Ngan, Ngui Khiong |
collection | PubMed |
description | In the title co-crystal, [Mo(C(14)H(9)ClN(2)O(4))O(2)(CH(3)OH)]·C(10)H(8)N(2), the deprotonated Schiff base O,N,O′-chelates to the Mo(VI) atom, the three atoms involved in chelation comprising the fac sites of the octahedron surrounding the methanol-coordinated metal atom. The methanol molecule forms an O—H⋯N hydrogen bond to an N atom of the 4,4′-bipyridine solvent molecule; the hydroxy group of the Schiff base forms an O—H⋯N hydrogen bond to the other N atom of another molecule. The two hydrogen bonds leading to the formation of a helical chain running along the b axis. |
format | Online Article Text |
id | pubmed-3120353 |
institution | National Center for Biotechnology Information |
language | English |
publishDate | 2011 |
publisher | International Union of Crystallography |
record_format | MEDLINE/PubMed |
spelling | pubmed-31203532011-07-13 [N′-(5-Chloro-2-oxidobenzyl-κO)-2,4-dihydroxybenzohydrazidato-κ(2) N′,O](methanol-κO)dioxidomolybdenum(VI)–4,4′-bipyridine (1/1) Ngan, Ngui Khiong Wong, Richard Chee Seng Lo, Kong Mun Ng, Seik Weng Acta Crystallogr Sect E Struct Rep Online Metal-Organic Papers In the title co-crystal, [Mo(C(14)H(9)ClN(2)O(4))O(2)(CH(3)OH)]·C(10)H(8)N(2), the deprotonated Schiff base O,N,O′-chelates to the Mo(VI) atom, the three atoms involved in chelation comprising the fac sites of the octahedron surrounding the methanol-coordinated metal atom. The methanol molecule forms an O—H⋯N hydrogen bond to an N atom of the 4,4′-bipyridine solvent molecule; the hydroxy group of the Schiff base forms an O—H⋯N hydrogen bond to the other N atom of another molecule. The two hydrogen bonds leading to the formation of a helical chain running along the b axis. International Union of Crystallography 2011-05-14 /pmc/articles/PMC3120353/ /pubmed/21754638 http://dx.doi.org/10.1107/S1600536811017259 Text en © Ngan et al. 2011 http://creativecommons.org/licenses/by/2.0/uk/ This is an open-access article distributed under the terms of the Creative Commons Attribution Licence, which permits unrestricted use, distribution, and reproduction in any medium, provided the original authors and source are cited. |
spellingShingle | Metal-Organic Papers Ngan, Ngui Khiong Wong, Richard Chee Seng Lo, Kong Mun Ng, Seik Weng [N′-(5-Chloro-2-oxidobenzyl-κO)-2,4-dihydroxybenzohydrazidato-κ(2) N′,O](methanol-κO)dioxidomolybdenum(VI)–4,4′-bipyridine (1/1) |
title | [N′-(5-Chloro-2-oxidobenzyl-κO)-2,4-dihydroxybenzohydrazidato-κ(2)
N′,O](methanol-κO)dioxidomolybdenum(VI)–4,4′-bipyridine (1/1) |
title_full | [N′-(5-Chloro-2-oxidobenzyl-κO)-2,4-dihydroxybenzohydrazidato-κ(2)
N′,O](methanol-κO)dioxidomolybdenum(VI)–4,4′-bipyridine (1/1) |
title_fullStr | [N′-(5-Chloro-2-oxidobenzyl-κO)-2,4-dihydroxybenzohydrazidato-κ(2)
N′,O](methanol-κO)dioxidomolybdenum(VI)–4,4′-bipyridine (1/1) |
title_full_unstemmed | [N′-(5-Chloro-2-oxidobenzyl-κO)-2,4-dihydroxybenzohydrazidato-κ(2)
N′,O](methanol-κO)dioxidomolybdenum(VI)–4,4′-bipyridine (1/1) |
title_short | [N′-(5-Chloro-2-oxidobenzyl-κO)-2,4-dihydroxybenzohydrazidato-κ(2)
N′,O](methanol-κO)dioxidomolybdenum(VI)–4,4′-bipyridine (1/1) |
title_sort | [n′-(5-chloro-2-oxidobenzyl-κo)-2,4-dihydroxybenzohydrazidato-κ(2)
n′,o](methanol-κo)dioxidomolybdenum(vi)–4,4′-bipyridine (1/1) |
topic | Metal-Organic Papers |
url | https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3120353/ https://www.ncbi.nlm.nih.gov/pubmed/21754638 http://dx.doi.org/10.1107/S1600536811017259 |
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